生物炭改性技术及其吸附典型气态污染物研究
Research on Biochar Modification Technologies and Their Adsorption of Typical Gaseous Pollutants
DOI: 10.12677/aep.2026.164062, PDF,    科研立项经费支持
作者: 谢雨欣, 薛竣捷, 李佳旭, 汤媛媛, 陶育壮, 李思彤, 曹澄澄*:徐州工程学院环境工程学院,江苏 徐州
关键词: 生物炭改性技术气态污染物吸附孔隙结构Biochar Modification Technology Gaseous Pollutants Adsorption Pore Structure
摘要: 大气污染治理至关重要,VOCs、SO2、H2S、NH3等气态污染物严重危害生态环境与人体健康。吸附法是低浓度气态污染物治理的主流技术,生物炭兼具固碳与治污功能,但原生生物炭吸附性能有限,改性技术是突破其瓶颈的关键。本文梳理了物理、化学、生物及组合改性方法,总结了生物炭的改性效果,分析了改性生物炭对四种典型气态污染物的吸附规律与机理。研究表明,改性生物炭吸附性能提升依赖“孔隙优化 + 活性位点增加”的协同作用,不同改性方法可针对性强化生物炭对污染物的吸附能力。本文可为改性生物炭绿色制备、性能优化及规模化应用提供理论参考,为生物质高值化利用和“双碳”目标实现提供新思路。
Abstract: Atmospheric pollution control is of vital importance, as gaseous pollutants such as VOCs, SO2, H2S, NH3 pose severe hazards to the ecological environment and human health. Adsorption is the mainstream technology for treating low-concentration gaseous pollutants. Biochar has both carbon sequestration and pollution control functions, yet the adsorption performance of raw biochar is limited, and modification technologies are the key to breaking this bottleneck. This paper combs physical, chemical, biological and combined modification methods, summarizes the modification effects of biochar, and analyzes the adsorption rules and mechanisms of modified biochar on four typical gaseous pollutants. The results show that the improvement of adsorption performance of modified biochar relies on the synergistic effect of “pore optimization + active site increase”, and different modification methods can targetedly enhance the adsorption capacity of biochar for pollutants. This study can provide a theoretical reference for the green preparation, performance optimization and large-scale application of modified biochar, and offer new ideas for the high-value utilization of biomass and the achievement of the “Dual-Carbon” goals.
文章引用:谢雨欣, 薛竣捷, 李佳旭, 汤媛媛, 陶育壮, 李思彤, 曹澄澄. 生物炭改性技术及其吸附典型气态污染物研究[J]. 环境保护前沿, 2026, 16(4): 633-646. https://doi.org/10.12677/aep.2026.164062

参考文献

[1] Li, Y., Zhang, H.X., Tao, B., Zhang, J.Z. and Li, J.Z. (2023) Adsorption and Adsorption-Photocatalytic Degradation of VOCs Based on Carbon Materials. China Petroleum Processing & Petrochemical Technology, 25, 1-11. (In Chinese)
[2] 徐曼, 刁刘丽. 新型大气污染治理技术在环境保护工程中的应用研究[J]. 皮革制作与环保科技, 2025, 6(8): 130-132.
[3] Wu, P., Wang, Y. and Liu, Y. (2024) Recent Advances in Heteroatom-Doped Porous Carbon for Adsorption of Gaseous Pollutants. Chemical Engineering Journal, 491, Article ID: 152142. [Google Scholar] [CrossRef
[4] Chen, Y., Zhang, X., Chen, W., Yang, H. and Chen, H. (2017) The Structure Evolution of Biochar from Biomass Pyrolysis and Its Correlation with Gas Pollutant Adsorption Performance. Bioresource Technology, 246, 101-109. [Google Scholar] [CrossRef] [PubMed]
[5] 吴凡, 郝晓霞, 张明美, 等. KOH-苯甲酸改性生物炭吸附芳香类VOCs的研究[J]. 现代化工, 2026, 46(3): 175-179+184.
