|
[1]
|
Fagnou, K. and Lautens, M. (2002) Rhodium-Catalyzed Carbon-Carbon Bond Forming Reactions of Organometallic Compounds. Chemical Reviews, 103, 169-196. [Google Scholar] [CrossRef] [PubMed]
|
|
[2]
|
Cherney, A.H., Kadunce, N.T. and Reisman, S.E. (2015) Enantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents to Construct C-C Bonds. Chemical Reviews, 115, 9587-9652. [Google Scholar] [CrossRef] [PubMed]
|
|
[3]
|
Lovering, F., Bikker, J. and Humblet, C. (2009) Escape from Flatland: Increasing Saturation as an Approach to Improving Clinical Success. Journal of Medicinal Chemistry, 52, 6752-6756. [Google Scholar] [CrossRef] [PubMed]
|
|
[4]
|
Rudolph, A. and Lautens, M. (2009) Secondary Alkyl Halides in Transition‐Metal‐Catalyzed Cross‐Coupling Reactions. Angewandte Chemie International Edition, 48, 2656-2670. [Google Scholar] [CrossRef] [PubMed]
|
|
[5]
|
Jana, R., Pathak, T.P. and Sigman, M.S. (2011) Advances in Transition Metal (Pd, Ni, Fe)-Catalyzed Cross-Coupling Reactions Using Alkyl-Organometallics as Reaction Partners. Chemical Reviews, 111, 1417-1492. [Google Scholar] [CrossRef] [PubMed]
|
|
[6]
|
McDonald, R.I., Liu, G. and Stahl, S.S. (2011) Palladium(II)-Catalyzed Alkene Functionalization via Nucleopalladation: Stereochemical Pathways and Enantioselective Catalytic Applications. Chemical Reviews, 111, 2981-3019. [Google Scholar] [CrossRef] [PubMed]
|
|
[7]
|
Merino, E. and Nevado, C. (2014) Addition of CF3 across Unsaturated Moieties: A Powerful Functionalization Tool. Chemical Society Reviews, 43, 6598-6608. [Google Scholar] [CrossRef] [PubMed]
|
|
[8]
|
Cheng, L. and Mankad, N.P. (2020) C-C and C-X Coupling Reactions of Unactivated Alkyl Electrophiles Using Copper Catalysis. Chemical Society Reviews, 49, 8036-8064. [Google Scholar] [CrossRef] [PubMed]
|
|
[9]
|
Peng, J.B., Wu, F.P. and Wu, X.F. (2019) First-Row Transition-Metal-Catalyzed Carbonylative Transformations of Carbon Electrophiles. Chemical Reviews, 119, 2090-2127. [Google Scholar] [CrossRef] [PubMed]
|
|
[10]
|
Torborg, C. and Beller, M. (2009) Recent Applications of Palladium‐Catalyzed Coupling Reactions in the Pharmaceutical, Agrochemical, and Fine Chemical Industries. Advanced Synthesis & Catalysis, 351, 3027-3043. [Google Scholar] [CrossRef]
|
|
[11]
|
Zhuang, C., Zhang, W., Sheng, C., Zhang, W., Xing, C. and Miao, Z. (2017) Chalcone: A Privileged Structure in Medicinal Chemistry. Chemical Reviews, 117, 7762-7810. [Google Scholar] [CrossRef] [PubMed]
|
|
[12]
|
Devendar, P., Qu, R., Kang, W., He, B. and Yang, G. (2018) Palladium-Catalyzed Cross-Coupling Reactions: A Powerful Tool for the Synthesis of Agrochemicals. Journal of Agricultural and Food Chemistry, 66, 8914-8934. [Google Scholar] [CrossRef] [PubMed]
|
|
[13]
|
