面向胺基CO2捕集工艺的吸收剂评价和过程强化
Evaluation of Absorbents and Process Intensification for Amine-Based CO2 Capture Processes
摘要: 降低吸收剂再生能耗是提升胺基吸收剂CO2捕集技术工业化应用潜力的主要任务之一。针对常规胺基吸收剂在CO2捕集过程中再生能耗高的原因，综述了CO2捕集过程强化和胺基相变吸收剂的节能研究进展。研究结论表明：过程强化是通过回收利用汽化潜热和吸收剂显热以达到降低再生能耗的目的，胺基相变吸收剂则是减少吸收剂解吸量以降低再生能耗。随着新型吸收剂的开发，先进吸收剂与工艺强化间的匹配性研究将成为未来CO2捕集技术研究的重要方向。
Abstract: Reducing the regeneration energy consumption is one of the main tasks to enhance the industrial application potential of amine-based absorbent CO2 capture technology. For problem of high regeneration energy consumption for conventional amine-based absorbents CO2 capture process, the research progress of CO2 capture process improvement and amine-based phase change absorbents for energy saving was reviewed. The research conclusion showed that the regeneration energy consumption can be reduced through process improvement to recover the vaporization latent heat and sensible heat of absorbent. Regeneration energy consumption can be reduced by reducing the amount of phase change absorbents desorption. With the development of new absorbents, the matching research between advanced absorbent and process improvement will become the development direction of CO2 capture technology in the future.
文章引用：王伟, 李亚珍, 闫宏宇, 宋婷婷, 王兆文. 面向胺基CO2捕集工艺的吸收剂评价和过程强化[J]. 化学工程与技术, 2024, 14(6): 440-448. https://doi.org/10.12677/hjcet.2024.146047

参考文献

[1] 陆诗建, 黄凤敏, 李清方, 等. 燃烧后CO2捕集技术与工程进展[J]. 现代化工, 2015, 35(6): 48-52.
[2] 晏水平, 方梦祥, 张卫风, 等. 烟气中CO2化学吸收法脱除技术分析与进展[J]. 化工进展, 2006, 25(9): 1018-1025.
[3] 平甜甜, 尹鑫, 董玉, 等. 有机胺非水溶液吸收CO2的动力学研究进展[J]. 化工学报, 2021, 72(8): 3968-3983.
[4] Chu, F., Yang, L., Du, X. and Yang, Y. (2016) CO2 Capture Using MEA (Monoethanolamine) Aqueous Solution in Coal-Fired Power Plants: Modeling and Optimization of the Absorbing Columns. Energy, 109, 495-505. [Google Scholar] [CrossRef] 
[5] 郑园园. N-甲基二乙醇胺吸收CO2的热力学模型研究[J]. 气体净化, 2015, 15(3): 23-27.
[6] Bishnoi, S. and Rochelle, G.T. (2000) Absorption of Carbon Dioxide into Aqueous Piperazine: Reaction Kinetics, Mass Transfer and Solubility. Chemical Engineering Science, 55, 5531-5543. [Google Scholar] [CrossRef] 
[7] Svensson, H., Hulteberg, C. and Karlsson, H.T. (2013) Heat of Absorption of CO2 in Aqueous Solutions of N-Methyldiethanolamine and Piperazine. International Journal of Greenhouse Gas Control, 17, 89-98. [Google Scholar] [CrossRef] 
[8] Bishnoi, S. and Rochelle, G.T. (2002) Absorption of Carbon Dioxide in Aqueous Piperazine/Methyldiethanolamine. AIChE Journal, 48, 2788-2799. [Google Scholar] [CrossRef] 
[9] Mangalapally, H.P. and Hasse, H. (2011) Pilot Plant Study of Two New Solvents for Post Combustion Carbon Dioxide Capture by Reactive Absorption and Comparison to Monoethanolamine. Chemical Engineering Science, 66, 5512-5522. [Google Scholar] [CrossRef] 
[10] Kadiwala, S., Rayer, A.V. and Henni, A. (2012) Kinetics of Carbon Dioxide (CO2) with Ethylenediamine, 3-Amino-1-Propanol in Methanol and Ethanol, and with 1-Dimethylamino-2-Propanol and 3-Dimethylamino-1-Propanol in Water Using Stopped-Flow Technique. Chemical Engineering Journal, 179, 262-271. [Google Scholar] [CrossRef] 
[11] Liang, Y., Liu, H., Rongwong, W., Liang, Z., Idem, R. and Tontiwachwuthikul, P. (2015) Solubility, Absorption Heat and Mass Transfer Studies of CO2 Absorption into Aqueous Solution of 1-Dimethylamino-2-Propanol. Fuel, 144, 121-129. [Google Scholar] [CrossRef] 
[12] Zhou, X., Jing, G., Lv, B., Liu, F. and Zhou, Z. (2019) Low-Viscosity and Efficient Regeneration of Carbon Dioxide Capture Using a Biphasic Solvent Regulated by 2-Amino-2-Methyl-1-Propanol. Applied Energy, 235, 379-390. [Google Scholar] [CrossRef] 
[13] 陈东良, 张忠林, 杨景轩, 等. 基于自热再生的化学吸收法CO2捕集工艺模拟及节能分析[J]. 化工学报, 2019, 70(8): 2938-2945.
