ZSM-5分子筛膜在水处理中的应用研究进展
Research Progress of ZSM-5 Molecular Sieve Membrane in Water Treatment
DOI: 10.12677/ms.2024.149144, PDF,    科研立项经费支持
作者: 吴 凡, 许 琳, 张 洁, 杨美玲, 易 欢, 熊 伟, 何 柏, 蒋松山*：重庆科技大学化学化工学院，重庆
关键词: ZSM-5；分子筛膜材料；水处理；研究进展；ZSM-5； Molecular Sieve Membrane； Water Treatment； Research Progress
摘要: 新型沸石膜材料在多个领域的新兴应用中表现出高性能。ZSM-5分子筛膜以其独特的微孔结构、可控的硅铝比、高化学稳定性、高渗透性和优异的选择性在水处理中成为研究热点。本文先介绍了各类型ZSM-5分子筛膜材料，然后从水中有机污染物、重金属的去除和有机物分离以及海水淡化除盐等方面综述了ZSM-5分子筛膜的应用。最后，对ZSM-5分子筛膜在水处理应用中存在的不足进行了总结，并对其存在的问题和未来发展进行了分析，以期为ZSM-5分子筛膜在水处理中的应用研究提供参考。
Abstract: The emerging applications of novel zeolite materials demonstrate high performance across multiple fields. ZSM-5 molecular sieve membranes, characterized by their unique microporous structure, controllable Si/Al ratio, high chemical stability, excellent permeability, and superior selectivity, have become a research hotspot in water treatment. This article first introduces various types of ZSM-5 molecular sieve membrane materials. Subsequently, it comprehensively reviews the applications of ZSM-5 molecular sieve membranes in water treatment, including the removal of organic pollutants and heavy metals, separation of organic compounds, and seawater desalination. Finally, the shortcomings of ZSM-5 molecular sieve membranes in water treatment applications are summarized, and an analysis of current issues and future developments is provided, aiming to offer insights for further research on the application of ZSM-5 molecular sieve membranes in water treatment.
文章引用：吴凡, 许琳, 张洁, 杨美玲, 易欢, 熊伟, 何柏, 蒋松山. ZSM-5分子筛膜在水处理中的应用研究进展[J]. 材料科学, 2024, 14(9): 1299-1308. https://doi.org/10.12677/ms.2024.149144

参考文献

[1] Hassan Rashid, M.A.U., Manzoor, M.M. and Mukhtar, S. (2018) Urbanization and Its Effects on Water Resources: An Exploratory Analysis. Asian Journal of Water, Environment and Pollution, 15, 67-74. [Google Scholar] [CrossRef] 
[2] Manna, M. and Sen, S. (2022) Advanced Oxidation Process: A Sustainable Technology for Treating Refractory Organic Compounds Present in Industrial Wastewater. Environmental Science and Pollution Research, 30, 25477-25505. [Google Scholar] [CrossRef] [PubMed]
[3] Rout, P.R., Zhang, T.C., Bhunia, P. and Surampalli, R.Y. (2021) Treatment Technologies for Emerging Contaminants in Wastewater Treatment Plants: A Review. Science of the Total Environment, 753, Article ID: 141990. [Google Scholar] [CrossRef] [PubMed]
[4] Eslami, S., Norouzbahari, S., Vatanpour, V., Ghadimi, A. and Rostamizadeh, M. (2024) Synthesis and Characterization of Enhanced Polysulfone-Based Mixed Matrix Membranes Containing ZSM-5 Zeolite for Protein and Dye Removal. Journal of Industrial and Engineering Chemistry, 137, 455-467. [Google Scholar] [CrossRef] 
[5] 王志文. ZSM-5沸石膜的制备及其分离性能研究[D]: [硕士学位论文]. 大连: 大连理工大学, 2017.
[6] Cui, J., Zhang, X., Liu, H., Liu, S. and Yeung, K.L. (2008) Preparation and Application of Zeolite/Ceramic Microfiltration Membranes for Treatment of Oil Contaminated Water. Journal of Membrane Science, 325, 420-426. [Google Scholar] [CrossRef] 
[7] 徐凯. ZSM-5与Fe-ZSM-5分子筛膜的合成, 表征及其在脱盐过程中的应用[D]: [硕士学位论文]. 天津: 天津大学, 2014.
