氧化石墨烯碳纤维水泥基材料综述
Overview of Graphene Oxide Carbon Fiber Cement-Based Materials
DOI: 10.12677/aep.2026.168137, PDF,   
作者: 许文华, 王学志：辽宁工业大学土木建筑工程学院，辽宁 锦州；朱安标：上海建工建材科技集团股份有限公司，上海
关键词: 氧化石墨烯；碳纤维；水泥基材料；界面改性；Graphene Oxide； Carbon Fiber； Cement-Based Materials； Interface Modification
摘要: 水泥基材料抗压性能优良、成本低廉，广泛应用于基建工程，但脆性高、抗裂性差，难以适配大跨度、智能化高端工程。碳纤维(CF)可提升基体力学、耐久与传感性能，然而其表面惰性导致界面黏结薄弱，改性效果受限。氧化石墨烯复配碳纤维(GO-CF)可有效改善两相界面结合。本文综述GO-CF复合增强体制备工艺、界面增强机制及对水泥基材料的提升作用，探讨聚羧酸减水剂、粉煤灰、硅灰对体系性能的调控效应，并展望该复合材料后续研究方向。
Abstract: Cement-based materials, with their excellent compressive properties and low cost, are widely used in infrastructure projects. However, due to their high brittleness and poor crack resistance, they are difficult to adapt to large-span and intelligent high-end projects. Carbon fiber (CF) can enhance the mechanical, durability, and sensing properties of the matrix, but its surface inertness leads to weak interfacial bonding, limiting the modification effect. Graphene oxide (GO) compounded with carbon fiber (GO-CF) can effectively improve the interfacial bonding between the two phases. This paper reviews the preparation process, interfacial reinforcement mechanism, and enhancement effect on cement-based materials of the GO-CF composite reinforcement system. It discusses the regulating effects of polycarboxylate superplasticizers, fly ash, and silica fume on the system’s performance, and looks forward to the future research directions of this composite material.
文章引用：许文华, 王学志, 朱安标. 氧化石墨烯碳纤维水泥基材料综述[J]. 环境保护前沿, 2026, 16(8): 1361-1371. https://doi.org/10.12677/aep.2026.168137

参考文献

[1] Gao, Y., Zou, F., Wang, S., Sui, H., Yu, J., Xu, B., et al. (2025) Redefining the Cement Substitution Potential of Recycled Concrete Powder Using Graphene Oxide Coating. Cement and Concrete Composites, 164, Article 106276.
https://doi.org/10.1016/j.cemconcomp.2025.106276
[2] Kong, X.Q., Wang, R.Z., Zhang, T.T., Sun, R.X., Fu, Y., et al. (2022) Effects of Graphene Oxygen Content on Durability and Microstructure of Cement Mortar Composites. Construction and Building Materials, 354, Article ID: 129121.
https://doi.org/10.1016/j.conbuildmat.2022.129121
[3] Fan, Y., Wei, H., Zheng, H. and Du, H. (2025) Effect of a Carbon Fibre-Steel Fibre-Graphite Conductive Filler on the Electrothermal Properties of Cementitious Materials. Journal of Wuhan University of Technology-Mater, 40, 141-151.
https://doi.org/10.1007/s11595-025-3048-1
[4] Cassese, P., Rainieri, C. and Occhiuzzi, A. (2021) Applications of Cement-Based Smart Composites to Civil Structural Health Monitoring: A Review. Applied Sciences, 11, Article 8530.
https://doi.org/10.3390/app11188530
[5] Bheel, N., Waqar, A., Radu, D., Benjeddou, O., Alwetaishi, M. and Almujibah, H.R. (2024) A Comprehensive Study on the Impact of Nano-Silica and Ground Granulated Blast Furnace Slag on High Strength Concrete Characteristics: RSM Modeling and Optimization. Structures, 62, Article 106160.
https://doi.org/10.1016/j.istruc.2024.106160
[6] Xiao, J., Han, N., Li, Y., Zhang, Z. and Shah, S.P. (2021) Review of Recent Developments in Cement Composites Reinforced with Fibers and Nanomaterials. Frontiers of Structural and Civil Engineering, 15, 1-19.
https://doi.org/10.1007/s11709-021-0723-y
[7] 李子琪, 裴纯, 朱继华. 碳纤维增强水泥基复合材料界面优化设计研究进展[J]. 复合材料学报, 2024, 41(10): 5125-5145.
[8] Armoosh, S.R., Oltulu, M., Alameri, I., Mohammed, H.M.A. and Karacali, T. (2022) The Combined Effect of Carbon Fiber and Carbon Nanotubes on the Electrical and Self-Heating Properties of Cement Composites. Journal of Intelligent Material Systems and Structures, 33, 2271-2284.
https://doi.org/10.1177/1045389x221077447
[9] Park, G., Kim, S., Park, G.-K. and Lee, N. (2020) Influence of Carbon Fiber on the Electromagnetic Shielding Effectiveness of High-Performance Fiber-Reinforced Cementitious Composites. Journal of Building Engineering, 35, Article 101982.
