木质素改性沥青阻燃抑烟性能研究综述
Review on Flame Retardant and Smoke Suppression Properties of Lignin-Modified Asphalt
摘要: 木质素与沥青具有相似的化学结构,且作为一种环境友好、可再生的碳基烃类材料,近年来在沥青路面领域的应用研究受到广泛关注。本文系统总结了木质素的来源、化学组成以及其在沥青中的多种应用形式,如改性剂、抗氧化剂、乳化剂和填充剂等,并重点探讨了木质素改性沥青的燃烧特性及阻燃抑烟机理,同时介绍了沥青阻燃性能的常用试验方法。本文还结合国内外研究进展,深入分析了木质素在降低沥青可燃性、抑制烟雾释放以及提升沥青综合路用性能方面的重要影响,并对未来木质素改性沥青阻燃抑烟材料的研究方向进行了展望。目前,木质素改性沥青的阻燃抑烟机理尚未得到系统深入的研究,但已有的研究表明,木质素能够显著改善沥青的高温流变性、抗老化性能,并在对沥青进行PG分级后提高其高温等级。因此,木质素在公路隧道及普通公路建设中具有重要的应用潜力,其环境友好、可再生且价格低廉的特性使其有望成为未来沥青阻燃抑烟领域的重要发展方向,未来仍需开展更多研究以推动木质素在路面工程中的广泛应用。
Abstract: Lignin has a similar chemical structure to asphalt, and as an environmentally friendly and renewable carbon-based hydrocarbon material, its application research in the field of asphalt pavement has received extensive attention in recent years. This paper systematically summarizes the sources, chemical composition of lignin, and its various application forms in asphalt, such as modifier, antioxidant, emulsifier, and filler, and focuses on the combustion characteristics and flame retardant and smoke suppression mechanism of lignin-modified asphalt, while introducing the common test methods for asphalt flame retardant performance. Combined with the research progress at home and abroad, this paper deeply analyzes the important influence of lignin in reducing asphalt flammability, suppressing smoke release, and improving the comprehensive road performance of asphalt, and prospects the future research direction of lignin-modified asphalt flame retardant and smoke suppression materials. At present, the flame retardant and smoke suppression mechanism of lignin-modified asphalt have not been systematically and in-depth studied, but existing studies have shown that lignin can significantly improve the high-temperature rheological properties and anti-aging performance of asphalt and increase its high-temperature grade after PG grading of asphalt. Therefore, lignin has important application potential in highway tunnel and ordinary highway construction. Its environmentally friendly, renewable and low-cost characteristics make it expected to become an important development direction in the field of asphalt flame retardant and smoke suppression in the future. More research is still needed to promote the wide application of lignin in pavement engineering.
文章引用:杨春巧. 木质素改性沥青阻燃抑烟性能研究综述[J]. 土木工程, 2026, 15(8): 76-91. https://doi.org/10.12677/hjce.2026.158203

参考文献

[1] Qiu, J.L., Yang, T., Wang, X.L., Wang, L. and Zhang, G. (2019) Review of the Flame Retardancy on Highway Tunnel Asphalt Pavement. Construction and Building Materials, 195, 468-482.
https://doi.org/10.1016/j.conbuildmat.2018.11.034
[2] 罗刚. 中国10 km以上超长公路隧道统计[J]. 隧道建设(中英文), 2019, 39(8): 1380-1383.
[3] 刘继国, 崔庆龙, 李丹妮, 等. 截至2023年底中国10 km以上特长公路隧道统计与分析[J]. 隧道建设(中英文), 2024, 44(1): 189-198.