[6] Shao, J., Zhang, J., Zhang, X., Feng, Y., Zhang, H., Zhang, S., et al. (2018) Enhance SO2 Adsorption Performance of Biochar Modified by CO2 Activation and Amine Impregnation. Fuel, 224, 138-146. [Google Scholar] [CrossRef
[7] Ogungbenro, A.E., Quang, D.V., Al-Ali, K.A., Vega, L.F. and Abu-Zahra, M.R.M. (2018) Physical Synthesis and Characterization of Activated Carbon from Date Seeds for CO2 Capture. Journal of Environmental Chemical Engineering, 6, 4245-4252. [Google Scholar] [CrossRef
[8] Cao, C., Li, R., Dai, H., Zhao, Y., Sun, L., Zhuang, X., et al. (2025) Anaerobic Digestion Enhances the Comprehensive Utilization of Shaddock Peel: Methane Production, Biochar Preparation, and CO2 Capture. Water, Air, & Soil Pollution, 236, Article No. 540. [Google Scholar] [CrossRef
[9] Setiawan, H., Sakamoto, M., Fujisaki, T., Lyth, S.M. and Shiratori, Y. (2022) Development of a Sustainable Nitrogen-Doped Biochar Desulfurizer for Solid Oxide Fuel Cell Systems. Biomass and Bioenergy, 167, Article ID: 106631. [Google Scholar] [CrossRef
[10] Zhao, Y. and Liu, Y. (2022) Preparation of Hydrogen Sulfide Adsorbent Derived from Spent Fenton-Like Reagent Modified Biochar and Its Removal Characteristics for Hydrogen Sulfide. Fuel Processing Technology, 238, Article ID: 107495. [Google Scholar] [CrossRef
[11] Nor, N.M., Chung, L.L. and Mohamed, A.R. (2022) Development of Microwave-Assisted Nitrogen-Modified Activated Carbon for Efficient Biogas Desulfurization: A Practical Approach. Environmental Science and Pollution Research, 30, 17129-17148. [Google Scholar] [CrossRef] [PubMed]
[12] Guo, J., Luo, Y., Lua, A.C., Chi, R., Chen, Y., Bao, X., et al. (2007) Adsorption of Hydrogen Sulphide (H2S) by Activated Carbons Derived from Oil-Palm Shell. Carbon, 45, 330-336. [Google Scholar] [CrossRef
[13] 高超. 镍改性多孔材料对氨气的吸附机理及应用研究[D]: [硕士学位论文]. 南京: 南京师范大学, 2022.
[14] 刘明辉, 唐子君, 饶梓凌, 等. 高性能甘蔗基生物炭制备及其对H2S和NH3吸附[J]. 南昌大学学报(理科版), 2023, 47(4): 374-382.
[15] 李桥. 生物炭紫外改性及对VOCs气体吸附性能与机理研究[D]: [博士学位论文]. 重庆: 重庆大学, 2016.
[16] Zhang, L., Cui, L., Wang, Z. and Dong, Y. (2016) Modification of Activated Carbon Using Microwave Radiation and Its Effects on the Adsorption of SO2. Journal of Chemical Engineering of Japan, 49, 52-59. [Google Scholar] [CrossRef
[17] 李立清, 梁鑫, 姚小龙, 等. 微波改性对活性炭及其甲醇吸附的影响[J]. 湖南大学学报(自然科学版), 2014, 41(7): 78-83.
[18] Ning, P., Liu, S., Wang, C., Li, K., Sun, X., Tang, L., et al. (2018) Adsorption-Oxidation of Hydrogen Sulfide on Fe/Walnut-Shell Activated Carbon Surface Modified by NH3-Plasma. Journal of Environmental Sciences, 64, 216-226. [Google Scholar] [CrossRef] [PubMed]
[19] Taskin, M.B., Özbek, S., Demirhan, E. and Özbek, B. (2016) BSA Adsorption onto Commercial Activated Carbon Modified by Microwave Assisted Chemical Activation. Bulgarian Chemical Communications, 48, 261-268.
