双功能卟啉催化剂催化二氧化碳与环氧化物环加成反应
Bifunctional Porphyrin Catalyst Catalyzes the Cycloaddition Reaction of Carbon Dioxide with Epoxides
摘要: 设计并合成了一种成本可控、合成简便,且可有效回收的金属卟啉–季铵盐双功能催化剂,其在循环使用三次后活性无明显下降。在常压CO2条件下,无需添加任何溶剂和助催化剂,仅以0.02 mol%的超低负载量即可实现多种环氧化物的高效转化为环碳酸酯。
Abstract: A cost-controllable, easily synthesized, and efficiently recyclable metal porphyrin-quaternary ammonium bifunctional catalyst was designed and synthesized. Its activity showed no significant decline after being used in three consecutive cycles. Under atmospheric CO2 conditions, without the addition of any solvents or co-catalysts, a very low loading of only 0.02 mol% can achieve the efficient conversion of various epoxides into cyclic carbonates.
文章引用:韩佳璇, 马陇君. 双功能卟啉催化剂催化二氧化碳与环氧化物环加成反应[J]. 有机化学研究, 2026, 14(2): 354-361. https://doi.org/10.12677/jocr.2026.142031

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