[4] Xu, T., Huang, X.M. and Zhao, Y.L. (2011) Investigation into the Properties of Asphalt Mixtures Containing Magnesium Hydroxide Flame Retardant. Fire Safety Journal, 46, 330-334.
https://doi.org/10.1016/j.firesaf.2011.05.001
[5] Qun, Y. and Guo, Z.Y. (2005) Mixture Design of Fire-Retarded OGFC in Road Tunnel. Road Materials and Pavement Design, 6, 255-268.
https://doi.org/10.1080/14680629.2005.9690008
[6] Jadsadajerm, S., Muangthong-on, T., Wannapeera, J., Ohgaki, H., Miura, K. and Worasuwannarak, N. (2018) Degradative Solvent Extraction of Biomass Using Petroleum Based Solvents. Bioresource Technology, 260, 169-176.
https://doi.org/10.1016/j.biortech.2018.03.124
[7] Boerjan, W., Ralph, J. and Baucher, M. (2003) Lignin Biosynthesis. Annual Review of Plant Biology, 54, 519-546.
https://doi.org/10.1146/annurev.arplant.54.031902.134938
[8] 陈向东, 袁永坤, 邵凯凌, 等. 木质素的改性及其对SBS改性沥青性能的影响[J]. 化工新型材料, 2025, 53(7): 285-290.
[9] 吴文娟, 金永灿, 吴建涛, 等. 木质素改性沥青的红外光谱分析[J]. 江苏大学学报(自然科学版), 2019, 40(1): 120-124.
[10] 阮金奎, 付鑫, 饶应军, 等. 基于多应力蠕变恢复评价木质素改性沥青高温性能[J]. 应用化工, 2023, 52(1): 17-21, 27.
[11] 任梵, 张晓娇, 孙海斌, 等. 国内外路用阻燃沥青的研究现状与展望[J]. 长安大学学报(自然科学版), 2012, 32(6): 1-10.
[12] 刘栋, 曾俐豪, 冯学茂, 等. 公路沥青阻燃剂及阻燃性能评价方法综述[J]. 合成材料老化与应用, 2023, 52(3): 104-107, 149.
[13] 何兆益, 谭洋伟, 李家琪, 等. 埃洛石纳米管协效阻燃改性沥青性能及机理研究[J]. 材料导报, 2022, 36(2): 72-79.
[14] 张康, 张瑞宁, 程晓亮, 等. 改性木质素磺酸钠在煤沥青水浆中的性能研究[J]. 化学工程, 2024, 52(3): 72-77, 83.
[15] 李学凡, 唐新德, 郭海超, 等. 改性木质素磺酸钠沥青乳化剂的合成及应用性能[J]. 新型建筑材料, 2024, 51(1): 70-73.
[16] 王雨晴, 吕婉蓉, 崔明辉, 等. 超疏水阻燃木质素基聚氨酯泡沫材料的结构及油水分离研究[J]. 化工新型材料, 2025, 53(12): 251-257.
[17] 赵宇宏, 彭顺显, 廖春花, 等. 酶解木质素改性沥青在不同老化时程下性能分析[J]. 应用化工, 2025, 54(02): 383-392, 397.
[18] Sundstrom, D.W., Klei, H.E. and Daubenspeck, T.H. (1983) Use of Byproduct Lignins as Extenders in Asphalt. Industrial & Engineering Chemistry Product Research and Development, 22, 496-500.
https://doi.org/10.1021/i300011a022
[19] Williams, R. (2008) The Utilization of Agriculturally Derived Lignin as an Antioxidant in Asphalt Binder. Master’s Thesis, Iowa State University Digital Repository.
http://lib.dr.iastate.edu/intrans_reports/14
[20] Zhang, Y., Liu, X., Apostolidis, P., Gard, W., van de Ven, M., Erkens, S., et al. (2019) Chemical and Rheological Evaluation of Aged Lignin-Modified Bitumen. Materials, 12, Article 4176.
https://doi.org/10.3390/ma12244176
[21] Norgbey, E., Huang, J., Hirsch, V., Liu, W.J., Wang, M., Ripke, O., et al. (2020) Unravelling the Efficient Use of Waste Lignin as a Bitumen Modifier for Sustainable Roads. Construction and Building Materials, 230, Article ID: 116957.
https://doi.org/10.1016/j.conbuildmat.2019.116957
[22] Slaghek, T., et al. (2015) Bitumen Composition. World Intellectual Property Organization. Patent WO2015137813.
