我国地下水中新型污染物的研究进展
Research Progress in the Emerging Contaminants in Groundwater in China
DOI: 10.12677/japc.2024.134074, PDF,    国家自然科学基金支持
作者: 曹果宜, 张 影, 石 健*:南通大学交通与土木工程学院,江苏 南通;秦 娟*:南通大学化学化工学院,江苏 南通
关键词: 新型污染物地下水分布监测检测Emerging Contaminants Groundwater Distribution Monitoring Detection Technology
摘要: 随着工业化和技术进步,新型污染物日益增多,对地下水环境和人类健康造成显著影响。本文聚焦于我国地下水中的新型污染物,探讨了它们的分类、特性及其对人类健康的潜在危害;重点阐述了我国地下水中典型新型污染物的分布规律,并指出我国东南部和发达城市地下水中新型污染物的检出率较高,与地区经济发展水平呈正相关关系;概述了我国在新型污染物监管制度建设和检测技术方面的现状,强调地下水污染监管机制亟待完善,监测技术和科学研究能力亟需提升。本文旨在为地下水中新型污染物的监测、管理和防控提供科学依据和参考方向,以有效应对新型污染物带来的挑战。
Abstract: With the progress in industrial and technological development, the number of emerging contaminants has increased, affecting the groundwater environment and human health. This paper focused on the emerging contaminants in groundwater in China, and discussed their classification, characteristics, and potential health risks. It specifically emphasized the distribution of typical emerging contaminants in groundwater in China. It was found that the detection rate of emerging contaminants in the groundwater of Southeast China and developed cities is relatively high, with a positive correlation observed between economic development levels and contaminant concentrations. It also summarized the current system and detection technologies for emerging contaminants in China, and emphasized the urgent need to enhance the control of groundwater pollution and the capability of monitoring and research. This paper offered a scientific basis and strategies for monitoring, managing, and controlling emerging contaminants in groundwater to tackle associated challenges.
文章引用:曹果宜, 张影, 石健, 秦娟. 我国地下水中新型污染物的研究进展[J]. 物理化学进展, 2024, 13(4): 741-749. https://doi.org/10.12677/japc.2024.134074

参考文献

[1] Naidu, R., Biswas, B., Willett, I.R., Cribb, J., Kumar Singh, B., Paul Nathanail, C., et al. (2021) Chemical Pollution: A Growing Peril and Potential Catastrophic Risk to Humanity. Environment International, 156, Article 106616. [Google Scholar] [CrossRef] [PubMed]
[2] Sørensen, M., Møller, B.L., et al. (2021) Metabolic Engineering of Photosynthetic Cells in Collaboration with Nature. Metabolic Engineering: Concepts and Applications, 13, 803-857.
[3] Arman, N.Z., Salmiati, S., Aris, A., Salim, M.R., Nazifa, T.H., Muhamad, M.S., et al. (2021) A Review on Emerging Pollutants in the Water Environment: Existences, Health Effects and Treatment Processes. Water, 13, Article 3258. [Google Scholar] [CrossRef
[4] Yang, M., Yi, J., Wei, C., Lu, Y., Yang, Y., Yang, Z., et al. (2023) Determination of Human Epidermal Growth Factor in Cosmetics by Solid Phase Extraction (SPE) with High-Performance Liquid Chromatography—Tandem Mass Spectrometry (HPLC-MS/MS). Analytical Letters, 57, 1704-1714. [Google Scholar] [CrossRef
[5] Egbuna, C., Amadi, C.N., Patrick-Iwuanyanwu, K.C., Ezzat, S.M., Awuchi, C.G., Ugonwa, P.O., et al. (2021) Emerging Pollutants in Nigeria: A Systematic Review. Environmental Toxicology and Pharmacology, 85, Article 103638. [Google Scholar] [CrossRef] [PubMed]
[6] 王毅. 水环境中新型有机污染物高通量筛查研究[D]: [博士学位论文]. 南京: 南京大学, 2019.