Janssen‐Müller, D., Sahoo, B., Sun, S. and Martin, R. (2019) Tackling Remote sp3 C-H Functionalization via Ni‐Catalyzed “Chain‐Walking” Reactions. Israel Journal of Chemistry, 60, 195-206. [Google Scholar] [CrossRef]
|
|
[14]
|
Li, Y., Wu, D., Cheng, H. and Yin, G. (2020) Difunctionalization of Alkenes Involving Metal Migration. Angewandte Chemie International Edition, 59, 7990-8003. [Google Scholar] [CrossRef] [PubMed]
|
|
[15]
|
Catellani, M., Chiusoli, G.P., Giroldini, W. and Salerno, G. (1980) New Transition Metal-Catalyzed C-C Coupling Reactions Initiated by C-X Bond Cleavage and Terminated by H-Transfer. Journal of Organometallic Chemistry, 199, C21-C23. [Google Scholar] [CrossRef]
|
|
[16]
|
Sakuraba, S., Awano, K. and Achiwa, K. (1994) Asymmetric Heck-Type Hydroarylation of Norbornene with Phenyl Triflate Catalyzed by Palladium Complexes of Chiral (β-n-Sulfonylaminoalkyl)phosphines. Synlett, 1994, 291-292. [Google Scholar] [CrossRef]
|
|
[17]
|
Ozawa, F., Kobatake, Y., Kubo, A. and Hayashi, T. (1994) Palladium-Catalysed Asymmetric Hydroalkenylation of Norbornene. Journal of the Chemical Society, Chemical Communications, 11, 1323-1324. [Google Scholar] [CrossRef]
|
|
[18]
|
Matsuura, R., Jankins, T.C., Hill, D.E., Yang, K.S., Gallego, G.M., Yang, S., et al. (2018) Palladium(II)-Catalyzed γ-Selective Hydroarylation of Alkenyl Carbonyl Compounds with Arylboronic Acids. Chemical Science, 9, 8363-8368. [Google Scholar] [CrossRef] [PubMed]
|
|
[19]
|
Zheng, K., Xiao, G., Guo, T., Ding, Y., Wang, C., Loh, T., et al. (2020) Intermolecular Reductive Heck Reaction of Unactivated Aliphatic Alkenes with Organohalides. Organic Letters, 22, 694-699. [Google Scholar] [CrossRef] [PubMed]
|
|
[20]
|
Wang, C., Xiao, G., Guo, T., Ding, Y., Wu, X. and Loh, T. (2018) Palladium-Catalyzed Regiocontrollable Reductive Heck Reaction of Unactivated Aliphatic Alkenes. Journal of the American Chemical Society, 140, 9332-9336. [Google Scholar] [CrossRef] [PubMed]
|
|
[21]
|
Gurak, J.A. and Engle, K.M. (2018) Practical Intermolecular Hydroarylation of Diverse Alkenes via Reductive Heck Coupling. ACS Catalysis, 8, 8987-8992. [Google Scholar] [CrossRef] [PubMed]
|
|
[22]
|
Jin, L., Qian, J., Sun, N., Hu, B., Shen, Z. and Hu, X. (2018) Pd-Catalyzed Reductive Heck Reaction of Olefins with Aryl Bromides for Csp2-Csp3 Bond Formation. Chemical Communications, 54, 5752-5755. [Google Scholar] [CrossRef] [PubMed]
|
|
[23]
|
Oxtoby, L.J., Li, Z.-Q., Tran, V.T., Erbay, T.G., Deng, R., Liu, P., et al. (2020) A Transient‐Directing‐Group Strategy Enables Enantioselective Reductive Heck Hydroarylation of Alkenes. Angewandte Chemie International Edition, 59, 8885-8890. [Google Scholar] [CrossRef] [PubMed]
|
|
[24]
|
Niu, J., Wu, H., Niu, C., Huang, G. and Zhang, C. (2022) Stabilization of Ni0/NiII Heterojunctions inside Robust Porous Metal Silicate Materials for High-Performance Catalysis. ACS Catalysis, 12, 8667-8675.