[8] Li, L., Yang, J., Li, J., Wang, J., Lu, J., Yin, D., et al. (2016) High Performance ZSM‐5 Membranes on Coarse Macroporous Α‐Al2O3 Supports for Dehydration of Alcohols. AIChE Journal, 62, 2813-2824. [Google Scholar] [CrossRef] 
[9] Cao, Z., Zeng, S., Xu, Z., Arvanitis, A., Yang, S., Gu, X., et al. (2018) Ultrathin ZSM-5 Zeolite Nanosheet Laminated Membrane for High-Flux Desalination of Concentrated Brines. Science Advances, 4, eaau8634. [Google Scholar] [CrossRef] [PubMed]
[10] Peng, L., Xu, X., Yao, X., Liu, H. and Gu, X. (2018) Fabrication of Novel Hierarchical ZSM-5 Zeolite Membranes with Tunable Mesopores for Ultrafiltration. Journal of Membrane Science, 549, 446-455. [Google Scholar] [CrossRef] 
[11] Chen, H., Zhang, H. and Yan, Y. (2012) Preparation and Characterization of a Novel Gradient Porous ZSM-5 Zeolite Membrane/PSSF Composite and Its Application for Toluene Adsorption. Chemical Engineering Journal, 209, 372-378. [Google Scholar] [CrossRef] 
[12] Radoor, S., Karayil, J., Jayakumar, A., Parameswaranpillai, J. and Siengchin, S. (2021) An Efficient Removal of Malachite Green Dye from Aqueous Environment Using ZSM-5 Zeolite/Polyvinyl Alcohol/Carboxymethyl Cellulose/Sodium Alginate Bio Composite. Journal of Polymers and the Environment, 29, 2126-2139. [Google Scholar] [CrossRef] 
[13] Yang, S., Zhang, Y., Guo, W., Zhou, L., Chen, M., Ma, J., et al. (2022) Synthesis of Thin ZSM-5 Zeolite Membranes in a Self-Terminating Mother Liquor. Separation and Purification Technology, 299, Article ID: 121721. [Google Scholar] [CrossRef] 
[14] Schneider, H., Schindel, L.K., Gomes, L.B., Tessaro, I.C. and Marcilio, N.R. (2021) Template-Free ZSM-5 Membrane Preparation on Alumina Support by Secondary Hydrothermal Synthesis. Current Research in Green and Sustainable Chemistry, 4, Article ID: 100049. [Google Scholar] [CrossRef] 
[15] Wang, S., Li, L., Li, J., Wang, J., Pan, E., Lu, J., et al. (2021) Sustainable Synthesis of Highly Water-Selective ZSM-5 Membrane by Wet Gel Conversion. Journal of Membrane Science, 635, Article ID: 119431. [Google Scholar] [CrossRef] 
[16] Lakhane, M., Mahabole, M., Bogle, K., Khairnar, R. and Kokol, V. (2019) Nanocomposite Films Prepared from Differently Modified ZSM-5 Zeolite and Cellulose Nanofibrils for Cationic and Anionic Dyes Removal. Fibers and Polymers, 20, 2127-2139. [Google Scholar] [CrossRef] 
[17] Radoor, S., Karayil, J., Parameswaranpillai, J. and Siengchin, S. (2020) Adsorption Study of Anionic Dye, Eriochrome Black T from Aqueous Medium Using Polyvinyl Alcohol/Starch/ZSM-5 Zeolite Membrane. Journal of Polymers and the Environment, 28, 2631-2643. [Google Scholar] [CrossRef] 
[18] Salahshoori, I., Seyfaee, A. and Babapoor, A. (2021) Recent Advances in Synthesis and Applications of Mixed Matrix Membranes. Synthesis and Sintering, 1, 1-27. [Google Scholar] [CrossRef] 
[19] 郭宇, 戴耀城, 吴红梅. Pd-ZSM-5复合膜的制备及其氢气分离性能[J]. 南京工业大学学报(自然科学版), 2024, 46(2): 160-169.