[23] Landa, P. and Gosselink, R. (2019) Lignin-Based Bio-Asphalt. World Intellectual Property Organization, Patent WO2019092278.
[24] Moretti, C., Corona, B., Hoefnagels, R., Vural-Gürsel, I., Gosselink, R. and Junginger, M. (2021) Review of Life Cycle Assessments of Lignin and Derived Products: Lessons Learned. Science of the Total Environment, 770, Article ID: 144656.
https://doi.org/10.1016/j.scitotenv.2020.144656
[25] Wu, J., Liu, Q., Wang, C., Wu, W. and Han, W. (2021) Investigation of Lignin as an Alternative Extender of Bitumen for Asphalt Pavements. Journal of Cleaner Production, 283, Article ID: 124663.
https://doi.org/10.1016/j.jclepro.2020.124663
[26] Batista, K.B., Padilha, R.P.L., Castro, T.O., Silva, C.F.S.C., Araújo, M.F.A.S., Leite, L.F.M., et al. (2018) High-Temperature, Low-Temperature and Weathering Aging Performance of Lignin Modified Asphalt Binders. Industrial Crops and Products, 111, 107-116.
https://doi.org/10.1016/j.indcrop.2017.10.010
[27] Gao, J., Wang, H., Liu, C., Ge, D., You, Z. and Yu, M. (2020) High-Temperature Rheological Behavior and Fatigue Performance of Lignin Modified Asphalt Binder. Construction and Building Materials, 230, Article ID: 117063.
https://doi.org/10.1016/j.conbuildmat.2019.117063
[28] Arafat, S., Kumar, N., Wasiuddin, N.M., Owhe, E.O. and Lynam, J.G. (2019) Sustainable Lignin to Enhance Asphalt Binder Oxidative Aging Properties and Mix Properties. Journal of Cleaner Production, 217, 456-468.
https://doi.org/10.1016/j.jclepro.2019.01.238
[29] Duval, A. and Lawoko, M. (2014) A Review on Lignin-Based Polymeric, Micro-and Nano-Structured Materials. Reactive and Functional Polymers, 85, 78-96.
https://doi.org/10.1016/j.reactfunctpolym.2014.09.017
[30] Graichen, F.H.M., Grigsby, W.J., Hill, S.J., Raymond, L.G., Sanglard, M., Smith, D.A., et al. (2017) Yes, We Can Make Money Out of Lignin and Other Bio-Based Resources. Industrial Crops and Products, 106, 74-85.
https://doi.org/10.1016/j.indcrop.2016.10.036
[31] S. Abdel Zaher, K., Swellem, R.H., A.M. Nawwar, G., M. Abdelrazek, F. and H. El-Sabbagh, S. (2014) Proper Use of Rice Straw Black Liquor: Lignin/Silica Derivatives as Efficient Green Antioxidants for SBR Rubber. Pigment & Resin Technology, 43, 159-174.
https://doi.org/10.1108/prt-01-2013-0001
[32] Naseem, A., Tabasum, S., Zia, K.M., Zuber, M., Ali, M. and Noreen, A. (2016) Lignin-Derivatives Based Polymers, Blends and Composites: A Review. International Journal of Biological Macromolecules, 93, 296-313.
https://doi.org/10.1016/j.ijbiomac.2016.08.030
[33] Kun, D. and Pukánszky, B. (2017) Polymer/Lignin Blends: Interactions, Properties, Applications. European Polymer Journal, 93, 618-641.
https://doi.org/10.1016/j.eurpolymj.2017.04.035
[34] Yuan, Y.Q., Gao, D.Y., Zhao, J., Tang, J.Y. and Zhai, S.H. (2011) Experimental Study on Water Stability of Asphalt Mixture. Advanced Materials Research, 266, 135-138.
https://doi.org/10.4028/www.scientific.net/amr.266.135
[35] 王芷, 刘乾静, 刘莉, 等. 木质素提取及木质素吸附剂制备方法研究进展[J]. 现代化工, 2022, 42(6): 16-19.
