融雪盐冻融耦合环境下混凝土护栏劣化特性及柔性协同防护涂料的研究
Study on Deterioration Characteristics of Concrete Guardrails under Coupled Environment of Deicing Salt and Freeze-Thaw and Flexible Coordinated Protective Coatings
DOI: 10.12677/ojtt.2026.155052, PDF,   
作者: 张 展:安徽省交通控股集团有限公司宁宣杭高速公路管理中心,安徽 宣城;吴 磊:安徽交控工程集团有限公司,安徽 合肥;李玉龙, 余秋伯:重庆交通大学材料科学与工程学院,重庆
关键词: 混凝土护栏劣化机制防护涂料氯离子侵蚀冻融循环耐久性柔性协同Concrete Guardrail Deterioration Mechanism Protective Coating Chloride Ingress Freeze-Thaw Cycle Durability Flexible Coordination
摘要: 混凝土护栏作为道路交通基础设施的重要安全构件,长期暴露于融雪盐、冻融循环、干湿交替、碳化、硫酸盐侵蚀和微生物腐蚀等复杂环境中,易发生开裂、剥落、钢筋锈蚀及承载性能下降等耐久性问题。本文围绕混凝土护栏劣化特性与柔性协同防护涂料研究现状进行综述,系统归纳氯离子侵蚀、碳化、硫酸盐侵蚀、碱–骨料反应、生物劣化、冻融循环、干湿循环和风化等主要劣化机制,总结成膜型、孔隙封闭型和渗透型防护涂料的研究进展及防护机理,并分析当前研究中涂层–基体柔性协调性不足、多因素耦合作用研究薄弱和工程长期验证不足等问题。研究表明,未来混凝土护栏防护材料应向高耐久、柔性协同、绿色环保方向发展。
Abstract: As critical safety components of road transportation infrastructure, concrete guardrails are continuously exposed to complex environments involving deicing salts, freeze-thaw cycles, wetting-drying alternation, carbonation, sulfate attack, and microbial corrosion. Consequently, they are prone to durability-related deterioration such as cracking, spalling, reinforcement corrosion, and degradation of load-bearing capacity. This paper reviews the deterioration characteristics of concrete guardrails and the current research status of protective coatings. The major deterioration mechanisms are systematically summarized, including chloride ingress, carbonation, sulfate attack, alkali-aggregate reaction, biodeterioration, freeze-thaw cycling, wetting-drying cycling, and weathering. Research progress and protection mechanisms of film-forming, pore-blocking, and penetrating protective coatings are also discussed. In addition, existing challenges are analyzed, including insufficient coating-substrate compatibility, limited understanding of multi-factor coupling effects, and inadequate long-term engineering validation. Studies indicate that protective materials for concrete guardrails in the future should evolve toward high durability, flexible coordination and eco-friendliness.
文章引用:张展, 吴磊, 李玉龙, 余秋伯. 融雪盐冻融耦合环境下混凝土护栏劣化特性及柔性协同防护涂料的研究[J]. 交通技术, 2026, 15(5): 603-613. https://doi.org/10.12677/ojtt.2026.155052

参考文献

[1] 刘旭文, 王明洲, 裴彦明, 等. 水利工程混凝土结构环氧防护材料开发与研究[J]. 全面腐蚀控制, 2026, 40(5): 39-43.
[2] Álava, H.E., Tsangouri, E., De Belie, N. and De Schutter, G. (2016) Chloride Interaction with Concretes Subjected to a Permanent Splitting Tensile Stress Level of 65%. Construction and Building Materials, 127, 527-538.
https://doi.org/10.1016/j.conbuildmat.2016.10.009
[3] Ren, M., Wang, Z., Aoki, H., Takahashi, H. and Maekawa, K. (2024) Numerical Investigation on Chloride-Induced Macro-Cell Corrosion of Steel Fiber Reinforced Concrete. Construction and Building Materials, 455, Article 139194.
https://doi.org/10.1016/j.conbuildmat.2024.139194
[4] 龚明子, 饶先鹏, 潘阿馨, 等. 潮汐区干湿循环下基于碳化与氯离子侵蚀的钢筋混凝土寿命预测[J]. 硅酸盐学报, 2026, 54(2): 590-601.
