铜钴硫纳米材料的合成及应用研究概述
A Review on Synthesis and Application of Copper Cobalt Sulfide Nanomaterials
DOI: 10.12677/MS.2018.83026, PDF,    国家自然科学基金支持
作者: 王 豪, 杨伟鑫, 刘雅慧, 刘若纳, 郭祥瑞, 林婷婷, 叶寅路, 尹德武：温州大学化学与材料工程学院，浙江 温州
关键词: 铜钴硫；纳米材料；合成；性能；应用；Copper Cobalt Sulfur； Nanomaterials； Synthesis； Performance； Application
摘要: 近年来，三元金属基硫化物纳米材料因结构多元和储量丰富的特点，对其应用的研究已经成为了当今材料研究的热点。因尺寸纯相的三元硫化物合成较为困难，目前对于纳米级三元硫族化合物的研究及报道较少。本文主要介绍了铜钴硫(CuCo2S4)纳米材料的常规合成方法以及在光热疗法、制备高性能的超级电容器、锂离子电池和各类反应催化剂等各个领域的应用。最后指出了铜钴硫(CuCo2S4)纳米材料目前存在的问题以及今后的发展方向。
Abstract: In recent years, the ternary metal-based sulfide nanomaterials have become the hotspot in material research due to their multiple structures and rich reserves. Because it is difficult to synthesize ternary sulphide with pure phase, there are few researches and reports on nanoscale ternary chalcogenides. This article mainly introduces the conventional synthesis methods of copper, cobalt and sulfur (CuCo2S4) nanomaterials and their application in various fields such as photothermal therapy, preparation of high performance supercapacitors, lithium ion batteries and various types of reaction catalysts. Finally, it points out the existing problems of copper, cobalt and sulfur (CuCo2S4) nanomaterials and the future development direction.
文章引用：王豪, 杨伟鑫, 刘雅慧, 刘若纳, 郭祥瑞, 林婷婷, 叶寅路, 尹德武. 铜钴硫纳米材料的合成及应用研究概述[J]. 材料科学, 2018, 8(3): 245-252. https://doi.org/10.12677/MS.2018.83026

参考文献

[1] Wiltrout, A.M., Read, C.G., Spencer, E.M., et al. (2015) Solution Synthesis of Thiospinel CuCo2S4 Nanoparticles. In-organic Chemistry, 55, 221-226.
[Google Scholar] [CrossRef] [PubMed]
[2] Li, B., Yuan, F., He, G., et al. (2017) Ultrasmall CuCo2S4 Nanocrystals: All-in-One Theragnosis Nanoplatform with Magnetic Reso-nance/Near-Infrared Imaging for Efficiently Photothermal Therapy of Tumors. Advanced Functional Materials, 27, 1606218.
[Google Scholar] [CrossRef] 
[3] Ahmed, A.T.A., Chavan, H.S., Jo, Y., et al. (2017) One-Step Facile Route to Copper Cobalt Sulfide Electrodes for Supercapacitors with High-Rate Long-Cycle Life Per-formance. Journal of Alloys & Compounds, , 724.
[Google Scholar] [CrossRef] 
[4] Huang, X., Deng, G., Liao, L., et al. (2017) CuCo2S4 Nano-crystals: A New Platform for Multimodal Imaging Guided Photothermal Therapy. Nanoscale, 9, 2626.
[Google Scholar] [CrossRef] 
[5] Givalou, L., Antoniadou, M., Perganti, D., et al. (2016) Electrode-posited Cobalt-Copper Sulfide Counter Electrodes for Highly Efficient Quantum Dot Sensitized Solar Cells. Electro-chimica Acta, 210, 630-638.
[Google Scholar] [CrossRef] 
[6] Zhu, Y., Chen, X., Zhou, W., et al. (2017) Controllable Preparation of Highly Uniform CuCo2S4 Materials as Battery Electrode for Energy Storage with Enhanced Electro-chemical Performances. Electrochimica Acta, 249, 64-71.
[Google Scholar] [CrossRef] 
[7] Verma, R., Kothandaraman, R. and Varadaraju, U.V. (2016) In-Situ Carbon Coated CuCo2S4 Anode Material for Li-Ion Battery Applications. Applied Surface Science, 418, 30-39.
