UiO-66基材料在水处理领域的应用进展
Progress in the Application of UiO-66-Based Materials in the Field of Water Treatment
摘要: UiO-66是一类以锆氧团簇和对苯二甲酸构筑的金属有机框架材料，因其优异的水热稳定性、化学稳定性和结构可调性在水处理领域受到广泛关注。本文系统综述了UiO-66的结构特性、合成方法及其在吸附、光催化降解、荧光传感和膜分离等方面的应用进展。针对原始UiO-66在光响应范围窄、孔径受限和官能团单一等方面的不足，重点总结了配体功能化修饰、缺陷工程和复合结构构建三种主要改性策略，并通过典型案例展示了这些策略在提升污染物去除效率、选择性和材料可操作性方面的成效。最后，文章指出现有研究仍以实验室模拟为主，未来需在协同机制解析、绿色规模化制备、真实水体长期验证及技术经济性评估等方面持续突破，以推动UiO-66基材料向实际水处理工程应用转化。
Abstract: UiO-66 is a zirconium-based metal-organic framework (MOF) constructed from zirconium-oxo clusters and terephthalic acid ligands. Owing to its excellent hydrothermal stability, chemical stability, and structural tunability, UiO-66 has attracted extensive attention in the field of water treatment. This review systematically summarizes the structural characteristics, synthesis strategies, and recent advances of UiO-66 in various water treatment applications, including adsorption, photocatalytic degradation, fluorescence sensing, and membrane separation. To address the limitations of pristine UiO-66, such as limited light responsiveness, restricted pore accessibility, and insufficient functional diversity, three major modification strategies, including ligand functionalization, defect engineering, and composite construction, are highlighted. Representative studies are discussed to demonstrate how these strategies enhance pollutant removal efficiency, selectivity, and practical applicability of UiO-66-based materials. Finally, current challenges are discussed, including the predominance of laboratory-scale investigations, and future perspectives are proposed regarding synergistic mechanism elucidation, green and scalable synthesis, long-term validation in real water matrices, and techno-economic assessment, aiming to promote the practical implementation of UiO-66-based materials in water treatment applications.
文章引用：辛鹏飞. UiO-66基材料在水处理领域的应用进展[J]. 环境保护前沿, 2026, 16(9): 1568-1583. https://doi.org/10.12677/aep.2026.169157

参考文献

[1] Ahmadijokani, F., Molavi, H., Rezakazemi, M., Tajahmadi, S., Bahi, A., Ko, F., et al. (2022) UiO-66 Metal-Organic Frameworks in Water Treatment: A Critical Review. Progress in Materials Science, 125, Article 100904.
https://doi.org/10.1016/j.pmatsci.2021.100904
[2] Li, Y.H., Wang, C.C., Yi, X.H., et al. (2023) UiO-66(Zr)-Based Functional Materials for Water Purification: An Updated Review. Environmental Functional Materials, 2, 93-132.
https://doi.org/10.1016/j.efmat.2024.02.001
[3] Kiteto, M., Vidija, B., Mecha, C.A., Mrosso, R. and Chollom, M.N. (2024) Advances in Metal-Organic Frameworks as Adsorbents, Photocatalysts and Membranes: A New Frontier in Water Purification. Discover Water, 4, Article No. 54.
https://doi.org/10.1007/s43832-024-00119-4
[4] Perera, A.A.P.R., Madhushani, K.A.U., Kumar, A. and Gupta, R.K. (2023) Metal-Organic Frameworks for Wastewater Treatment: Recent Developments, Challenges, and Future Prospects. Chemosphere, 339, Article 139713.
https://doi.org/10.1016/j.chemosphere.2023.139713
[5] Aziz, K.H.H., Mustafa, F.S., Hamarawf, R.F. and Omer, K.M. (2025) Adsorptive Removal of Toxic Heavy Metals from Aquatic Environment by Metal Organic Framework (MOF): A Review. Journal of Water Process Engineering, 70, Article 106867.