[5] Paul, S.C., Panda, B., Huang, Y., Garg, A. and Peng, X. (2018) An Empirical Model Design for Evaluation and Estimation of Carbonation Depth in Concrete. Measurement, 124, 205-210.
https://doi.org/10.1016/j.measurement.2018.04.033
[6] Zhang, C., Li, J., Yu, M., Lu, Y. and Liu, S. (2024) Mechanism and Performance Control Methods of Sulfate Attack on Concrete: A Review. Materials, 17, Article 4836.
https://doi.org/10.3390/ma17194836
[7] 郭正发, 朱红兵, 余志武, 等. 硫酸盐环境下轻骨料混凝土-普通混凝土界面性能劣化规律[J]. 科学技术与工程, 2026, 26(14): 6137-6144.
[8] 肖强, 陈艳丽, 王小勇, 等. 滨海枢纽工程碱骨料反应抑制高性能混凝土配制技术[J]. 粉煤灰综合利用, 2025, 39(2): 1-5.
[9] Gaylarde, C.C. and Ortega-Morales, B.O. (2023) Biodeterioration and Chemical Corrosion of Concrete in the Marine Environment: Too Complex for Prediction. Microorganisms, 11, Article 2438.
https://doi.org/10.3390/microorganisms11102438
[10] Yang, Y., Liu, J., Zhang, S., Jiang, C., Liu, L., Chen, Z., et al. (2025) Characterizing the Moisture Migration and Phase Transition in Cement-Based Materials during In-Situ Freeze-Thaw Cycles by Hydrogen Nuclear Magnetic Resonance (1H NMR). Cement and Concrete Composites, 163, Article 106204.
https://doi.org/10.1016/j.cemconcomp.2025.106204
[11] 田振海, 罗斌, 李明明, 等. 干湿循环条件下疏水改性泡沫混凝土的耐久性研究[J]. 材料导报, 2026, 40(9): 159-166.
[12] Ting, M.Z.Y., Wong, K.S., Rahman, M.E. and Meheron, S.J. (2021) Deterioration of Marine Concrete Exposed to Wetting-Drying Action. Journal of Cleaner Production, 278, Article 123383.
https://doi.org/10.1016/j.jclepro.2020.123383
[13] Pramanik, S.K., Bhuiyan, M., Robert, D., Roychand, R., Gao, L. and Pramanik, B.K. (2025) MIL-101(Cr)/Epoxy Composite Coating for Enhanced Corrosion Resistance in Concrete Sewer Infrastructure. Process Safety and Environmental Protection, 199, Article 107360.
https://doi.org/10.1016/j.psep.2025.107360
[14] Cui, Y., Tan, Z. and An, C. (2022) Research and Application of Multi-Functional Acrylic Resin Grouting Material. Construction and Building Materials, 359, Article 129381.
https://doi.org/10.1016/j.conbuildmat.2022.129381
[15] Zhuo, X., Sun, X., Wu, J., Dong, H., Shen, P., Zhang, X., et al. (2024) Molten CMAS Resistance Strategy for PS-PVD TBCs Based on Laser Textured and Al-Modified Bionic Structure. npj Materials Degradation, 8, Article No. 85.
https://doi.org/10.1038/s41529-024-00505-2
[16] Li, M., Zheng, H., Duan, Y., Hou, D., Wang, P., Pang, B., et al. (2023) The Wetting Behavior of Water Droplets on Silane and Silane/Go-Modified Ettringite Surfaces: Insights into Molecular Dynamics Simulations. Coatings, 13, Article 1299.
https://doi.org/10.3390/coatings13071299
[17] Ding, X., Xu, X., Wang, Y., Bao, J. and Zhang, P. (2024) Design of Functional Coating with Superior Liquid Repellency, Self-Cleaning, Photodegradation and Thermal Insulation Properties for Building Protection. Progress in Organic Coatings, 188, Article 108159.
https://doi.org/10.1016/j.porgcoat.2023.108159