[14] Plaza, J.M., Van Wagener, D. and Rochelle, G.T. (2010) Modeling CO2 Capture with Aqueous Monoethanolamine. International Journal of Greenhouse Gas Control, 4, 161-166. [Google Scholar] [CrossRef] 
[15] Li, K., Cousins, A., Yu, H., Feron, P., Tade, M., Luo, W., et al. (2015) Systematic Study of Aqueous Monoethanolamine‐based CO2 Capture Process: Model Development and Process Improvement. Energy Science & Engineering, 4, 23-39. [Google Scholar] [CrossRef] 
[16] Baburao, B. and Schuber, C. (2013) Advanced Intercooling and Recycling in CO2 Absorption: US2011/0168020.
[17] Marafi, M., Stanislaus, A. and Furimsky, E. (2017) Handbook of Spent Hydroprocessing Catalysts. Elsevier.
[18] Jin, H., Liu, P. and Li, Z. (2021) Impact of Solvent Properties on Post-Combustion Carbon Capture Processes: A Vapor-Liquid Equilibrium Modelling Approach. Chemical Engineering Science: X, 10, Article 100095. [Google Scholar] [CrossRef] 
[19] 李小飞, 王淑娟, 陈昌和. 胺法脱碳系统流程改进及优化模拟[J]. 化工学报, 2013, 64(10): 3750-3759.
[20] Zhao, B., Liu, F., Cui, Z., Liu, C., Yue, H., Tang, S., et al. (2017) Enhancing the Energetic Efficiency of MDEA/PZ-Based CO2 Capture Technology for a 650 MW Power Plant: Process Improvement. Applied Energy, 185, 362-375. [Google Scholar] [CrossRef] 
[21] Jassim, M.S. and Rochelle, G.T. (2005) Innovative Absorber/stripper Configurations for CO2 Capture by Aqueous Monoethanolamine. Industrial & Engineering Chemistry Research, 45, 2465-2472. [Google Scholar] [CrossRef] 
[22] Ahn, H., Luberti, M., Liu, Z. and Brandani, S. (2013) Process Configuration Studies of the Amine Capture Process for Coal-Fired Power Plants. International Journal of Greenhouse Gas Control, 16, 29-40. [Google Scholar] [CrossRef] 
[23] Xue, B., Yu, Y., Chen, J., Luo, X. and Wang, M. (2016) A Comparative Study of MEA and DEA for Post-Combustion CO2 Capture with Different Process Configurations. International Journal of Coal Science & Technology, 4, 15-24. [Google Scholar] [CrossRef] 
[24] Wang, D., Li, J., Meng, W., Wang, J., Wang, K., Zhou, H., et al. (2022) Integrated Process for Producing Glycolic Acid from Carbon Dioxide Capture Coupling Green Hydrogen. Processes, 10, Article 1610. [Google Scholar] [CrossRef] 
[25] Lv, B., Zhou, X., Zhou, Z. and Jing, G. (2019) Kinetics and Thermodynamics of CO2 Absorption into a Novel DETA-AMP-PMDETA Biphasic Solvent. ACS Sustainable Chemistry & Engineering, 7, 13400-13410. [Google Scholar] [CrossRef] 
[26] Liu, F., Fang, M., Dong, W., Wang, T., Xia, Z., Wang, Q., et al. (2019) Carbon Dioxide Absorption in Aqueous Alkanolamine Blends for Biphasic Solvents Screening and Evaluation. Applied Energy, 233, 468-477. [Google Scholar] [CrossRef] 
[27] Wang, R., Liu, S., Wang, L., Li, Q., Zhang, S., Chen, B., et al. (2019) Superior Energy-Saving Splitter in Monoethanolamine-Based Biphasic Solvents for CO2 Capture from Coal-Fired Flue Gas. Applied Energy, 242, 302-310. [Google Scholar] [CrossRef] 
[28] Wang, L., Yu, S., Li, Q., Zhang, Y., An, S. and Zhang, S. (2018) Performance of Sulfolane/Deta Hybrids for CO2 Absorption: Phase Splitting Behavior, Kinetics and Thermodynamics. Applied Energy, 228, 568-576. [Google Scholar] [CrossRef] 
[29] Ye, J., Jiang, C., Chen, H., Shen, Y., Zhang, S., Wang, L., et al. (2019) Novel Biphasic Solvent with Tunable Phase Separation for CO2 Capture: Role of Water Content in Mechanism, Kinetics, and Energy Penalty. Environmental Science & Technology, 53, 4470-4479. [Google Scholar] [CrossRef] [PubMed]
[30] Wang, L., Zhang, Y., Wang, R., Li, Q., Zhang, S., Li, M., et al. (2018) Advanced Monoethanolamine Absorption Using Sulfolane as a Phase Splitter for CO2 Capture. Environmental Science & Technology, 52, 14556-14563. [Google Scholar] [CrossRef] [PubMed]
[31] Zhang, J., Qiao, Y. and Agar, D.W. (2012) Intensification of Low Temperature Thermomorphic Biphasic Amine Solvent Regeneration for CO2 Capture. Chemical Engineering Research and Design, 90, 743-749. [Google Scholar] [CrossRef] 
[32] Raynal, L., Alix, P., Bouillon, P., Gomez, A., de Nailly, M.F., Jacquin, M., et al. (2011) The DMX™ Process: An Original Solution for Lowering the Cost of Post-Combustion Carbon Capture. Energy Procedia, 4, 779-786. [Google Scholar] [CrossRef]