https://doi.org/10.1016/j.jwpe.2024.106867
[6] Iroegbu, A.O.C., Teffo, M.L., Sadiku, E.R., Meijboom, R. and Hlangothi, S.P. (2025) Advancing Wastewater Treatment with Green and Scalable Metal-Organic Frameworks: From Synthetic Strategies to Real-World Deployment. npj Clean Water, 8, Article No. 85.
https://doi.org/10.1038/s41545-025-00514-x
[7] Cavka, J.H., Jakobsen, S., Olsbye, U., Guillou, N., Lamberti, C., Bordiga, S., et al. (2008) A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability. Journal of the American Chemical Society, 130, 13850-13851.
https://doi.org/10.1021/ja8057953
[8] Cliffe, M.J., Wan, W., Zou, X., Chater, P.A., Kleppe, A.K., Tucker, M.G., et al. (2014) Correlated Defect Nanoregions in a Metal-Organic Framework. Nature Communications, 5, Article No. 4176.
https://doi.org/10.1038/ncomms5176
[9] Winarta, J., Shan, B., Mcintyre, S.M., Ye, L., Wang, C., Liu, J., et al. (2020) A Decade of UiO-66 Research: A Historic Review of Dynamic Structure, Synthesis Mechanisms, and Characterization Techniques of an Archetypal Metal-Organic Framework. Crystal Growth & Design, 20, 1347-1362.
https://doi.org/10.1021/acs.cgd.9b00955
[10] Chi, H.Y., Song, S., Zhao, K., et al. (2025) Non-van-der-Waals Oriented Two-Dimensional UiO-66 Films by Rapid Aqueous Synthesis at Room Temperature. Journal of the American Chemical Society, 147, 7255-7263.
https://doi.org/10.1021/jacs.4c11134
[11] Li, B., Wu, W., Zhang, T., Jiang, S., Chen, X., Zhang, G., et al. (2017) Ferrocene Particles Incorporated into Zr-Based Metal-Organic Frameworks for Selective Phenol Hydroxylation to Dihydroxybenzenes. RSC Advances, 7, 38691-38698.
https://doi.org/10.1039/c7ra06917k
[12] Butova, V.V., Burachevskaya, O.A., Podshibyakin, V.A., Shepelenko, E.N., Tereshchenko, A.A., Shapovalova, S.O., et al. (2021) Photoswitchable Zirconium MOF for Light-Driven Hydrogen Storage. Polymers, 13, Article 4052.
https://doi.org/10.3390/polym13224052
[13] Koriem, O.A., Showman, M.S., El-Shazly, A.H. and Elkady, M. (2024) Synthesis of High-Performance Biocompatible Polymeric Membranes Incorporated with Zirconium-Based MOF for an Enhanced Brackish Water RO Desalination. Cellulose, 31, 2309-2325.
https://doi.org/10.1007/s10570-023-05723-6
[14] Chen, L., Pan, W., Li, K., Chen, M., Li, P., Liu, Y., et al. (2025) University of Oslo-66: A Versatile Zr-Based MOF for Water Purification through Adsorption and Photocatalysis. Processes, 13, Article 1133.
https://doi.org/10.3390/pr13041133
[15] Taddei, M., Dau, P.V., Cohen, S.M., Ranocchiari, M., van Bokhoven, J.A., Costantino, F., et al. (2015) Efficient Microwave Assisted Synthesis of Metal-Organic Framework UiO-66: Optimization and Scale Up. Dalton Transactions, 44, 14019-14026.
https://doi.org/10.1039/c5dt01838b
[16] Karadeniz, B., Howarth, A.J., Stolar, T., Islamoglu, T., Dejanović, I., Tireli, M., et al. (2018) Benign by Design: Green and Scalable Synthesis of Zirconium UiO-Metal-Organic Frameworks by Water-Assisted Mechanochemistry. ACS Sustainable Chemistry & Engineering, 6, 15841-15849.