[20] Cui, N., Guo, H., Zhou, J., Li, L., Guo, L. and Hua, Z. (2020) Regulation of Framework Al Distribution of High-Silica Hierarchically Structured ZSM-5 Zeolites by Boron-Modification and Its Effect on Materials Catalytic Performance in Methanol-to-Propylene Reaction. Microporous and Mesoporous Materials, 306, Article ID: 110411. [Google Scholar] [CrossRef] 
[21] Ben Soltan, W., Sun, J., Wang, W., Peng, J., Zhang, Y., Wang, T., et al. (2024) Modification of Fe on Hydrophobic ZSM-5 Zeolite: Optimization of Adsorption and Catalytic Performance for Decomposition of VOCs at Low-Temperature. Separation and Purification Technology, 333, Article ID: 125908. [Google Scholar] [CrossRef] 
[22] Yashnik, S.A., Taran, O.P., Surovtsova, T.A., Ayusheev, A.B. and Parmon, V.N. (2022) Cu-and Fe-Substituted ZSM-5 Zeolite as an Effective Catalyst for Wet Peroxide Oxidation of Rhodamine 6 G Dye. Journal of Environmental Chemical Engineering, 10, Article ID: 107950. [Google Scholar] [CrossRef] 
[23] Chen, H., Zhang, H. and Yan, Y. (2014) Fabrication of Porous Copper/Manganese Binary Oxides Modified ZSM-5 Membrane Catalyst and Potential Application in the Removal of VOCs. Chemical Engineering Journal, 254, 133-142. [Google Scholar] [CrossRef] 
[24] Wang, X., Huang, Y., Zhang, X., Feng, X. and Huang, W. (2017) Synthesis of Hydrophilic Acid-Resistant Ge-ZSM-5 Membranes via Secondary Growth Method Using Silicalite-1 Zeolite as Seeds. Chemical Research in Chinese Universities, 33, 12-16. [Google Scholar] [CrossRef] 
[25] Saranya, R., Arthanareeswaran, G., Ismail, A.F., Reddy, N.L., Shankar, M.V. and Kweon, J. (2017) Efficient Rejection of Organic Compounds Using Functionalized ZSM-5 Incorporated PPSU Mixed Matrix Membrane. RSC Advances, 7, 15536-15552. [Google Scholar] [CrossRef] 
[26] Wenten, I.G., Khoiruddin, K., Mukti, R.R., Rahmah, W., Wang, Z. and Kawi, S. (2021) Zeolite Membrane Reactors: From Preparation to Application in Heterogeneous Catalytic Reactions. Reaction Chemistry & Engineering, 6, 401-417. [Google Scholar] [CrossRef] 
[27] Raza, W., Lee, J., Raza, N., Luo, Y., Kim, K. and Yang, J. (2019) Removal of Phenolic Compounds from Industrial Waste Water Based on Membrane-Based Technologies. Journal of Industrial and Engineering Chemistry, 71, 1-18. [Google Scholar] [CrossRef] 
[28] Jiang, S., Zhang, H. and Yan, Y. (2015) Catalytic Wet Peroxide Oxidation of Phenol Wastewater over a Novel Cu-ZSM-5 Membrane Catalyst. Catalysis Communications, 71, 28-31. [Google Scholar] [CrossRef] 
[29] Yan, Y., Jiang, S., Zhang, H. and Zhang, X. (2015) Preparation of Novel Fe-ZSM-5 Zeolite Membrane Catalysts for Catalytic Wet Peroxide Oxidation of Phenol in a Membrane Reactor. Chemical Engineering Journal, 259, 243-251. [Google Scholar] [CrossRef] 
[30] He, D., Zhang, H. and Yan, Y. (2017) Chemical Vapor Deposition of CuO on ZSM-5 Membrane for Catalytic Wet Peroxide Oxidation of Phenol in a Fixed Bed Reactor. RSC Advances, 7, 47435-47447. [Google Scholar] [CrossRef] 