[36] Weng, S., Li, Z., Bo, C., Song, F., Xu, Y., Hu, L., et al. (2023) Design Lignin Doped with Nitrogen and Phosphorus for Flame Retardant Phenolic Foam Materials. Reactive and Functional Polymers, 185, Article ID: 105535.
https://doi.org/10.1016/j.reactfunctpolym.2023.105535
[37] 常森林. 核桃壳木质素提取及制备酚醛树脂泡沫的研究[D]: [硕士学位论文]. 北京: 中国科学院大学(中国科学院过程工程研究所), 2017.
[38] 李丰泉. 辣木籽壳吸附性及木质素提取与应用研究[D]: [硕士学位论文]. 重庆: 西南大学, 2020.
[39] 熊绍俊. 有机溶剂分级工业碱木质素在木质素/PBAT复合膜材料中的应用[D]: [硕士学位论文]. 北京: 北京林业大学, 2021.
[40] Li, Y., Hou, S., Wei, Q., Ma, X. and Qu, Y. (2021) Effect of Alkali and 1,4-Butanediol Contents on the Extraction of Lignin and Lignin-Based Activated Carbon. ACS Omega, 6, 34386-34394.
https://doi.org/10.1021/acsomega.1c04318
[41] 王东玲, 王文锦, 彭梓芳, 等. 醇溶剂提取松木木质素及其结构表征[J]. 化工学报, 2020, 71(8): 3761-3769.
[42] Yong, K.J. and Wu, T.Y. (2023) Recent Advances in the Application of Alcohols in Extracting Lignin with Preserved Β-O-4 Content from Lignocellulosic Biomass. Bioresource Technology, 384, Article ID: 129238.
https://doi.org/10.1016/j.biortech.2023.129238
[43] 李双洋. 甲酸木质素的提取、结构表征及化学改性的研究[D]: [硕士学位论文]. 青岛: 青岛科技大学, 2017.
[44] Ma, S., Chen, B., Zeng, A., Li, Z., Tang, X., Sun, Y., et al. (2022) Chemical Structure Change of Lignin Extracted from Bamboo Biomass by Maleic Acid. International Journal of Biological Macromolecules, 221, 986-993.
https://doi.org/10.1016/j.ijbiomac.2022.09.002
[45] 高嘉祥, 靳昕怡, 肖杨, 等. 环氧树脂的阻燃改性研究进展[J]. 北京服装学院学报(自然科学版), 2022, 42(4): 83-91.
[46] 杨小龙, 申爱琴, 蒋宜馨, 等. 基于阻燃抑烟的纳米黏土改性沥青综述[J]. 交通运输工程学报, 2021, 21(5): 42-61.
[47] Xiao, F., Guo, R. and Wang, J. (2019) Flame Retardant and Its Influence on the Performance of Asphalt—A Review. Construction and Building Materials, 212, 841-861.
https://doi.org/10.1016/j.conbuildmat.2019.03.118
[48] 王超, 陆海梅, 等. 木质素基膨胀阻燃剂的制备及其在硬质聚氨酯泡沫中的阻燃机理[J]. 高分子材料科学与工程, 2020, 36(9): 119-125.
[49] 呼微, 赵晓杰, 刘昱含, 等. 新型木质素基阻燃剂在聚氨酯泡沫中的应用[J]. 长春工业大学学报, 2024, 45(4): 313-321.
[50] Yang, H., Qin, Y., Liang, D., Lu, X. and Gu, X. (2023) Preparation of a Novel Flame Retardant Based on Phosphorus/Nitrogen Modified Lignin with Metal–organic Framework and Its Application in Epoxy Resin. Journal of Thermal Analysis and Calorimetry, 148, 12845-12857.
https://doi.org/10.1007/s10973-023-12578-3
[51] Li, J., He, Z., Yu, L., He, L. and Shen, Z. (2021) Multi-objective Optimization and Performance Characterization of Asphalt Modified by Nanocomposite Flame-Retardant Based on Response Surface Methodology. Materials, 14, 4367.
https://doi.org/10.3390/ma14164367
[52] 李晓超, 刘圣洁, 曾俐豪, 等. 沥青复合阻燃抑烟剂的作用效果与协同机理[J]. 建筑材料学报, 2024, 27(4): 320-326.