https://doi.org/10.1021/acssuschemeng.8b04458
[17] Julien, P.A., Mottillo, C. and Friščić, T. (2017) Metal-Organic Frameworks Meet Scalable and Sustainable Synthesis. Green Chemistry, 19, 2729-2747.
https://doi.org/10.1039/c7gc01078h
[18] Chakraborty, D., Yurdusen, A., Mouchaham, G., Nouar, F. and Serre, C. (2023) Large-Scale Production of Metal-Organic Frameworks. Advanced Functional Materials, 34, Article 2309089.
https://doi.org/10.1002/adfm.202309089
[19] Teo, W.L., Zhou, W., Qian, C. and Zhao, Y. (2021) Industrializing Metal-Organic Frameworks: Scalable Synthetic Means and Their Transformation into Functional Materials. Materials Today, 47, 170-186.
https://doi.org/10.1016/j.mattod.2021.01.010
[20] Dunne, P.W., Lester, E. and Walton, R.I. (2016) Towards Scalable and Controlled Synthesis of Metal-Organic Framework Materials Using Continuous Flow Reactors. Reaction Chemistry & Engineering, 1, 352-360.
https://doi.org/10.1039/c6re00107f
[21] Liu, H., Cheng, M., Liu, Y., Zhang, G., Li, L., Du, L., et al. (2022) Modified UiO-66 as Photocatalysts for Boosting the Carbon-Neutral Energy Cycle and Solving Environmental Remediation Issues. Coordination Chemistry Reviews, 458, Article 214428.
https://doi.org/10.1016/j.ccr.2022.214428
[22] Lei, Y., Xie, J., Quan, W., Chen, Q., Long, X. and Wang, A. (2023) Advances in the Adsorption of Heavy Metal Ions in Water by UiO-66 Composites. Frontiers in Chemistry, 11, Article 1211989.
https://doi.org/10.3389/fchem.2023.1211989
[23] Zhang, X., Yang, Y., Lv, X., Wang, Y., Liu, N., Chen, D., et al. (2019) Adsorption/Desorption Kinetics and Breakthrough of Gaseous Toluene for Modified Microporous-Mesoporous UiO-66 Metal Organic Framework. Journal of Hazardous Materials, 366, 140-150.
https://doi.org/10.1016/j.jhazmat.2018.11.099
[24] Kandiah, M., Nilsen, M.H., Usseglio, S., Jakobsen, S., Olsbye, U., Tilset, M., et al. (2010) Synthesis and Stability of Tagged UiO-66 Zr-MOFs. Chemistry of Materials, 22, 6632-6640.
https://doi.org/10.1021/cm102601v
[25] Sun, Q., Qin, L., Lai, C., Liu, S., Chen, W., Xu, F., et al. (2023) Constructing Functional Metal-Organic Frameworks by Ligand Design for Environmental Applications. Journal of Hazardous Materials, 447, Article 130848.
https://doi.org/10.1016/j.jhazmat.2023.130848
[26] Shen, L., Liang, R., Luo, M., Jing, F. and Wu, L. (2015) Electronic Effects of Ligand Substitution on Metal-Organic Framework Photocatalysts: The Case Study of UiO-66. Physical Chemistry Chemical Physics, 17, 117-121.
https://doi.org/10.1039/c4cp04162c
[27] Lam, I.T.Y., Yuan, Y., Bang, K., Choi, S., Shin, D., Lu, D., et al. (2023) Towards the Fastest Kinetics and Highest Uptake of Post-Functionalized UiO-66 for Hg2+ Removal from Water. Nanoscale, 15, 10558-10566.
https://doi.org/10.1039/d3nr01959d
[28] Yang, Y.Q., Palaniandy, P., Zaman, H.G. and Khan, A.H. (2025) Functionalized Metal-Organic Frameworks for Efficient Uranium Adsorption from Seawater. Journal of Radioanalytical and Nuclear Chemistry, 334, 4457-4484.
