钼酸铋氧化钛复合光催化剂的研究
Research on Bismuth Molybdate Titanium Oxide Composite Photocatalyst
DOI: 10.12677/AAC.2023.132026, PDF,   
作者: 孙祥森：南京林业大学马克思主义学院，江苏 南京；李宇轩：齐鲁工业大学材料科学与工程学院，山东 济南
关键词: 复合；钼酸铋；氧化钛；光催化活性；异质结；Composite； Bi2MoO6； TiO2； Photocatalytic Activity； Heterojunction
摘要: 钼酸铋作为一种具有天然矿石结构的复合氧化物，因带隙宽度小，对可见光有响应被广泛关注。其中γ-Bi2MoO6在钼酸铋所有相态里光催化性能最好，可以用于有机污水处理，空气净化等方面，但是其低下的量子产率限制了其光催化性能。近年来人们为了提高其光催化性能研究了其多种形貌结构和其与二氧化钛复合性能的变化。本文综述了钼酸铋半导体及其与二氧化钛复合的制备方法，总结了钼酸铋及钼酸铋氧化钛复合光催化剂的改性方法，并展望了其在污水处理、光电转换和卫生保健等方面的应用。
Abstract: Bismuth molybdate, as a composite oxide with natural ore structure, is widely concerned because of its small band gap width and its response to visible light. Among them, the photocatalytic performance of past-Bi2MoO6 is the best in all phase states of bismuth molybdate, which can be used in organic sewage treatment, air purification, etc., but its low quantum yield limits its photocatalytic performance. In order to improve its photocatalytic properties, the changes of its morphology and structure as well as its composite properties with titanium dioxide have been studied in recent years. In this paper, the preparation methods of bismuth molybdate semiconductor and its composite with titanium dioxide are reviewed, the modification methods of bismuth molybdate and bismuth molybdate titania composite photocatalyst are summarized, and their applications in sewage treatment, photoelectric conversion and health care are prospected.
文章引用：孙祥森, 李宇轩. 钼酸铋氧化钛复合光催化剂的研究[J]. 分析化学进展, 2023, 13(2): 223-231. https://doi.org/10.12677/AAC.2023.132026