[Google Scholar] [CrossRef] 
[8] Nie, L., Wang, H., Chai, Y., et al. (2016) In Situ Formation of Flower-Like CuCo2S4 Nanosheets/Graphene Composites with Enhanced Lithium Storage Properties. RSC Advances, 6, 38321-38327.
[Google Scholar] [CrossRef] 
[9] You, H., Zhang, L., Jiang, Y., et al. (2018) Bub-ble-Supported Engineering of Hierarchical CuCo2S4 Hollow Spheres for Enhanced Electrochemical Performance. Journal of Materials Chemistry A.
[Google Scholar] [CrossRef] 
[10] Li, B., Ye, K., Zhang, Y., et al. (2015) Photothermal Theragnosis Synergistic Therapy Based on Bimetal Sulphide Nanocrystals Rather than Nanocomposites. Advanced Materials, 27, 1339-1345.
[Google Scholar] [CrossRef] [PubMed]
[11] Gou, X., Cheng, F., Shi, Y., et al. (2006) Shape-Controlled Synthesis of Ternary Chalcogenide ZnIn2S4 and CuIn(S,Se)2 Nano-/Microstructures via Facile Solution Route. Journal of the American Chemical Society, 128, 7222-7229.
[Google Scholar] [CrossRef] [PubMed]
[12] Yang, L., Xie, L., Ren, X., et al. (2017) Hierarchical CuCo2S4 Nanoarrays for High-Efficient and Durable Water Oxidation Electrocatalysis. Chemical Communications, 54, 78-81.
[Google Scholar] [CrossRef] 
[13] Fath, R.H. and Hoseini, S.J. (2017) Synthesis of Thiospinel CuCo2S4 and CuCo2S4/Reduced-Graphene Oxide Nanohybrids as Highly Effective Catalysts for the Sonogashira Reaction. New Journal of Chemistry, 41, 3392-3398.
[Google Scholar] [CrossRef] 
[14] Han, M., Zhao, S., Wang, Y., et al. (2016) Two-Dimensional Nanostructures of Non-Layered Ternary Thiospinels and Their Bifunctional Electrocatalytic Properties for Oxygen Reduction and Evolution: The Case of CuCo2S4 Nanosheets. Inorganic Chemistry Frontiers, 3, 1501-1509.
[Google Scholar] [CrossRef] 
[15] Chauhan, M., Reddy, K.P., Gopinath, C.S., et al. (2017) Copper Co-balt Sulfide Nanosheets Realizing a Promising Electrocatalytic Oxygen Evolution Reaction. ACS Catalysis, 7, 5871-5879.
[Google Scholar] [CrossRef] 
[16] Ge, Y., Wu, J., Xu, X., et al. (2016) Facile Synthesis of CoNi2S4, and CuCo2S4, with Different Morphologies as Prominent Catalysts for Hydrogen Evolution Reaction. International Journal of Hydrogen Energy, 41, 19847-19854.
[Google Scholar] [CrossRef] 
[17] Zhang, M., Annamalai, K.P., Liu, L., et al. (2017) Multiwalled Carbon Nanotube-Supported CuCo2S4 as a Heterogeneous Fenton-Like Catalyst with Enhanced Performance. RSC Advances, 7, 20724-20731.
[Google Scholar] [CrossRef] 
[18] Miller, J.R. and Simon, P. (2008) Materials Science. Electrochemical Capacitors for Energy Management. Science, 321, 651-652.
[Google Scholar] [CrossRef] [PubMed]
[19] Winter, M. and Brodd, R.J. (2004) What Are Batteries, Fuel Cells, and Supercapacitors? Chemical Reviews, 35, 4245-4269.
[Google Scholar] [CrossRef] 
[20] Zhang, Y., Xu, J., Zhang, Y., et al. (2017) Facile Fabrication of Flower-Like CuCo2S4, on Ni Foam for Supercapacitor Application. Journal of Materials Science, 52, 9531-9538.
[Google Scholar] [CrossRef] 
[21] Wang, Q., Liang, X., Yang, D., et al. (2017) Facile Synthesis of Novel CuCo2S4 Nanospheres for Coaxial Fiber Supercapacitors. RSC Advances, 7, 29933-29937.
[Google Scholar] [CrossRef] 
[22] Cheng, S., Shi, T., Chen, C., et al. (2017) Construction of Porous CuCo2S4 Nanorod Arrays via Anion Exchange for High-Performance Asymmetric Supercapacitor. Scientific Reports, 7, 6681.