[7] 陈亚杰. 地下水水质分析及水污染治理措施[J]. 石材, 2024(10): 6-8.
[8] 张一清, 郭珊珊, 孙倩. 冷冻干燥技术在环境水样有机新污染物前处理中的应用进展[J]. 色谱, 2021, 39(8): 827-834.
[9] Bunke, D., Moritz, S., Brack, W., Herráez, D.L., Posthuma, L. and Nuss, M. (2019) Developments in Society and Implications for Emerging Pollutants in the Aquatic Environment. Environmental Sciences Europe, 31, Article No. 32. [Google Scholar] [CrossRef
[10] Gondi, R., Kavitha, S., Yukesh Kannah, R., Parthiba Karthikeyan, O., Kumar, G., Kumar Tyagi, V., et al. (2022) Algal-based System for Removal of Emerging Pollutants from Wastewater: A Review. Bioresource Technology, 344, Article 126245. [Google Scholar] [CrossRef] [PubMed]
[11] Jian, L., Han, J., Wen, H., Shen, Y., Zhang, K., Yu, L., et al. (2024) Rapid Determination of 111 Anti-Infective Drugs Possibly Added in Cosmetics Using High-Performance Liquid Chromatography-Tandem Mass Spectrometry with Scheduled Multiple Reaction Monitoring. Rapid Communications in Mass Spectrometry, 38, e9778. [Google Scholar] [CrossRef] [PubMed]
[12] Shahid, M.K., Kashif, A., Fuwad, A. and Choi, Y. (2021) Current Advances in Treatment Technologies for Removal of Emerging Contaminants from Water—A Critical Review. Coordination Chemistry Reviews, 442, Article 213993. [Google Scholar] [CrossRef
[13] Yang, J., Zhao, Y., Li, M., Du, M., Li, X. and Li, Y. (2019) A Review of a Class of Emerging Contaminants: The Classification, Distribution, Intensity of Consumption, Synthesis Routes, Environmental Effects and Expectation of Pollution Abatement to Organophosphate Flame Retardants (OPFRs). International Journal of Molecular Sciences, 20, Article 2874. [Google Scholar] [CrossRef] [PubMed]
[14] Pereira, L.C., de Souza, A.O., Bernardes, M.F.F., Pazin, M., Tasso, M.J., Pereira, P.H., et al. (2015) A Perspective on the Potential Risks of Emerging Contaminants to Human and Environmental Health. Environmental Science and Pollution Research, 22, 13800-13823. [Google Scholar] [CrossRef] [PubMed]
[15] Fenton, S.E., Ducatman, A., Boobis, A., DeWitt, J.C., Lau, C., Ng, C., et al. (2020) Per and Polyfluoroalkyl Substance Toxicity and Human Health Review: Current State of Knowledge and Strategies for Informing Future Research. Environmental Toxicology and Chemistry, 40, 606-630. [Google Scholar] [CrossRef] [PubMed]
[16] 邵一先. 郭庄泉岩溶水系统中多环芳烃的分布与归趋研究[D]: [博士学位论文]. 北京: 中国地质大学, 2014.
[17] Dong, W., Xie, W., Su, X., Wen, C., Cao, Z. and Wan, Y. (2018) Review: Micro-Organic Contaminants in Groundwater in China. Hydrogeology Journal, 26, 1351-1369. [Google Scholar] [CrossRef
[18] 黄冠星, 孙继朝, 等. 珠江三角洲地下水有机氯农药分布特征的初探[J]. 农业环境科学学报, 2008, 27(4): 1471-1475.
[19] 孔祥胜, 苗迎, 等. 南宁市朝阳溪岸边地下水持久性有机污染物的污染特征[J]. 地球与环境, 2016, 44(4): 406-413.
[20] 俞光明, 刘红樱, 等. 杭州市浅层地下水有机污染及其风险初步评价[J]. 资源调查与环境, 2007, 28(3): 198-204.
[21] 刘菲. 地下水系统中的新污染物[J]. 水文地质工程地质, 2024, 51(2): 1-2.