参考文献

[1] Zhang, X., Ai, Z.H., Jia, F.L. and Zhang, L.Z. (2008) Generalized One-Pot Synthesis, Characterization, and Photocatalytic Activity of Hierarchical BiOX (X = Cl, Br, I) Nanoplate Microspheres. Journal of Physical Chemistry C, 112, 747-753.
[Google Scholar] [CrossRef] 
[2] Dai, Z., Qin, F., Zhao, H.P., et al. (2016) Crystal Defects Engineering of AurivilliusBi2MoO6 by Ce Doping for Increased Reactive Species Production in Photocatalysis. ACS Catalysis, 6, 3180-3192.
[Google Scholar] [CrossRef] 
[3] Zhao, J., Yang, Y., Yu, W.S., et al. (2017) Bi2MoO6/RGO Composite Nanofibers: Facile Electrospinning Fabrication, Structure, and Significantly Improved Photocatalytic Water Splitting Activity. Journal of Materials Science: Materials in Electronics, 28, 543-552.
[Google Scholar] [CrossRef] 
[4] Hao, Y.Z., Dong, X.L., Zhai, S.R., et al. (2016) Towards Understanding the Photocatalytic Activity Enhancement of Ordered Mesoporous Bi2MoO6 Crystals Prepared via a Novel Vacuum-Assisted Nanocasting Method. RSC Advances, 6, 35709-35718.
[Google Scholar] [CrossRef] 
[5] Tian, J., Hao, P., Wei, N., Cui, H.Z. and Liu, H. (2015) 3D Bi2MoO6 Nanosheet/TiO2 Nanobelt Heterostructure: Enhanced Photocatalytic Activities and Photoelectochemistry Performance. ACS Catalysis, 5, 4530-4536.
[Google Scholar] [CrossRef] 
[6] Umapathy, V., Manikandan, A., Antony, S.A., Ramu, P. and Neeraja, P. (2015) Structure, Morphology and Opto-Mag- netic Properties of Bi2MoO6 Nano-Photocatalyst Synthesized by Sol-Gel Method. Transactions of Nonferrous Metals Society of China, 25, 3271-3278.
[Google Scholar] [CrossRef] 
[7] 孙明志, 郭鹏瑶, 丁航行. 煅烧温度对溶胶-凝胶法制备钼酸铋光催化性能的影响[J]. 材料热处理学报, 2017, 38(3): 21-28.
[8] 李东. 钛氧化物复合多孔薄膜的制备及其光转化应用研究[D]: [硕士学位论文]. 太原: 中北大学, 2021.
[9] Surah, S.S., Sirohi, S., Nain, R. and Kumar, G. (2018) Antimicrobial Activity of TiO2 Nanostructures Synthesized by Hydrothermal Method. AIP Conference Proceedings, 1932, Article ID: 030038.
[Google Scholar] [CrossRef] 
[10] Acharyulu, N.P.S., Srinivasu, C. and Fakruddin Babavali, S.K. (2020) Synthesis of Carbon Nano Spherical Structures and Nano Composite Oxide [TiO2/SnO2 (2:1)] Hollow Spheres by Hydrothermal Method and Study of Characterization with Photo Catalytic Activity. Materials Today: Proceedings, 2, 1282-1288.
[Google Scholar] [CrossRef] 
[11] 张萍, 许丽, 王莉. 水热法合成二氧化钛纳米管的晶型与形貌控制的研究[J]. 当代化工, 2018, 47(5): 893-896.
[12] 张婷, 黄剑锋, 曹丽云. 微波水热温度对合成Bi2MoO6微晶形貌和光学性能的影响[J]. 人工晶体学报, 2012, 41(3): 616-620.
[13] 张艳君, 孙志君. 模板法制备TiO2纳米介孔薄膜[J]. 化工新型材料, 2015, 43(1): 52-54.
[14] Alosfur, F.K.M., Ouda, A.A., Ridha, N.J. and Abud, S.H. (2019) Structure and Optical Properties of TiO2 Nanorods Prepared Using Polyol Solvothermal Method. AIP Conference Proceedings, 2144, Article ID: 030025.
[Google Scholar] [CrossRef] 
[15] Li, D., Dai, S., Li, J., et al. (2018) Microstructure and Photocatalytic Properties of TiO2-Reduced Graphene Oxide Nanocomposites Prepared by Solvothermal Method. Journal of Electronic Materials, 47, 7372-7379.
[Google Scholar] [CrossRef] 
[16] Alemi, A.A., Kashfi, R. and Shabani, B. (2014) Preparation and Characterization of Novel Ln (Gd3+, Ho3+ and Yb3+)-Doped Bi2MoO6 with Aurivillius Layered Structures and Photocatalytic Activities under Visible Light Irradiation. Journal of Molecular Catalysis A Chemical, 392, 290-298.
[Google Scholar] [CrossRef] 
[17] Imani, M., Farajnezhad, M. and Tadjarodi, A. (2017) 3D Hierarchical Flower-Like Nanostructure of Bi2MoO6: Mechanochemical Synthesis, the Effect of Synthesis Parameters and Photocatalytic Activity. Materials Research Bulletin, 87, 92-101.
[Google Scholar] [CrossRef] 
[18] 张婷, 黄剑锋, 曹丽云, 周森. 微波水热合成时间对Bi2MoO6微晶形貌和可见光催化性能的影响[J]. 硅酸盐学报, 2013, 41(5): 710-714.
[19] 朱礼. 钼酸铋复合氧化物的制备、修饰及其可见光催化性能的研究[D]: [硕士学位论文]. 广州: 华南理工大学, 2011.
[20] 杜永芳, 宋继梅, 王红, 等. 共沉淀法制备α-Bi2Mo3O12和γ-Bi2MoO6及可见光催化性能[J]. 合肥工业大学学报(自然科学版), 2012, 35(11): 66-71.
[21] Tian, G.H., Chen, Y.J., Lu, D.T., et al. (2013) Hierarchical Flake-Like Bi2MoO6/TiO2 Bilayer Films for Visible-Light- Induced Self-Cleaning Applications. Journal of Materials Chemistry A, 1, 6961-6968.
[Google Scholar] [CrossRef] 
[22] 王玉梅, 冀海伟, 常通. Au/TiO2复合物的制备、表征及其增强光催化灭菌活性[J]. 化工进展, 2020, 39(5): 1857-1865.
[23] 蔡永双, 张艳波. 铋自掺杂钼酸铋的合成及其可见光催化性能研究[J]. 武汉纺织大学学报, 2022, 35(4): 48-53.
[24] 崔心蕾, 王哲禹, 刘莹莹, 郭齐. 水热法制备钼酸铋及其光催化性能[J]. 中国石油和化工标准与质量, 2020, 40(22): 95-97.
[25] Zhang, Z.J., Wang, W.Z., Wang, L. And Sun, S.M. (2012) Enhancement of Visible-Light Photocatalysis by Coupling with Narrow-Band-Gap Semiconductor: A Case Study on Bi2S3/Bi2WO6. ACS Applied Materials & Interfaces, 4, 593-597.
[Google Scholar] [CrossRef] [PubMed]
[26] Tian, G.H., Chen, Y.J., Zhou, W., et al. (2011) Facile Solvothermal Synthesis of Hierarchical Flower-Like Bi2MoO6 Hollow Spheres as High Performance Visible-Light Driven Photocatalysts. Journal of Materials Chemistry, 21, 887-892.
[Google Scholar] [CrossRef] 
[27] 权晶晶, 秦冬冬, 贺彩花, 等. 3D Bi2MoO6纳米片与钨掺杂的二氧化钛纳米线异质结光电化学性能的研究[J]. 广东化工, 2017, 44(10): 1-3.
[28] 李华. Bi2MoO6Au/TiO2三元光催化薄膜的制备及其催化性能研究[D]: [硕士学位论文]. 西安: 西北大学, 2017.
[29] Wang, Q., Xie, W.L. and Guo, L. (2022) Molybdenum and Zirconium Oxides Supported on KIT-6 Silica: A Recyclable Composite Catalyst for One-Pot Biodiesel Production from Simulated Low-Quality Oils. Renew Energy, 187, 907-922.
[Google Scholar] [CrossRef] 

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