[Google Scholar] [CrossRef] [PubMed]
[23] Liu, L.L., Annamalai, K.P. and Tao, Y.S. (2016) A Hierarchi-cally Porous CuCo2S4/Graphene Composite as an Electrode Material for Supercapacitors. New Carbon Materials, 31, 336-342.
[Google Scholar] [CrossRef] 
[24] Zhu, Y., Ji, X., Chen, H., et al. (2016) The Investigation of the Electrochemically Supercapacitive Performances of Mesoporous CuCo2S4. RSC Advances, 6, 84236-84241.
[Google Scholar] [CrossRef] 
[25] Shen, J., Tang, J., Dong, P., et al. (2016) Construction of Three-Dimensional CuCo2S4/CNT/Graphene Nanocomposite for High Performance Supercapacitors. RSC Advances, 6, 13456-13460.
[Google Scholar] [CrossRef] 
[26] Moosavifard, S.E., Fani, S. and Rahmanian, M. (2016) Hierarchical CuCo2S4 Hollow Nanoneedle Arrays as Novel Binder-Free Electrodes for High-Performance Asymmetric Supercapacitors. Chemical Communications, 52, 4517-4520.
[Google Scholar] [CrossRef] 
[27] Tang, J., Ge, Y., Shen, J., et al. (2016) Facile Synthesis of CuCo2S4 as a Novel Electrode Material for Ultrahigh Supercapacitor Performance. Chemical Communications, 52, 1509-1512.
[Google Scholar] [CrossRef] 
[28] Xu, Y., Zhou, T., Cao, X., et al. (2017) Low-Cost Synthesis and Electrochemical Characteristics of Ternary Cu-Co Sulfides for High Performance Full-Cell Asymmetric Supercapacitors. Materials Research Bulletin, 91, 68-76.
[Google Scholar] [CrossRef] 
[29] Ma, H., He, J., Xiong, D.B., et al. (2016) Nickel Cobalt Hydroxide @Reduced Graphene Oxide Hybrid Nanolayers for High Performance Asymmetric Supercapacitors with Remarkable Cycling Stability. ACS Applied Materials & Interfaces, 8, 1992-2000.
[Google Scholar] [CrossRef] [PubMed]
[30] Syedvali, P., Rajeshkhanna, G., Umeshbabu, E., et al. (2015) In Situ Fabrication of Graphene Decorated Microstructured Globe Artichokes of Partial Molar Nickel Cobaltite Anchored on a Ni Foam as a High-Performance Supercapacitor Electrode. RSC Advances, 5, 38407-38416.
[Google Scholar] [CrossRef] 
[31] Peng, S., Li, L., Li, C., et al. (2013) Growth of NiCo2S4 Nanosheets on Graphene for High-Performance Supercapacitors. Chemical Communications, 49, 10178-10180.
[Google Scholar] [CrossRef] [PubMed]
[32] Wang, Q., Xu, J., Wang, X., et al. (2014) Core-Shell CuCo2S4@MnO2 Nanowires on Carbon Fabrics as High-Performance Materials for Flexible, All-Solid-State. Electrochemical Capacitors Chemelectrochem, 1, 559-564.
[Google Scholar] [CrossRef] 
[33] Liu, L., Niu, Z. and Chen, J. (2016) Unconventional Supercapacitors from Nanocarbon-Based Electrode Materials to Device Configurations. Chemical Society Reviews, 45, 4340-4363.
[Google Scholar] [CrossRef] 
[34] Dai, L., Chang, D.W., Baek, J.B., et al. (2012) Carbon Nanomaterials for Advanced Energy Conversion and Storage. Small, 8, 1130-1166.
[Google Scholar] [CrossRef] [PubMed]
[35] Prabakar, S.J.R., Babu, R.S., Oh, M., et al. (2014) Dense CoO/Graphene Stacks via Self-Assembly for Improved Reversibility as High Performance Anode in Lithium Ion Bat-teries. Journal of Power Sources, 272, 1037-1045.
[Google Scholar] [CrossRef] 
[36] Luo, Q., Gu, Y., Li, J., et al. (2016) Efficient Ternary Cobalt Spinel Counter Electrodes for Quantum-Dot Sensitized Solar Cells. Journal of Power Sources, 312, 93-100.
[Google Scholar] [CrossRef] 

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