钙钛矿基光电催化水分解体系的研究进展
Research Progress on Perovskite-Based Photoelectrocatalytic Water Splitting Systems
DOI: 10.12677/japc.2026.152017, PDF,   
作者: 李瑾璇：兰州交通大学国家绿色镀膜技术与装备工程技术研究中心，甘肃 兰州
关键词: 光电催化；钙钛矿；水分解；Photoelectrocatalysis； Perovskite； Water Splitting
摘要: 钙钛矿基光电催化水分解制氢是实现太阳能向化学能转化的有效途径。本文综述了影响该体系太阳能–氢能转换效率的关键因素，包括光电极本征性能、稳定性及助催化剂活性。针对贵金属催化剂成本高的问题，总结了元素掺杂、表面空位、异质结构及协同策略在非贵金属助催化剂性能提升中的应用。这些策略通过调控电子结构与反应动力学，显著增强了析氢性能。最后，对封装材料、催化剂理性设计、原位表征及器件优化等未来方向进行了展望。
Abstract: Perovskite-based photoelectrocatalytic water splitting for hydrogen production is an effective approach to convert solar energy into chemical energy. This article reviews the key factors affecting the solar-to-hydrogen (STH) conversion efficiency of such systems, including the intrinsic properties of photoelectrodes, their stability, and the activity of cocatalysts. In view of the high cost of noble metal catalysts, the application of strategies such as elemental doping, surface vacancy engineering, heterostructure construction, and synergistic effects in enhancing the performance of non-noble metal cocatalysts is summarized. These strategies significantly improve hydrogen evolution performance by modulating the electronic structure and reaction kinetics. Finally, future research directions are discussed, including encapsulation materials, rational design of catalysts, in situ characterization techniques, and device optimization.
文章引用：李瑾璇. 钙钛矿基光电催化水分解体系的研究进展[J]. 物理化学进展, 2026, 15(2): 161-177. https://doi.org/10.12677/japc.2026.152017

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