[22] 徐昕, 孙玉川, 等. 重庆老龙洞地下河流域水体有机氯农药污染及来源初步研究[J]. 中国岩溶, 2013, 32(2): 189-194.
[23] 韦丽丽, 郭芳, 等. 柳州岩溶地下河水体有机氯农药分布特征[J]. 中国岩溶, 2011, 30(1): 16-21.
[24] 张俊鹏, 祁士华, 等. 广西岩溶地下河水体中有机氯农药浓度分布特征研究[J]. 环境污染与防治, 2011, 33(4): 54-57.
[25] 胡英, 祁士华, 等. 岩溶地下河中HCHs和DDTs的分布特征与健康风险评价[J]. 中国环境科学, 2010, 30(6): 802-807.
[26] 孙玉川. 有机氯农药和多环芳烃在表层岩溶系统中的迁移、转化特征研究[D]: [博士学位论文]. 重庆: 西南大学, 2012.
[27] An, R., Li, B., Zhong, S., Peng, G., Li, J., Ma, R., et al. (2023) Distribution, Source Identification, and Health Risk of Emerging Organic Contaminants in Groundwater of Xiong’an New Area, Northern China. Science of the Total Environment, 893, Article 164786. [Google Scholar] [CrossRef] [PubMed]
[28] Conesa, J.A., Nuñez, S.S., Ortuño, N. and Moltó, J. (2021) PAH and POP Presence in Plastic Waste and Recyclates: State of the Art. Energies, 14, Article 3451. [Google Scholar] [CrossRef
[29] 王程, 刘慧, 蔡鹤生, 等. 武汉市地下水中酞酸酯污染物检测及来源分析[J]. 环境科学与技术, 2009, 32(10): 118-123.
[30] 李建忠. 典型内分泌干扰物在土壤中迁移转化规律研究[D]: [博士学位论文]. 北京: 清华大学, 2013.
[31] Jiang, J., Zhou, Z. and Sharma, V.K. (2013) Occurrence, Transportation, Monitoring and Treatment of Emerging Micro-Pollutants in Waste Water—A Review from Global Views. Microchemical Journal, 110, 292-300. [Google Scholar] [CrossRef
[32] Shahid, M.K., Kashif, A., Fuwad, A. and Choi, Y. (2021) Current Advances in Treatment Technologies for Removal of Emerging Contaminants from Water—A Critical Review. Coordination Chemistry Reviews, 442, Article 213993. [Google Scholar] [CrossRef
[33] Li, Z., Xiang, X., Li, M., Ma, Y., Wang, J. and Liu, X. (2015) Occurrence and Risk Assessment of Pharmaceuticals and Personal Care Products and Endocrine Disrupting Chemicals in Reclaimed Water and Receiving Groundwater in China. Ecotoxicology and Environmental Safety, 119, 74-80. [Google Scholar] [CrossRef] [PubMed]
[34] 丁紫荣. 珠三角地区典型污染源及地下水中药物与个人护理品的分布特征研究[D]: [博士学位论文]. 长沙: 湖南师范大学, 2016.
[35] Peng, X., Ou, W., Wang, C., Wang, Z., Huang, Q., Jin, J., et al. (2014) Occurrence and Ecological Potential of Pharmaceuticals and Personal Care Products in Groundwater and Reservoirs in the Vicinity of Municipal Landfills in China. Science of the Total Environment, 490, 889-898. [Google Scholar] [CrossRef] [PubMed]
[36] 周爱霞. 潜水中磺胺抗生素迁移转化机理及修复技术研究[D]: [博士学位论文]. 长春: 吉林大学, 2015.