|
|
[25]
|
Lv, H., Xiao, L., Zhao, D. and Zhou, Q. (2018) Nickel(0)-Catalyzed Linear-Selective Hydroarylation of Unactivated Alkenes and Styrenes with Aryl Boronic Acids. Chemical Science, 9, 6839-6843. [Google Scholar] [CrossRef] [PubMed]
|
|
[26]
|
Wang, D.-M., Feng, W., Wu, Y., Liu, T. and Wang, P. (2020) Redox‐Neutral Nickel(II) Catalysis: Hydroarylation of Unactivated Alkenes with Arylboronic Acids. Angewandte Chemie International Edition, 59, 20399-20404. [Google Scholar] [CrossRef] [PubMed]
|
|
[27]
|
Liu, C.-F., Luo, X., Wang, H. and Koh, M.J. (2021) Catalytic Regioselective Olefin Hydroarylation (Alkenylation) by Sequential Carbonickelation-Hydride Transfer. Journal of the American Chemical Society, 143, 9498-9506. [Google Scholar] [CrossRef] [PubMed]
|
|
[28]
|
Tong, W.-Y., Chen, Z., Qu, S. and Wang, X. (2024) Mechanistic Insight into Ni(I)-Catalyzed Regioselective Alkene Hydroarylation: Is It Carbonickelation or Hydronickelation? Organic Chemistry Frontiers, 11, 7176-7185. [Google Scholar] [CrossRef]
|
|
[29]
|
Wang, Z., Luo, X., Zhang, J., Liu, C., Koh, M.J. and Shi, S. (2023) Enantioselective C-C Cross-Coupling of Unactivated Alkenes. Nature Catalysis, 6, 1087-1097. [Google Scholar] [CrossRef]
|
|
[30]
|
Wang, Z.-C., Zhang, J.-W., Koh, M.J. and Shi, S.-L. (2023) Nickel-Catalyzed Enantioselective Hydroarylation of 1,1-Disubstituted Unactivated Alkenes. Angewandte Chemie International Edition, 62, e202310203.
|
|
[31]
|
Liu, M.-Y., Zhang, K.-X., Pan, J.-B., Zhou, Q.-L. and Xiao, L.-J. (2026) Nickel‐Catalyzed Enantioselective Reductive Heck Reaction of Olefins with Aryl Bromides and Chlorides Enabled by Chiral NHC Ligands. Angewandte Chemie International Edition, 65, e25600. [Google Scholar] [CrossRef]
|
|
[32]
|
Tsui, G.C., Menard, F. and Lautens, M. (2010) Regioselective Rhodium(I)-Catalyzed Hydroarylation of Protected Allylic Amines with Arylboronic Acids. Organic Letters, 12, 2456-2459. [Google Scholar] [CrossRef] [PubMed]
|
|
[33]
|
Tsui, G.C. and Lautens, M. (2010) Linear‐Selective Rhodium(I)‐Catalyzed Addition of Arylboronic Acids to Allyl Sulfones. Angewandte Chemie International Edition, 49, 8938-8941. [Google Scholar] [CrossRef] [PubMed]
|
|
[34]
|
Saxena, A. and Lam, H.W. (2011) Enantioselective Rhodium-Catalyzed Arylation of Electron-Deficient Alkenylarenes. Chemical Science, 2, 2326-2331. [Google Scholar] [CrossRef]
|
|
[35]
|
Liu, T., Yang, Y. and Wang, C. (2020) Manganese‐Catalyzed Hydroarylation of Unactivated Alkenes. Angewandte Chemie International Edition, 59, 14256-14260. [Google Scholar] [CrossRef] [PubMed]
|
|
[36]
|
Han, J., Yu, H. and Zi, W. (2022) Carboxylic Acid-Directed Manganese(I)-Catalyzed Regioselective Hydroarylation of Unactivated Alkenes. Organic Letters, 24, 6154-6158. [Google Scholar] [CrossRef] [PubMed]
|
|
[37]
|
Wang, Y., He, Y. and Zhu, S. (2022) NiH-Catalyzed Functionalization of Remote and Proximal Olefins: New Reactions and Innovative Strategies. Accounts of Chemical Research, 55, 3519-3536. [Google Scholar] [CrossRef] [PubMed]
