再生砖骨料–秸秆灰地聚物混凝土机理与改性综述
Review on Mechanism and Modification of Recycled Brick Aggregate-Straw Ash Geopolymer Concrete
摘要: 为了将建筑废弃物资源利用实现环境美化的问题,提出地质聚合物(Geopolymer)作为一种绿色建筑材料,具有替代硅酸盐水泥的潜力,因其具有固废资源利用和原料广泛等优点,有望实现低碳环保目标。基于此,本文研究了地质聚合物的反应机理和力学性能影响因素;分析了碱激发剂、凝胶材料、水胶比对GPC胶凝分子的影响,总结了固废秸秆灰理化性质、作用机制、性能影响以及对地聚物的研究;掌握了废砖再生骨料物理性质、化学改性以及对地聚物的研究;介绍了地聚物的微观分析和界面强化。旨在为固废基地质聚合物中的发展研究提供理论支持和技术借鉴。
Abstract: In order to solve the problem of environmental beautification by using construction waste resources, Geopolymer is proposed as a green building material, which has the potential to replace Portland cement. Because of its advantages of solid waste resource utilization and wide range of raw materials, it is expected to achieve low-carbon environmental protection goals. Based on this, this paper studies the reaction mechanism of geopolymer and the influencing factors of mechanical properties; the effects of alkali activator, gel material and water-binder ratio on GPC gelling molecules were analyzed. The physical and chemical properties, action mechanism, performance influence of solid waste straw ash and the research on geopolymer were summarized. Mastered the waste brick recycled aggregate physical properties, chemical modification and the study of geopolymer; the microscopic analysis and interface strengthening of geopolymers are introduced. The aim is to provide theoretical support and technical reference for the development of solid waste-based geopolymers.
文章引用:宋波波, 孙洪军. 再生砖骨料–秸秆灰地聚物混凝土机理与改性综述[J]. 土木工程, 2026, 15(8): 68-75. https://doi.org/10.12677/hjce.2026.158202

参考文献

[1] 王深, 吕连宏, 张保留, 等. 基于多目标模型的中国低成本碳达峰、碳中和路径[J]. 环境科学研究, 2021, 34(9): 2044-2055.
[2] 刘琼, 肖建庄, 潘智生, 等. 废混凝土骨料和废砖骨料再生混凝土的模型化研究[J]. 建筑结构学报, 2020, 41(12): 133-140.
[3] 《“十四五”循环经济发展规划》发布[N]. 现代物流报, 2021-07-12(A03).
[4] 王福成, 赵欣荣, 田家冰, 等. 水稻秸秆灰对混凝土抗压性能及微观结构的影响[J]. 吉林大学学报(工学版), 2024, 54(9): 2620-2630.
[5] Davidovits, J. (1989) Geopolymers and Geopolymeric Materials. Journal of Thermal Analysis, 35, 429-441.
https://doi.org/10.1007/bf01904446
[6] 黎洁, 谢贤, 李博琦, 等. 地质聚合物研究进展[J]. 矿产保护与利用, 2020, 40(6): 141-148.
[7] 张鹏, 张顶飞, 吴庆东. 地质聚合物力学性能影响分析及应用前景探讨[J]. 中国陶瓷, 2023, 59(2): 37-46.
[8] 岳子建, 徐金花. 地聚物混凝土的力学性能研究综述[J]. 四川建材, 2023, 49(2): 10-11.
[9] Choi, S. and Lee, K.M. (2019) Influence of Na2O Content and Ms (SiO2/Na2O) of Alkaline Activator on Workability and Setting of Alkali-Activated Slag Paste. Materials, 12, Article 2072.
https://doi.org/10.3390/ma12132072.