[20] 刘璐, 胡宇琴, 刘钰铃, 等. 钠盐改性的N掺杂多孔碳的制备及其电容性能[J]. 武汉工程大学学报, 2023, 45(6): 647-654.
[21] Pi, X., Qu, Z., Sun, F., Zhang, Z. and Gao, J. (2021) Catalytic Activation Preparation of Nitrogen-Doped Hierarchical Porous Bio-Char for Efficient Adsorption of Dichloromethane and Toluene. Journal of Analytical and Applied Pyrolysis, 156, Article ID: 105150. [Google Scholar] [CrossRef
[22] Rizwan, M., Lin, Q., Chen, X., Li, Y., Li, G., Zhao, X., et al. (2020) Synthesis, Characterization and Application of Magnetic and Acid Modified Biochars Following Alkaline Pretreatment of Rice and Cotton Straws. Science of the Total Environment, 714, Article ID: 136532. [Google Scholar] [CrossRef] [PubMed]
[23] Wang, Y., Zhu, W., Zhao, G., Ye, G., Jiao, Y., Wang, X., et al. (2023) Precise Preparation of Biomass-Based Porous Carbon with Pore Structure-Dependent VOCs Adsorption/Desorption Performance by Bacterial Pretreatment and Its Forming Process. Environmental Pollution, 322, Article ID: 121134. [Google Scholar] [CrossRef] [PubMed]
[24] Pan, Z., Qi, G., Zhang, X., Dai, H., Xiang, W., Zhao, Y., et al. (2025) Biological Pretreatment through Anaerobic Digestion for Micro-Mesoporous Biochar Production: Characterization and Environmental Remediation Application. Bioresource Technology Reports, 29, Article ID: 102062. [Google Scholar] [CrossRef
[25] 冼学权, 杜芳黎, 龙思宇, 等. 碳酸钙-糖蜜生物炭复合材料的制备及其对Pb2+的吸附性能[J]. 农业工程学报, 2025, 41(24): 265-276.
[26] Huynh, T.L., Dao, B.T.T., Le, M.T., Doan, K.A.T., Nguyen, T.D., Le, H.N., et al. (2026) Polyethyleneimine-Modified Activated Biochar Derived from Rice Husk Ash: Material Development and Preliminary Formaldehyde Adsorption Study. Carbon Research, 5, Article No. 5. [Google Scholar] [CrossRef
[27] He, D., Wang, J., Deng, W., Xiong, J., Lu, M., Tu, X., et al. (2026) Green Preparation of Shell-Based Biochar and Its Adsorption of Multi-Component Chlorinated Volatile Organic Compounds. RSC Advances, 16, 2462-2474. [Google Scholar] [CrossRef
[28] 丁佳蓉. 微纳米壳聚糖-活性炭复合刨花板的甲醛及VOCs散发特性研究[D]: [硕士学位论文]. 哈尔滨: 东北林业大学, 2025.
[29] Gutierrez-Martinez, J., Flores-Chaparro, C.E. and Rangel-Mendez, J.R. (2025) Superior Dynamic Adsorption-Desorption of a Valorized Lignocellulosic Waste Composite Enhanced with Carbon Nanofibers for Gasoline Emissions Control: Regenerative Fixed Bed and Modeling. Environmental Science and Pollution Research, 32, 26821-26839. [Google Scholar] [CrossRef
[30] 任鹏锟, 仲兆平, 张小霓, 等. 污泥-木屑基活性炭的制备及其对苯系VOCs的吸附性能[J]. 化工进展, 2025, 44(6): 3031-3040.
[31] 郭萧蒙. 农林生物质炭的制备及其对CO2和VOCs吸附性能研究[D]: [硕士学位论文]. 石家庄: 河北科技大学, 2025.