|
|
[38]
|
Ye, R., Liu, X. and Dong, G. (2025) Enabling Aryl Chloride‐Mediated Palladium/norbornene Cooperative Catalysis. Angewandte Chemie International Edition, 64, e202500897. [Google Scholar] [CrossRef] [PubMed]
|
|
[39]
|
Li, Y. and Yin, G. (2023) Nickel Chain-Walking Catalysis: A Journey to Migratory Carboboration of Alkenes. Accounts of Chemical Research, 56, 3246-3259. [Google Scholar] [CrossRef] [PubMed]
|
|
[40]
|
Romano, C. and Martin, R. (2024) Ni-Catalysed Remote C(sp3)-H Functionalization Using Chain-Walking Strategies. Nature Reviews Chemistry, 8, 833-850. [Google Scholar] [CrossRef] [PubMed]
|
|
[41]
|
Loup, J., Zell, D., Oliveira, J.C.A., Keil, H., Stalke, D. and Ackermann, L. (2017) Asymmetric Iron‐Catalyzed C-H Alkylation Enabled by Remote Ligand meta‐Substitution. Angewandte Chemie International Edition, 56, 14197-14201. [Google Scholar] [CrossRef] [PubMed]
|
|
[42]
|
Jacob, N., Zaid, Y., Oliveira, J.C.A., Ackermann, L. and Wencel-Delord, J. (2022) Cobalt-Catalyzed Enantioselective C-H Arylation of Indoles. Journal of the American Chemical Society, 144, 798-806. [Google Scholar] [CrossRef] [PubMed]
|
|
[43]
|
Luc, A., Oliveira, J.C.A., Boos, P., Jacob, N., Ackermann, L. and Wencel-Delord, J. (2023) Double Cobalt-Catalyzed Atroposelective C-H Activation: One-Step Synthesis of Atropisomeric Indoles Bearing Vicinal C-C and C-N Diaxes. Chem Catalysis, 3, Article ID: 100765. [Google Scholar] [CrossRef]
|
|
[44]
|
Zhang, Z., Jacob, N., Bhatia, S., Boos, P., Chen, X., DeMuth, J.C., et al. (2024) Iron-Catalyzed Stereoselective C-H Alkylation for Simultaneous Construction of C-N Axial and C-Central Chirality. Nature Communications, 15, Article No. 3503. [Google Scholar] [CrossRef] [PubMed]
|
|
[45]
|
Wu, H.-Y., Koh, M.J., Wang, Z.-C. and Shi, S.-L. (2025) Modular Access to Arylethylamines Enabled by Ni-Catalyzed Markovni-Kov-Selective Hydroarylation of Allylic Amines. Angewandte Chemie International Edition, 64, e202503126.
|
|
[46]
|
Wang, Z.-C. and Shi, S.-L. (2025) Induced-Fit Chiral n-Heterocyclic Carbene Ligands for Asymmetric Catalysis. Accounts of Chemical Research, 58, 2157-2177. [Google Scholar] [CrossRef] [PubMed]
|
|
[47]
|
Mukherjee, P., Alassad, Z. and Hyster, T.K. (2025) Synergistic Photoenzymatic Anti-Markovnikov Hydroarylation of Olefins via Heteroaryl Radical Intermediates. Journal of the American Chemical Society, 147, 14048-14053. [Google Scholar] [CrossRef] [PubMed]
|
|
[48]
|
Liu, S., Ma, D., Gao, Y. and Su, W. (2025) Photoinduced Nickel-Catalyzed Enantioselective Hydroarylation of Alkenes with (Hetero)aryl Chlorides. [Google Scholar] [CrossRef]
|
|
[49]
|
Wang, Z.-C., Gao, L., Liu, S.-Y., Wang, P. and Shi, S.-L. (2025) Facile Access to Quaternary Carbon Centers via Ni-Catalyzed Arylation of Alkenes with Organoborons. Journal of the American Chemical Society, 147, 3023-3031. [Google Scholar] [CrossRef] [PubMed]
|