[10] Ibrahim, M., Megat Johari, M.A., Maslehuddin, M., Rahman, M.K., Salami, B.A. and Mohamed, H.D. (2019) Influence of Composition and Concentration of Alkaline Activator on the Properties of Natural-Pozzolan Based Green Concrete. Construction and Building Materials, 201, 186-195.
https://doi.org/10.1016/j.conbuildmat.2018.12.117
[11] Jindal, B.B., Jangra, P. and Garg, A. (2020) Effects of Ultra Fine Slag as Mineral Admixture on the Compressive Strength, Water Absorption and Permeability of Rice Husk Ash Based Geopolymer Concrete. Materials Today: Proceedings, 32, 871-877.
https://doi.org/10.1016/j.matpr.2020.04.219
[12] Shao, Q., Zheng, K., Zhou, X., Zhou, J. and Zeng, X. (2019) Enhancement of Nano-Alumina on Long-Term Strength of Portland Cement and the Relation to Its Influences on Compositional and Microstructural Aspects. Cement and Concrete Composites, 98, 39-48.
https://doi.org/10.1016/j.cemconcomp.2019.01.016
[13] Duna, L.L., Audrey, N.N.G., Tchamba, A.B., Billong, N., Kamseu, E., Qoku, E., et al. (2022) Engineering and Mineralogical Properties of Portland Cement Used for Building and Road Construction in Cameroon. International Journal of Pavement Research and Technology, 15, 821-834.
https://doi.org/10.1007/s42947-021-00055-9
[14] 马必聪, 梁健, 翁贻令. 生物质灰用作混凝土掺合料的研究综述[J]. 中外公路, 2024, 44(5): 97-107.
[15] Hidalgo, S., Soriano, L., Monzó, J., Payá, J., Font, A. and Borrachero, M.V. (2021) Evaluation of Rice Straw Ash as a Pozzolanic Addition in Cementitious Mixtures. Applied Sciences, 11, Article 773.
https://doi.org/10.3390/app11020773
[16] Khan, K., Ishfaq, M., Amin, M.N., Shahzada, K., Wahab, N. and Faraz, M.I. (2022) Evaluation of Mechanical and Microstructural Properties and Global Warming Potential of Green Concrete with Wheat Straw Ash and Silica Fume. Materials, 15, Article 3177.
https://doi.org/10.3390/ma15093177
[17] 许鹏, 许昌东, 王正君, 等. 生物质秸秆灰活性分析及对混凝土力学特性的影响[J]. 混凝土, 2020(3): 108-112+116.
[18] Cao, F., Qiao, H., Li, Y., Shu, X. and Cui, L. (2022) Effect of Highland Barley Straw Ash Admixture on Properties and Microstructure of Concrete. Construction and Building Materials, 315, Article 125802.
https://doi.org/10.1016/j.conbuildmat.2021.125802
[19] 张延年, 张祥坤, 顾晓薇, 等. 铁尾矿基多元矿物掺和料耦合水化机理分析[J]. 非金属矿, 2022, 45(3): 103-106.
[20] 吕阳, 葛云露, 赵博宇, 等. 生物质灰对碱激发矿渣胶凝材料性能的影响[J]. 硅酸盐通报, 2025, 44(4): 1288-1296.
[21] Zhu, Z., Li, X., Liu, R., Wang, Z., Zhang, H., Zhao, D., et al. (2025) Workability and Environmental Evaluation of Using Sunflower Stalk Ash as an Alkali Activator with Blast Furnace Slag and Black Rice Hull Ash to Prepare Geopolymer Grouts. Waste and Biomass Valorization, 16, 1609-1626.
https://doi.org/10.1007/s12649-024-02686-y
[22] Moraes, J.C.B., Moraes, M.J.B., Batista, J.P.B., Akasaki, J.L., Font, A., Tashima, M.M., et al. (2024) Influence of Sugar Cane Straw Ash in Metakaolin-Based Geopolymers. Construction and Building Materials, 444, Article 137835.
https://doi.org/10.1016/j.conbuildmat.2024.137835
[23] 焦杨, 方祥位, 申春妮, 等. 砖混建筑垃圾资源化再生利用研究进展[J/OL]. 土木与环境工程学报(中英文), 1-14.
https://link.cnki.net/urlid/50.1218.TU.20250414.1008.002, 2025-04-14.
[24] 马昆林, 莫文波, 莫建红, 等. 砖混再生细骨料再生砂浆性能及工程应用[J]. 铁道科学与工程学报, 2021, 18(8): 2073-2080.
[25] İlcan, H., Demirbaş, A.O., Ulugöl, H. and Şahmaran, M. (2024) Low-Alkaline Activated Construction and Demolition Waste-Based Geopolymers. Construction and Building Materials, 411, Article 134546.
https://doi.org/10.1016/j.conbuildmat.2023.134546
[26] 洪永鹏. 再生砖混粉体性能提升技术研究[D]: [硕士学位论文]. 杭州: 浙江大学, 2020.
