一维钛酸盐纳米材料的制备及应用研究进展
Research Progress on the Preparation and Applications of One-Dimensional Titanate Nanomaterials
DOI: 10.12677/ms.2026.169179, PDF,    科研立项经费支持
作者: 陈炳全, 刘 峻, 倪成瑞, 刘世凯*：河南工业大学材料科学与工程学院，河南 郑州；刘书锋：郑州博特硬质材料有限公司，河南 郑州；曹晓雨：河南工业大学化学化工学院，河南 郑州
关键词: 一维钛酸盐纳米材料；晶体结构；制备策略；应用领域；研究进展；One-Dimensional Titanate Nanomaterials； Crystal Structure； Preparation Strategies； Application Fields； Research Progress
摘要: 一维钛酸盐纳米材料具有独特晶体结构、优异阳离子交换能力、良好半导体特性与高比表面积，在光催化、电化学储能、吸附分离、传感检测等领域具备巨大应用潜力。本文梳理该类材料晶体结构特征与主流制备工艺，重点讨论水热合成关键调控条件，评述溶解–再结晶、层状中间体卷曲、定向附着–奥斯瓦尔德熟化等生长机理；对比模板法、溶胶–凝胶法、熔盐法、高温固相法的优缺点与适用场景，建立制备方法对比体系，并从“制备–结构–性能”的关联角度展开分析。综述了一维钛酸盐纳米材料在光催化、染料敏化太阳能电池、锂/钠离子电池、催化剂载体、气体传感器领域的研究现状，总结当前研究存在的挑战，对后续发展方向进行展望。
Abstract: One-dimensional (1D) titanate nanomaterials, by virtue of their distinctive crystal structures, exceptional cation exchange capacity, favorable semiconducting properties, and high specific surface area, have demonstrated substantial application potential across diverse fields including photocatalysis, electrochemical energy storage, adsorption and separation, and sensing and detection. This review systematically examines the crystal structural characteristics, principal preparation strategies, and underlying growth mechanisms of these materials. Particular attention is devoted to the key regulatory factors governing hydrothermal synthesis, accompanied by a critical appraisal of multiple growth mechanism models—including dissolution-recrystallization, the rolling of layered intermediates, and the oriented attachment-Ostwald ripening cooperative mechanism. In parallel, the advantages, limitations, and applicable scopes of alternative synthetic routes, namely the template method, sol-gel method, molten salt method, and high temperature solid state method, are objectively evaluated, and a comparative evaluation framework for these preparation approaches is established. Furthermore, a synthesis-structure-performance correlation perspective is adopted to deliver a more nuanced commentary on the interrelationships among synthetic pathways, microstructural features, and functional properties. The research progress of 1D titanate nanomaterials in photocatalysis, dye sensitized solar cells, lithium/sodium ion batteries, catalyst supports, and gas sensors is comprehensively reviewed. Finally, the prevailing challenges and developmental directions in this field are summarized, and an outlook on prospective research trends is presented.
文章引用：陈炳全, 刘书锋, 刘峻, 倪成瑞, 曹晓雨, 刘世凯. 一维钛酸盐纳米材料的制备及应用研究进展[J]. 材料科学, 2026, 16(9): 19-31. https://doi.org/10.12677/ms.2026.169179

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