[10] Wanasinghe, D., Aslani, F. and Ma, G. (2021) Electromagnetic Shielding Properties of Cementitious Composites Containing Carbon Nanofibers, Zinc Oxide, and Activated Carbon Powder. Construction and Building Materials, 285, Article 122842.
https://doi.org/10.1016/j.conbuildmat.2021.122842
[11] 孔祥清, 班天一, 张筱萌, 等. 石墨烯在水泥基复合材料中的分散及其性能增强机理综述(英文) [J/OL]. 新型炭材料(中英文): 1-27.
https://link.cnki.net/urlid/14.1407.TQ.20250508.1019.001, 2025-12-10.
[12] 王志航, 白二雷, 黄河, 等. 碳纤维增强水泥基材料界面改性研究进展[J]. 材料导报, 2025, 39(5): 136-144.
[13] 楚电明, 董乾鹏, 白文娟, 等. 碳纤维/碳纳米管界面增强技术研究进展[J]. 化工新型材料, 2023, 51(1): 1006-3536.
[14] 李磊, 沈志刚, 屠晓萍, 等. 聚丙烯腈基高强高模碳纤维表面处理研究进展[J]. 上海纺织科技, 2024, 52(2): 1001-2044.
[15] 张美会, 曹维宇, 肖建文. 碳纤维表面化学接枝研究进展[J]. 化工新型材料, 2021, 49(6): 38-41+46.
[16] Yan, X., Zheng, D., Yang, H., Cui, H., Monasterio, M. and Lo, Y. (2020) Study of Optimizing Graphene Oxide Dispersion and Properties of the Resulting Cement Mortars. Construction and Building Materials, 257, Article 119477.
https://doi.org/10.1016/j.conbuildmat.2020.119477
[17] He, J., Wang, X., Han, L., Wang, S. and Xin, M. (2024) Effect of Graphene Oxide on the Electrothermal and Pressure-Sensitive Properties of Carbon Fiber Cementitious Composites. Materials, 17, Article 3928.
https://doi.org/10.3390/ma17163928
[18] 石丽娜. 水泥基复合材料导电性能及电热性能试验研究[D]: [硕士学位论文]. 太原: 太原理工大学, 2021.
[19] Lu, Z., Hanif, A., Sun, G., Liang, R., Parthasarathy, P. and Li, Z. (2018) Highly Dispersed Graphene Oxide Electrodeposited Carbon Fiber Reinforced Cement-Based Materials with Enhanced Mechanical Properties. Cement and Concrete Composites, 87, 220-228.
https://doi.org/10.1016/j.cemconcomp.2018.01.006
[20] 赵丹. 石墨烯对碳纤维表面修饰及其水泥基复合材料性能研究[D]: [硕士学位论文]. 济南: 济南大学, 2015.
[21] Chen, J., Zhao, D., Ge, H. and Wang, J. (2015) Graphene Oxide-Deposited Carbon Fiber/Cement Composites for Electromagnetic Interference Shielding Application. Construction and Building Materials, 84, 66-72.
https://doi.org/10.1016/j.conbuildmat.2015.03.050
[22] Li, M., Wang, H., Zhang, C., Deng, S., Li, K. and Guo, X. (2019) The Effect of Graphene Oxide Grafted Carbon Fiber on Mechanical Properties of Class G Portland Cement. Journal of Adhesion Science and Technology, 33, 2494-2516.
https://doi.org/10.1080/01694243.2019.1646848
[23] 汤寅寅, 金浩. 氧化石墨烯增韧碳纤维水泥基复合材料的力学特性研究[J]. 城市建筑, 2021, 18(8): 162-165.
[24] 王志航, 白二雷, 任彪, 等. 氧化石墨烯接枝碳纤维增强体改性混凝土的力学性能[J]. 复合材料学报, 2024, 41(10): 5504-5515.
[25] Wang, Z., Bai, E., Liang, L., Du, Y. and Liu, C. (2024) Comparison of Dynamic Mechanical Properties of Carbon Fiber and Graphene Oxide Grafted Carbon Fiber Modified Concrete. Journal of Building Engineering, 94, Article 109989.
https://doi.org/10.1016/j.jobe.2024.109989
[26] 王思月. 氧化石墨烯改性碳纤维水泥基复合材料性能研究[D]: [硕士学位论文]. 锦州: 辽宁工业大学, 2023.
[27] 孔祥清, 乔万福, 班天一, 等. 氧化石墨烯增强碳纤维/水泥基体界面的试验和分子模拟[J]. 复合材料学报, 2025, 42(9): 5216-5226.