[53] Chen, R., Zhao, R., Liu, Y., Xi, Z., Cai, J., Zhang, J., et al. (2021) Development of Eco-Friendly Fire-Retarded Warm-Mix Epoxy Asphalt Binders Using Reactive Polymeric Flame Retardants for Road Tunnel Pavements. Construction and Building Materials, 284, 122752.
https://doi.org/10.1016/j.conbuildmat.2021.122752
[54] Zhang, W., Liu, S., Sun, Q., Tian, N. and Wu, Z. (2023) Synthesis of Covalent Organic Framework Materials and Their Application in the Field of Sensing. Nano Research, 17, 162-195.
https://doi.org/10.1007/s12274-023-6027-x.
[55] 熊剑平, 彭文举, 陈宇, 等. 基于热分析的阻燃沥青阻燃机理[J]. 长安大学学报(自然科学版), 2019, 39(2): 47-56.
[56] 路建强, 杜傲伟, 柳伟, 等. 两种沥青路面阻燃剂的阻燃效果研究[J]. 有色金属材料与工程, 2023, 44(1): 75-84.
[57] 赵毅, 田玉峰, 郝增恒, 等. 隧道沥青路面阻燃抑烟技术及机理研究进展[J]. 应用化工, 2021, 50(5): 1430-1438.
[58] Jokic, M., Zhang, J. and Kabir, I.I. (2025) Polymer-based Flame-Retardant Asphalt: A Comprehensive Review of Materials, Performance, and Evaluation Methods. Polymers, 17, Article 3272.
https://doi.org/10.3390/polym17243272
[59] Sun, X., Zhao, Z., Xu, C., Hao, M., Bussemaker, M., Liu, L.X., et al. (2026) Reactive Nitrogen–boron Polyols for Flame-Retardant and Low-Smoke Rigid Polyurethane Foams. Reactive and Functional Polymers, 221, Article 106641.
https://doi.org/10.1016/j.reactfunctpolym.2026.106641.
[60] 陆海梅, 王超, 王洪坤, 等. 全组分微纳化木质纤维素基聚磷酸铵阻燃剂的制备及在纸张中的应用[J]. 材料导报, 2023, 37(10): 58-65.
[61] 王建祺. 无卤阻燃聚合物基础与应用[M]. 北京: 科学出版社, 2005.
[62] Wei, T., Yang, X., Huo, Y., Jia, X., Shan, W. and Wang, W. (2022) Lignin/Ammonium Polyphosphate-Modified Wood Flour/High-Density Polyethylene Composites. Materials Chemistry and Physics, 290, 126594.
https://doi.org/10.1016/j.matchemphys.2022.126594.
[63] 贾晓军, 申爱琴, 王超, 等. 氢氧化铝/有机改性蒙脱土复合改性沥青性能研究[J]. 硅酸盐通报, 2021, 40(12): 4167-4177.
[64] 汤智杰, 王路生. 温拌剂对氢氧化铝(ATH)/有机改性蒙脱土(OMMT)沥青混合料阻燃抑烟与路用性能的影响[J]. 材料科学与工程学报, 2023, 41(5): 799-805, 859.
[65] Tan, Y., He, Z., Li, X., Jiang, B., Li, J. and Zhang, Y. (2020) Research on the Flame Retardancy Properties and Mechanism of Modified Asphalt with Halloysite Nanotubes and Conventional Flame Retardant. Materials, 13, Article 4509.
https://doi.org/10.3390/ma13204509.
[66] Abniki, M., Rahmani, Z., Soleimani-Gorgani, A. and Shirkavand Hadavand, B. (2025) Recent Advances in Green Flame Retardant Compounds for Application in Polymers: A Review. Polymers from Renewable Resources, 16, 209-243.
https://doi.org/10.1177/20412479251345678
[67] Yang, H., Yu, B., Xu, X., Bourbigot, S., Wang, H. and Song, P. (2020) Lignin-derived Bio-Based Flame Retardants toward High-Performance Sustainable Polymeric Materials. Green Chemistry, 22, 2129-2161.
https://doi.org/10.1039/d0gc00449a.
