过渡金属Zn2+表面修饰Ti3C2Tx Mxene构筑高性能超级电容器负极
Surface Modification of Ti₃C2Tₓ MXene with Transition Metal Zn2+ for Constructing High-Performance Supercapacitor Negative Electrodes
DOI: 10.12677/ms.2026.163054, PDF,   
作者: 杨力豪:哈尔滨师范大学物理与电子工程学院,黑龙江 哈尔滨
关键词: 超级电容器;负极;Ti3C2Tx;插层;表面修饰;Supercapacitor; Anode Material for Supercapacitors; Ti3C2Tx; Intercalation; Surface Modification
摘要: Ti3C2Tx Mxene因其独特的理化特性,被广泛认为是高性能超级电容器的有前景的负极材料。然而,其储能潜力受限于固有缺陷,如层间堆叠问题及存在不利的-F表面端基。本研究报道了一种调控并提升Ti3C2Tx电化学性能的表面修饰策略。采用离子交换法将Zn2+离子嵌入Ti3C2Tx的层间间隙,有效扩展了离子扩散路径并暴露更多活性位点。经此结构调控后,所得Ti3C2Tx-Zn薄膜电极在1 A·g−1的电流密度下比电容高达361 F·g−1,较原始Ti3C2Tx薄膜电极(242 F·g−1)提升1.43倍;电流密度升至20 A·g−1时电容保持率为85%,10 A·g−1电流密度下1万次循环后容量保持率高达99.8%,展现出优异倍率性能与良好的循环稳定性。本研究通过层间工程优化Ti3C2Tx表面组分与结构,为过渡金属离子表面修饰MXene材料在超级电容器中的应用提供了科学依据与技术参考。
Abstract: Ti3C2Tx Mxene, with its distinctive physicochemical properties, is widely regarded as a promising anode material for high-performance supercapacitors. However, its energy storage potential is limited by inherent shortcomings, such as interlayer restacking and the presence of unfavorable –F surface terminations. This study reports a surface modification strategy aimed at regulating and improving the electrochemical performance of Ti3C2Tx. Through an ion-exchange approach, Zn2+ ions were intercalated into the interlayer gaps of Ti3C2Tx, effectively enlarging the ion diffusion pathways and exposing more active sites. After this structural modification, the resulting Ti3C2Tx-Zn film electrode delivered a high specific capacitance of 361  F·g−1 at a current density of 1  A·g−1, which is 1.43 times that of the pristine Ti3C2Tx film electrode (242  F·g−1). The electrode also exhibited superior rate capability with 85% capacitance retention at 20  A·g−1, as well as excellent cycling stability with 99.8% capacitance retention after 10,000 cycles at 10  A·g−1. This work demonstrates that interlayer engineering can effectively optimize the surface composition and structure of Ti3C2Tx, providing scientific and technical insights into the application of transition-metal-ion surface modification of MXene materials in supercapacitors.
文章引用:杨力豪. 过渡金属Zn2+表面修饰Ti3C2Tx Mxene构筑高性能超级电容器负极[J]. 材料科学, 2026, 16(3): 85-92. https://doi.org/10.12677/ms.2026.163054

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