[28] Wang, S., Wang, X., He, J. and Xin, M. (2022) Mechanical Behavior and Microstructure of Graphene Oxide Electrodeposited Carbon Fiber Reinforced Cement-Based Materials. Crystals, 12, Article 964.
https://doi.org/10.3390/cryst12070964
[29] 杨鑫, 张玉波, 刘艳慧. 氧化石墨烯改性碳纤维/C-S-H界面结合及强韧化机制[J]. 新型建筑材料, 2025, 52(9): 37-42.
[30] 欧阳威, 王志航, 林茂, 等. 碳纤维-氧化石墨烯复合改性混凝土的力学性能及机理研究[J]. 化工新型材料, 2026, 54(4): 154-160.
[31] Han, L., Wang, X., Geng, S., Fang, W., Hu, W., Wang, S., et al. (2025) Pressure Sensitivity, Compactness and Microstructural Characteristics of Cement Mortar Composites Enhanced by Density of Different Graphene Oxygen-Containing Functional Groups. Construction and Building Materials, 469, Article 140486.
https://doi.org/10.1016/j.conbuildmat.2025.140486
[32] 杨森, 王远贵, 齐孟, 等. 氧化石墨烯对多壁碳纳米管掺配水泥砂浆强度、压敏性能与微观结构的影响[J]. 复合材料学报, 2022, 39(5): 2340-2355.
[33] 王悦, 王琴, 郑海宇, 等. 分散剂对石墨烯水泥基复合材料压敏性能的影响研究[J]. 硅酸盐通报, 2021, 40(8): 2515-2526.
[34] 田维欣. 氧化石墨烯对水泥导热性能的改性机理及重力坝温控模拟[D]: [硕士学位论文]. 西安: 西安理工大学, 2023.
[35] Tian, W., Chai, J. and Cao, J. (2023) Cement-Based Composites Modified by Graphene Oxide Nano-Materials: Porosity and Thermal Conductivity. Journal of Physics: Conference Series, 2553, Article 012003.
https://doi.org/10.1088/1742-6596/2553/1/012003
[36] Li, W., Li, X., Chen, S.J., Liu, Y.M., Duan, W.H. and Shah, S.P. (2017) Effects of Graphene Oxide on Early-Age Hydration and Electrical Resistivity of Portland Cement Paste. Construction and Building Materials, 136, 506-514.
https://doi.org/10.1016/j.conbuildmat.2017.01.066
[37] Li, X., Wang, L., Liu, Y., Li, W., Dong, B. and Duan, W.H. (2018) Dispersion of Graphene Oxide Agglomerates in Cement Paste and Its Effects on Electrical Resistivity and Flexural Strength. Cement and Concrete Composites, 92, 145-154.
https://doi.org/10.1016/j.cemconcomp.2018.06.008
[38] 林立. 氧化石墨烯/碳纳米管水泥基复合材料性能研究[D]: [硕士学位论文]. 长沙: 湖南大学, 2018.
[39] 徐义洪, 范颖芳. 氧化石墨烯分散液对混凝土抗盐冻性能的影响[J]. 混凝土, 2022(2): 1-5.
[40] 韩雷莹, 王学志, 辛明, 等. 氧化石墨烯复掺纤维水泥基复合材料研究综述[J]. 功能材料, 2024, 55(3): 3073-3082.
[41] Muthu, M., Yang, E. and Unluer, C. (2021) Resistance of Graphene Oxide-Modified Cement Pastes to Hydrochloric Acid Attack. Construction and Building Materials, 273, Article 121990.
https://doi.org/10.1016/j.conbuildmat.2020.121990
[42] 高淑星. 聚羧酸减水剂的合成及复配技术综述[J]. 江西建材, 2020(6): 4+6.
[43] 金文. 聚羧酸高效减水剂品种对混凝土渗透性影响研究[J]. 浙江水利水电学院学报, 2015, 27(4): 65-68.
[44] 袁小亚, 曾俊杰, 牛佳伟, 等. 不同减水剂对氧化石墨烯掺配水泥胶砂力学性能及微观结构的影响[J]. 功能材料, 2018, 49(10): 10184-10189.
[45] 吴一晨, 郭荣鑫, 夏海廷, 等. 不同分散剂对复掺GO/CNFs水泥基复合材料力学和导电性能的影响[J]. 硅酸盐通报, 2021, 40(3): 731-740.
[46] Gu, Y. (2025) Studying on the Influence of Modified Graphene Oxide on the Performance of Cement-Based Composite Materials. RSC Advances, 15, 7609-7616.
https://doi.org/10.1039/d4ra08947b
[47] 张建武, 汪潇, 李志新, 等. 氧化石墨烯对高掺量粉煤灰水泥基材料性能的影响及机理[J]. 化工新型材料, 2021, 49(6): 240-243.
[48] 杜长青, 王章轩, 仝腾, 等. 硅灰/氧化石墨烯在水泥硬化浆体中的分散性研究[J]. 无机盐工业, 2023, 55(11): 115-120.