[31] Santos, A., Lewis, R.J., Morgan, D.J., Davies, T.E., Hampton, E., Gaskin, P., et al. (2022) The Oxidative Degradation of Phenol via in Situ H2O2 Synthesis Using Pd Supported Fe-Modified ZSM-5 Catalysts. Catalysis Science & Technology, 12, 2943-2953. [Google Scholar] [CrossRef] 
[32] Erfani, M. and Javanbakht, V. (2018) Methylene Blue Removal from Aqueous Solution by a Biocomposite Synthesized from Sodium Alginate and Wastes of Oil Extraction from Almond Peanut. International Journal of Biological Macromolecules, 114, 244-255. [Google Scholar] [CrossRef] [PubMed]
[33] Radoor, S., Karayil, J., Parameswaranpillai, J. and Siengchin, S. (2020) Removal of Anionic Dye Congo Red from Aqueous Environment Using Polyvinyl Alcohol/Sodium Alginate/ZSM-5 Zeolite Membrane. Scientific Reports, 10, Article No. 15452. [Google Scholar] [CrossRef] [PubMed]
[34] Sabarish, R. and Unnikrishnan, G. (2018) PVA/PDADMAC/ZSM-5 Zeolite Hybrid Matrix Membranes for Dye Adsorption: Fabrication, Characterization, Adsorption, Kinetics and Antimicrobial Properties. Journal of Environmental Chemical Engineering, 6, 3860-3873. [Google Scholar] [CrossRef] 
[35] Sabarish, R. and Unnikrishnan, G. (2018) Polyvinyl Alcohol/Carboxymethyl Cellulose/ZSM-5 Zeolite Biocomposite Membranes for Dye Adsorption Applications. Carbohydrate Polymers, 199, 129-140. [Google Scholar] [CrossRef] [PubMed]
[36] Ünnü, B.A., Gündüz, G. and Dükkancı, M. (2015) Heterogeneous Fenton-Like Oxidation of Crystal Violet Using an Iron Loaded ZSM-5 Zeolite. Desalination and Water Treatment, 57, 11835-11849. [Google Scholar] [CrossRef] 
[37] Sabarish, R., Jasila, K., Aswathy, J., Jyotishkumar, P. and Suchart, S. (2020) Fabrication of PVA/Agar/Modified ZSM-5 Zeolite Membrane for Removal of Anionic Dye from Aqueous Solution. International Journal of Environmental Science and Technology, 18, 2571-2586. [Google Scholar] [CrossRef] 
[38] Gao, J., Lin, Q., Yang, T., Bao, Y.C. and Liu, J. (2023) Preparation and Characterization of ZSM-5 Molecular Sieve Using Coal Gangue as a Raw Material via Solvent-Free Method: Adsorption Performance Tests for Heavy Metal Ions and Methylene Blue. Chemosphere, 341, Article ID: 139741. [Google Scholar] [CrossRef] [PubMed]
[39] Wang, X., Shao, D., Hou, G., Wang, X., Alsaedi, A. and Ahmad, B. (2015) Uptake of Pb(II) and U(VI) Ions from Aqueous Solutions by the ZSM-5 Zeolite. Journal of Molecular Liquids, 207, 338-342. [Google Scholar] [CrossRef] 
[40] Hellal, M.S., Rashad, A.M., Kadimpati, K.K., Attia, S.K. and Fawzy, M.E. (2023) Adsorption Characteristics of Nickel (II) from Aqueous Solutions by Zeolite Scony Mobile-5 (ZSM-5) Incorporated in Sodium Alginate Beads. Scientific Reports, 13, Article No. 19601. [Google Scholar] [CrossRef] [PubMed]
[41] Priyadi, Iskandar, Suwardi, and Mukti, R.R. (2016) Characteristics of Heavy Metals Adsorption Cu, Pb and Cd Using Synthetics Zeolite ZSM-5. Journal of Tropical Soils, 20, 77-83. [Google Scholar] [CrossRef] 