[68] 吴伟飞, 李玉环, 徐松, 等. Mg-AlLDHs改性沥青的制备与抗老化性能研究[J]. 武汉理工大学学报, 2014, 36(4): 5.
[69] Yang, X., Shen, A., Liang, M., Jiang, Y. and Meng, Y. (2021) Dynamic Flame Retardancy and Flame Mechanism of SBS-Modified Asphalt Containing Alumina Trihydrate and Organic Montmorillonite. Construction and Building Materials, 309, Article ID: 125077.
https://doi.org/10.1016/j.conbuildmat.2021.125077
[70] 杨群, 李望瑞. 沥青阻燃性能的评价方法与性能研究[J]. 建筑材料学报, 2008(4): 431-434.
[71] 黄晓明, 吴少鹏, 赵永利. 沥青与沥青混合料[M]. 南京: 东南大学出版社, 2002.
[72] Wang, S., Cheng, D. and Xiao, F. (2017) Recent Developments in the Application of Chemical Approaches to Rubberized Asphalt. Construction and Building Materials, 131, 101-113.
https://doi.org/10.1016/j.conbuildmat.2016.11.077
[73] 贺孟霜. 道路石油沥青结构行为与性能表征[D]: [硕士学位论文]. 西安: 长安大学, 2013.
[74] Zhao, H., Cao, Y., Sit, S.P., Lineberry, Q. and Pan, W. (2011) Thermal Characteristics of Bitumen Pyrolysis. Journal of Thermal Analysis and Calorimetry, 107, 541-547.
https://doi.org/10.1007/s10973-011-1590-x
[75] 赵洁雯, 黄晓明, 李晓东. 基于热重质谱联用的沥青质燃烧特性分析[J]. 东南大学学报: 自然科学版, 2014, 44(1): 178-182.
[76] 马峰, 富志鹏, 沙爱民, 等. 天然沥青改性沥青热性质与微观结构研究[J]. 中国公路学报, 2015, 28(6): 12-17.
[77] 马峰, 傅珍, 沙爱民. 基于热分析质谱联用技术的沥青老化机理研究[J]. 长安大学学报: 自然科学版, 2014, 34(6): 7-12.
[78] Hao, J., Che, Y., Tian, Y., Li, D., Zhang, J. and Qiao, Y. (2017) Thermal Cracking Characteristics and Kinetics of Oil Sand Bitumen and Its SARA Fractions by TG-FTIR. Energy & Fuels, 31, 1295-1309.
https://doi.org/10.1021/acs.energyfuels.6b02598
[79] 何立平, 申爱琴, 梁军林, 等. 阻燃沥青及沥青混合料的阻燃性能及路用性能[J]. 公路交通科技, 2013, 30(12): 15-22.
[80] 刘细军, 许涛. 氢氧化镁阻燃沥青热解特性及动力学分析[J]. 公路, 2021, 66(12): 341-347.
[81] 王俊天. 隧道温拌阻燃沥青混合料性能研究[D]: [硕士学位论文]. 南京: 东南大学, 2021.
[82] 李梦林. LDHs/氢氧化物复合改性沥青阻燃性能与机理研究[D]: [硕士学位论文]. 武汉: 武汉理工大学, 2019.
[83] Eberhardsteiner, L., Füssl, J., Hofko, B., Handle, F., Hospodka, M., Blab, R., et al. (2015) Towards a Microstructural Model of Bitumen Ageing Behaviour. International Journal of Pavement Engineering, 16, 939-949.
https://doi.org/10.1080/10298436.2014.993192
[84] 刘圣洁, 林钰, 李梦然, 等. 基于MSCR试验的温拌阻燃沥青高温性能评价与分级[J]. 材料导报, 2023, 37(9): 142-147.