[37] Sandoval, M.A., Calzadilla, W., Vidal, J., Brillas, E. and Salazar-González, R. (2024) Contaminants of Emerging Concern: Occurrence, Analytical Techniques, and Removal with Electrochemical Advanced Oxidation Processes with Special Emphasis in Latin America. Environmental Pollution, 345, Article 123397. [Google Scholar] [CrossRef] [PubMed]
[38] Farré, M., Kantiani, L., Petrovic, M., Pérez, S. and Barceló, D. (2012) Achievements and Future Trends in the Analysis of Emerging Organic Contaminants in Environmental Samples by Mass Spectrometry and Bioanalytical Techniques. Journal of Chromatography A, 1259, 86-99. [Google Scholar] [CrossRef] [PubMed]
[39] Jakimska, A., Kot-Wasik, A. and Namieśnik, J. (2014) The Current State-of-the-Art in the Determination of Pharmaceutical Residues in Environmental Matrices Using Hyphenated Techniques. Critical Reviews in Analytical Chemistry, 44, 277-298. [Google Scholar] [CrossRef] [PubMed]
[40] Patel, M., Kumar, R., Kishor, K., Mlsna, T., Pittman, C.U. and Mohan, D. (2019) Pharmaceuticals of Emerging Concern in Aquatic Systems: Chemistry, Occurrence, Effects, and Removal Methods. Chemical Reviews, 119, 3510-3673. [Google Scholar] [CrossRef] [PubMed]
[41] Chen, X., Bian, Z., Hou, H., Yang, F., Liu, S., Tang, G., et al. (2013) Development and Validation of a Method for the Determination of 159 Pesticide Residues in Tobacco by Gas Chromatography-Tandem Mass Spectrometry. Journal of Agricultural and Food Chemistry, 61, 5746-5757. [Google Scholar] [CrossRef] [PubMed]
[42] 王舒婷, 吴学勇, 牛学奎, 等. 地下水中新型有机污染物的识别与去除研究进展[J]. 云南化工, 2022, 49(11): 23-25.
[43] Edwards, M.A., Kimbrough, K., et al. (2024) An Assessment and Characterization of Pharmaceuticals and Personal Care Products (PPCPs) within the Great Lakes Basin: Mussel Watch Program (2013-2018). Environmental Monitoring and Assessment, 196, Article 345.
[44] Wille, K., De Brabander, H.F., Vanhaecke, L., De Wulf, E., Van Caeter, P. and Janssen, C.R. (2012) Coupled Chromatographic and Mass-Spectrometric Techniques for the Analysis of Emerging Pollutants in the Aquatic Environment. TrAC Trends in Analytical Chemistry, 35, 87-108. [Google Scholar] [CrossRef
[45] 李洪达. 新型固相微萃取纤维结合气相色谱检测环境样品中的多环芳烃类和硝基苯类污染物[D]: [硕士学位论文]. 保定: 河北农业大学, 2021.
[46] Carmona, E. and Picó, Y. (2018) The Use of Chromatographic Methods Coupled to Mass Spectrometry for the Study of Emerging Pollutants in the Environment. Critical Reviews in Analytical Chemistry, 48, 305-316. [Google Scholar] [CrossRef] [PubMed]
[47] Liu, J., Zhang, H., Ai, L., Wei, X. and Wang, J. (2024) Ultra-High Performance Liquid Chromatography Tandem Mass Spectrometry for the Determination of 21 Β-Blockers in Animal-Derived Foods. Journal of Food Composition and Analysis, 133, Article 106340. [Google Scholar] [CrossRef
[48] Kosić-Vukšić, J., Krivohlavek, A., Žuntar, I., Pocrnić, M. and Galić, N. (2024) Undeclared Phosphodiesterase Type 5 Inhibitors (PDE5Is) in Food Supplements on the Croatian Market Analyzed by Liquid Chromatography Time-of-Flight Mass Spectrometry (LC-QTOF-MS). Microchemical Journal, 203, Article 110917. [Google Scholar] [CrossRef
[49] Thangarathinam, K., Narayanan, M., Kumar KS, A., Arjunan, B. and Raja, D.B. (2024) Single Method for Determination of Biocides Benzalkonium Chloride, Chloroxylenol and Chlorhexidine Gluconate in Cosmetics, Hygiene and Health Care Products by Using High Performance Liquid Chromatography. Journal of Chromatographic Science, 62, 837-844. [Google Scholar] [CrossRef] [PubMed]