[42] Baile, P., Vidal, L., Aguirre, M.Á. and Canals, A. (2018) A Modified ZSM-5 Zeolite/Fe2O3 Composite as a Sorbent for Magnetic Dispersive Solid-Phase Microextraction of Cadmium, Mercury and Lead from Urine Samples Prior to Inductively Coupled Plasma Optical Emission Spectrometry. Journal of Analytical Atomic Spectrometry, 33, 856-866. [Google Scholar] [CrossRef] 
[43] Zou, X., Zhu, G., Guo, H., Jing, X., Xu, D. and Qiu, S. (2009) Effective Heavy Metal Removal through Porous Stainless-Steel-Net Supported Low Siliceous Zeolite ZSM-5 Membrane. Microporous and Mesoporous Materials, 124, 70-75. [Google Scholar] [CrossRef] 
[44] Syed Ibrahim, G.P., M. Isloor, A., Al Ahmed, A. and Lakshmi, B. (2017) Fabrication and Characterization of Polysulfone-Zeolite ZSM-5 Mixed Matrix Membrane for Heavy Metal Ion Removal Application. Journal of Applied Membrane Science & Technology, 18, 25-37. [Google Scholar] [CrossRef] 
[45] Humpert, D., Ebrahimi, M. and Czermak, P. (2016) Membrane Technology for the Recovery of Lignin: A Review. Membranes, 6, Article 42. [Google Scholar] [CrossRef] [PubMed]
[46] Wen, Y., Xie, Z., Xue, S., Li, W., Ye, H., Shi, W., et al. (2022) Functionalized Polymethyl Methacrylate-Modified Dialdehyde Guar Gum Containing Hydrazide Groups for Effective Removal and Enrichment of Dyes, Ion, and Oil/Water Separation. Journal of Hazardous Materials, 426, Article ID: 127799. [Google Scholar] [CrossRef] [PubMed]
[47] Guo, J. and Ji, Z. (2020) Superhydrophilic ZSM-5 Zeolite-Coated Membrane for Enhancing Water Coalescence in Water-In-Oil Emulsions. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 595, Article ID: 124727. [Google Scholar] [CrossRef] 
[48] Samadi, S., Yazd, S.S., Abdoli, H., Jafari, P. and Aliabadi, M. (2017) Fabrication of Novel Chitosan/Pan/Magnetic ZSM-5 Zeolite Coated Sponges for Absorption of Oil from Water Surfaces. International Journal of Biological Macromolecules, 105, 370-376. [Google Scholar] [CrossRef] [PubMed]
[49] Scheibler, J.R., Santos, E.R.F., Barbosa, A.S. and Rodrigues, M.G.F. (2014) Performance of Zeolite Membrane (ZSM-5/γ-Alumina) in the Oil/Water Separation Process. Desalination and Water Treatment, 56, 3561-3567. [Google Scholar] [CrossRef] 
[50] Elimelech, M. and Phillip, W.A. (2011) The Future of Seawater Desalination: Energy, Technology, and the Environment. Science, 333, 712-717. [Google Scholar] [CrossRef] [PubMed]
[51] Cao, Z., Iskhakova, L., Sun, X., Tang, Z. and Dong, J. (2021) ZSM-5 Zeolite Nanosheet-Based Membranes on Porous Polyvinylidene Fluoride for High-Flux Desalination. ACS Applied Nano Materials, 4, 2895-2902. [Google Scholar] [CrossRef] 
[52] Ziyi, L., Enze, P., Jiaxuan, W., et al. (2021) Preparation of ZSM-5 Zeolite Membrane and Its Application in Desalination. CIESC Journal, 72, 5247-5256.
[53] 李子祎, 潘恩泽, 王佳轩, 等. ZSM-5沸石分子筛膜的制备及脱盐性能研究[J]. 化工学报, 2021, 72(10): 5247-5256.
[54] Kumar, R.V., Goswami, L., Pakshirajan, K. and Pugazhenthi, G. (2016) Dairy Wastewater Treatment Using a Novel Low Cost Tubular Ceramic Membrane and Membrane Fouling Mechanism Using Pore Blocking Models. Journal of Water Process Engineering, 13, 168-175. [Google Scholar] [CrossRef] 

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