缺陷与掺杂调控对CsPbI3钙钛矿太阳能电池光电性能的影响
Effects of Defect and Doping Regulation on the Optoelectronic Performance of CsPbI3 Perovskite Solar Cells
DOI: 10.12677/aepe.2026.142010, PDF,    科研立项经费支持
作者: 王 希*, 陈金耀, 陈卓妍, 丁熙娅, 张 馨, 刘邦震:兴义民族师范学院,物理与工程技术学院,贵州 兴义;王传坤#:兴义民族师范学院,物理与工程技术学院,贵州 兴义;黔西南州微纳功能材料重点实验室,贵州 兴义
关键词: 钙钛矿层掺杂浓度界面缺陷SCAPS-1D软件Perovskite Layer Doping Concentration Interfacial Defect SCAPS-1D Software
摘要: 利用SCAPS-1D软件构建glass/FTO/PCBM/CsPbI3/GO/Au钙钛矿太阳能电池结构。通过该软件研究了钙钛矿层缺陷密度,GO掺杂浓度以及GO/CsPbI3、CsPbI3/PCBM界面缺陷对器件性能的影响。优化后器件的光电转换效率为24.79%,通过理论研究为提高钙钛矿太阳能电池的光电效率提供了理论支持。
Abstract: The glass/FTO/PCBM/CsPbI₃/GO/Au perovskite solar cell structure was constructed by the SCAPS-1D software. The effects of defect density of the perovskite layer, GO doping concentration, and interfacial defects at GO/CsPbI₃ and CsPbI₃/PCBM on the device performance were systematically investigated via this software. The optimized device achieves a photoelectric conversion efficiency (PCE) of 24.79%. This theoretical study provides a reliable theoretical basis for the efficiency enhancement of perovskite solar cells.
文章引用:王希, 陈金耀, 陈卓妍, 丁熙娅, 张馨, 刘邦震, 王传坤. 缺陷与掺杂调控对CsPbI3钙钛矿太阳能电池光电性能的影响[J]. 电力与能源进展, 2026, 14(2): 86-93. https://doi.org/10.12677/aepe.2026.142010

参考文献

[1] Husainat, A., Ali, W., Cofie, P., Attia, J. and Fuller, J. (2019) Simulation and Analysis of Methylammonium Lead Iodide (CH3NH3PbI3) Perovskite Solar Cell with Au Contact Using SCAPS 1D Simulator. American Journal of Optics and Photonics, 7, 33-40. [Google Scholar] [CrossRef
[2] Nalianya, M.A., Awino, C., Barasa, H., Odari, V., Gaitho, F., Omogo, B., et al. (2021) Numerical Study of Lead Free CsSn0.5Ge0.5I3 Perovskite Solar Cell by SCAPS-1D. Optik, 248, Article ID: 168060. [Google Scholar] [CrossRef
[3] Sunny, A., Rahman, S., Khatun, M.M. and Ahmed, S.R.A. (2021) Numerical Study of High Performance HTL-Free CH3NH3SnI3-Based Perovskite Solar Cell by SCAPS-1D. AIP Advances, 11, Article ID: 065102. [Google Scholar] [CrossRef
[4] Karthick, K., Suresh, S., Hussain, M.M.M.D., Ali, H.M. and Kumar, C.S.S. (2019) Evaluation of Solar Thermal System Configurations for Thermoelectric Generator Applications: A Critical Review. Solar Energy, 188, 111-142. [Google Scholar] [CrossRef
[5] 索鑫磊, 刘艳, 张立来, 等. 基于氧化石墨烯空穴传输层的平面异质结钙钛矿太阳能电池[J]. 材料导报, 2021, 35(6): 6015-6019.
[6] 赵大伟, 李铭, 戴世杰, 等. 共轭聚合物-氧化石墨烯钝化材料改善钙钛矿太阳能电池性能[J]. 科学通报, 2020, 65(32): 3593-3601.
[7] 许湘晨. 利用乙二醇修饰石墨烯应用于柔性钙钛矿太阳能电池[D]: [硕士学位论文]. 长春: 吉林大学, 2020.
[8] 范心怡. 石墨烯修饰钙钛矿太阳能电池电极材料及其增效研究[D]: [硕士学位论文]. 上海: 上海工程技术大学, 2021.
[9] Deepthi Jayan, K. and Sebastian, V. (2021) Comprehensive Device Modelling and Performance Analysis of MASnI3 Based Perovskite Solar Cells with Diverse ETM, HTM and Back Metal Contacts. Solar Energy, 217, 40-48. [Google Scholar] [CrossRef
[10] Dhivya Bharathi, C. and Sriramalakshmi, P. (2025) Simulation of Lead Free Heterojunction N-FASnI3/p-FrGeCl3 Based Perovskite Solar Cell with ZnMgO as Electron Transport Layer and GO as Hole Transport Layer Using SCAPS-1D. Results in Engineering, 27, Article ID: 106180. [Google Scholar] [CrossRef
[11] Zhang, A. and Duan, R. (2023) Design and Numerical Investigation of CsPbI3/CsSn0.5Ge0.5I3 Double‐Absorption‐Layer Heterojunction Perovskite Solar Cells Based on SCAPS‐1D. Physica Status Solidi (a), 220, Article ID: 2300525. [Google Scholar] [CrossRef
[12] Hossain, M.K., Rubel, M.H.K., Toki, G.F.I., Alam, I., Rahman, M.F. and Bencherif, H. (2022) Effect of Various Electron and Hole Transport Layers on the Performance of Cspbi3-Based Perovskite Solar Cells: A Numerical Investigation in DFT, SCAPS-1D, and wxAMPS Frameworks. ACS Omega, 7, 43210-43230. [Google Scholar] [CrossRef] [PubMed]
[13] 黄孝坤, 杨爱军, 黎健生, 等. 基于CuS空穴传输材料的钙钛矿电池的性能研究[J]. 人工晶体学报, 2023, 52(3): 485-492.
[14] He, B., Xu, Y., Zhu, J. and Zhang, X. (2021) Effects of the Doping Density of Charge-Transporting Layers on Regular and Inverted Perovskite Solar Cells: Numerical Simulations. Advanced Composites and Hybrid Materials, 4, 1146-1154. [Google Scholar] [CrossRef
[15] 姚广平, 文超, 刘佳澎, 等. 缺陷对全无机钙钛矿太阳能电池性能的影响[J]. 发光学报, 2023, 44(11): 2033-2040.
[16] 程友良, 寇雪宁, 张忠宝, 等. 以CZTS为空穴传输层的固态染料敏化太阳能电池的性能模拟与优化[J]. 复合材料学报, 2026, 43(4): 2173-2185.