[32] Yu, L., Pan, K., Tang, Y., Xu, W., Chen, J., Fang, R., et al. (2025) Preparation of CeO2/Biochar Composites by Flash Joule Heating and the Research on Its Efficient Removal Performance of VOCs. Chemical Engineering Journal, 521, Article ID: 166572. [Google Scholar] [CrossRef
[33] Liang, D., Chang, Y., Zhang, P., Liu, Y., Luo, C., Zhang, Z., et al. (2025) Construction of Biochar-Zeolite Composite for Enhanced VOCs Adsorption: Interfacial Reinforcement and Steam-Driven Synergistic Regulation of Pore Formation and Dealumination. Journal of Cleaner Production, 524, Article ID: 146481. [Google Scholar] [CrossRef
[34] 黄恋涵, 夏维清, 陈佳丽, 等. 胺基稻草秸秆生物炭对SO2气体吸附研究[C]//《环境工程》编委会, 工业建筑杂志社有限公司. 《环境工程》2019年全国学术年会论文集. 北京: 工业建筑杂志社有限公司, 2019: 230-233+250.
[35] 吴庚桦. 金属化合物改性生物质炭基复合材料的制备及其NH3吸附性能和机理研究[D]: [硕士学位论文]. 成都: 四川大学, 2023.
[36] 苏明雪, 李宁. 热解及改性温度对生物炭吸附氨气性能的影响[J]. 中国水泥, 2025(12): 19-23.
[37] 王海林. 改性柚皮基生物炭对氨气的吸附性能及其机理研究[D]: [硕士学位论文]. 重庆: 重庆大学, 2021.
[38] 程龙生, 陈蓉, 欧继光, 等. 生物质炭的制备、改性以及在挥发性有机物吸附方面的应用[J]. 化学通报, 2024, 87(1): 56-66+35.
[39] Zhang, X., Gao, B., Creamer, A.E., Cao, C. and Li, Y. (2017) Adsorption of VOCs onto Engineered Carbon Materials: A Review. Journal of Hazardous Materials, 338, 102-123. [Google Scholar] [CrossRef] [PubMed]
[40] 李津津, 杨孟依, 岑珂慧, 等. 氮掺杂生物炭制备及其脱除VOCs/H2S的研究进展[J]. 林产化学与工业, 2025, 45(5): 127-138.
[41] Zhu, M.P., Zhou, K.B., Sun, X.D., Zhao, Z.X., Tong, Z.F. and Zhao, Z.X. (2017) Hydrophobic N-Doped Porous Biocarbon from Dopamine for High Selective Adsorption of p-Xylene under Humid Conditions. Chemical Engineering Journal, 317, 660-672. [Google Scholar] [CrossRef
[42] 陈佳利. 甲酰氯甘蔗基生物炭吸附二氧化硫性能研究[J]. 湖南有色金属, 2021, 37(2): 60-63.
[43] 武传朋, 李传坤, 杨哲, 等. 固体吸附材料脱除SO2研究进展[J]. 化工进展, 2022, 41(7): 3840-3854.
[44] 崔帅博. 秸秆生物炭及其负载铜基吸附剂脱除气态硫化氢的研究[D]: [硕士学位论文]. 镇江: 江苏大学, 2022.
[45] 马靖元. 农作废物生物炭基材料的制备及对H2S吸附研究[D]: [硕士学位论文]. 重庆: 重庆大学, 2021.
[46] 阮昊天. 烟杆基生物炭载体催化剂同时脱除H2S、COS和CS2的研究[D]: [硕士学位论文]. 昆明: 昆明理工大学, 2017.
[47] 徐期勇, 梁铭珅, 许文君, 等. 生物炭吸附硫化氢机制与影响因素研究进展[J]. 环境科学, 2021, 42(11): 5086-5099.
[48] 郭嘉, 向守信, 桂本, 等. 磷酸浸渍法制备生物质活性炭吸附氨气[J]. 化学工程师, 2007(6): 1-4+19.
[49] Zhang, X., Xu, H., Xiang, W., You, X., Dai, H. and Gao, B. (2024) Lignin-Impregnated Biochar Assisted with Microwave Irradiation for CO2 Capture: Adsorption Performance and Mechanism. Biochar, 6, Article No. 22. [Google Scholar] [CrossRef