[27] 王小娟, 刘路, 贾昆程, 等. 陶粒泡沫混凝土的力学性能及吸能特性[J]. 建筑材料学报, 2021, 24(1): 207-215.
[28] 邱继生, 王建伟, 冯泽平, 等. 不同化学溶液下再生砖混骨料强化及微观机理研究[J]. 混凝土, 2025(5): 113-119.
[29] He, Z., Shen, A., Wu, H., Wang, W., Wang, L., Yao, C., et al. (2021) Research Progress on Recycled Clay Brick Waste as an Alternative to Cement for Sustainable Construction Materials. Construction and Building Materials, 274, Article 122113.
https://doi.org/10.1016/j.conbuildmat.2020.122113
[30] Migunthanna, J., Rajeev, P. and Sanjayan, J. (2022) Waste Clay Bricks as a Geopolymer Binder for Pavement Construction. Sustainability, 14, Article 6456.
https://doi.org/10.3390/su14116456
[31] Dadsetan, S., Siad, H., Lachemi, M. and Sahmaran, M. (2019) Construction and Demolition Waste in Geopolymer Concrete Technology: A Review. Magazine of Concrete Research, 71, 1232-1252.
https://doi.org/10.1680/jmacr.18.00307
[32] Ye, T., Xiao, J., Duan, Z. and Li, S. (2022) Geopolymers Made of Recycled Brick and Concrete Powder—A Critical Review. Construction and Building Materials, 330, Article 127232.
https://doi.org/10.1016/j.conbuildmat.2022.127232
[33] Jiang, J., Zhou, W., Gao, Y., Wang, L., Wang, F., Chu, H., et al. (2019) Feasibility of Manufacturing Ultra-High Performance Cement-Based Composites (UHPCCs) with Recycled Sand: A Preliminary Study. Waste Management, 83, 104-112.
https://doi.org/10.1016/j.wasman.2018.11.005
[34] 郑居焕, 刘如月, 颜桂云, 等. 砖骨料地聚物再生混凝土力学性能试验研究[J]. 工业建筑, 2022, 52(9): 234-240.
[35] 彭万里. 再生骨料地聚物高性能混凝土制备及其关键性能研究[D]: [硕士学位论文]. 合肥: 合肥工业大学, 2024.
[36] 王怀亮, 欧睿. 高温前后再生砖骨料地聚物混凝土受压本构模型[J]. 复合材料学报, 2024, 41(6): 3143-3153.
[37] Cheng, J., Shao, Z., Wang, Y., Wei, W. and Yuan, Y. (2023) The Current Status and Future of Solid Waste Recycled Building Bricks. Environmental Science and Pollution Research, 30, 105119-105148.
https://doi.org/10.1007/s11356-023-29902-x
[38] Lyu, B.C., Guo, L.P., Fei, X.P., et al. (2023) Preparation and Properties of Green High Ductility Geopolymer Composites Incorporating Recycled Fine Brick Aggregate. Cement and Concrete Composites, 139, Article 105054.
https://doi.org/10.1016/j.cemconcomp.2023.105054
[39] 张逸超, 杨昊霖, 吴晓鑫, 等. 地质聚合物混凝土力学性能、耐久性及微观结构综述[J]. 混凝土, 2024(11): 84-87+92.
[40] 黄华, 郭梦雪, 张伟, 等. 粉煤灰-矿渣基地聚物混凝土力学性能与微观结构[J]. 哈尔滨工业大学学报, 2022, 54(3): 74-84.
[41] 王婕. 地质聚合物透水混凝土的性能及微观结构研究[D]: [硕士学位论文]. 赣州: 江西理工大学, 2022.
[42] 张大旺. 地质聚合物新拌浆体流变性、微结构与界面研究[D]: [博士学位论文]. 北京: 中国矿业大学, 2020.
[43] Peng, H., Cui, C., Cai, C.S., Liu, Y. and Liu, Z. (2019) Microstructure and Microhardness Property of the Interface between a Metakaolin/GGBFS-Based Geopolymer Paste and Granite Aggregate. Construction and Building Materials, 221, 263-273.
https://doi.org/10.1016/j.conbuildmat.2019.06.090