https://doi.org/10.1007/s10967-025-10240-w
[29] Wu, H., Chua, Y.S., Krungleviciute, V., Tyagi, M., Chen, P., Yildirim, T., et al. (2013) Unusual and Highly Tunable Missing-Linker Defects in Zirconium Metal-Organic Framework UiO-66 and Their Important Effects on Gas Adsorption. Journal of the American Chemical Society, 135, 10525-10532.
https://doi.org/10.1021/ja404514r
[30] Bueken, B., Van Velthoven, N., Krajnc, A., Smolders, S., Taulelle, F., Mellot-Draznieks, C., et al. (2017) Tackling the Defect Conundrum in UiO-66: A Mixed-Linker Approach to Engineering Missing Linker Defects. Chemistry of Materials, 29, 10478-10486.
https://doi.org/10.1021/acs.chemmater.7b04128
[31] Zheng, M., Xuan, K., Yan, S., Guo, Y., Huang, Y., Xu, R., et al. (2024) Defective UiO-66 for the Highly Efficient Elimination of U(V) from Wastewater: Insights to the Effects of Defects and Pore Structure on the Adsorption Process. Separation and Purification Technology, 339, Article 126550.
https://doi.org/10.1016/j.seppur.2024.126550
[32] Xie, Z., He, Q., Liu, S., Huang, X., Dai, M., Chen, Q., et al. (2024) Enhanced Removal of As(III) by Manganese-Doped Defective UiO-66 Coupled Peroxymonosulfate: Multiple Reactive Oxygen Species and System Stability. Environmental Science: Nano, 11, 3585-3598.
https://doi.org/10.1039/d4en00194j
[33] Lan, D., Zhu, H., Zhang, J., Xie, C., Wang, F., Zheng, Y., et al. (2024) Heterojunction of UiO-66 and Porous G-C3N4 for Boosted Photocatalytic Removal of Organic Dye. Applied Surface Science, 655, Article 159623.
https://doi.org/10.1016/j.apsusc.2024.159623
[34] Zhao, Y., Wen, Y., Xu, X., Fan, M., Guo, S., Chen, Z., et al. (2025) Removal of Cu(II) and Cr(VI) from Electroplating Wastewater by Magnetic Fe3O4@SiO2-UiO-66-Edta: Adsorption Behavior and Mechanism. Environmental Research, 278, Article 121647.
https://doi.org/10.1016/j.envres.2025.121647
[35] Schaate, A., Roy, P., Godt, A., Lippke, J., Waltz, F., Wiebcke, M., et al. (2011) Modulated Synthesis of Zr-Based Metal-Organic Frameworks: From Nano to Single Crystals. Chemistry—A European Journal, 17, 6643-6651.
https://doi.org/10.1002/chem.201003211
[36] Zhang, Z., Tao, C., Zhao, J., Wang, F., Huang, J. and Wang, J. (2020) Microwave-Assisted Solvothermal Synthesis of UiO-66-NH2 and Its Catalytic Performance toward the Hydrolysis of a Nerve Agent Simulant. Catalysts, 10, Article 1086.
https://doi.org/10.3390/catal10091086
[37] Kang, D.A., Mohamed, A.M.O., Murphy, C., Ramos, A., Economou, I.G., Kim, J., et al. (2024) Rapid One-Pot Microwave-Assisted Synthesis and Defect Engineering of UiO-66 for Enhanced CO2 Capture. Journal of Materials Chemistry A, 13, 762-771.
https://doi.org/10.1039/d4ta06814a
[38] Zhao, J., Liu, Y., Wang, H., Fu, X.C. and Deng, N.M. (2024) Continuous, Solvent-Free, and Mechanochemical Synthesis of UiO-66 (Mn) by Gas-Solid Two-Phase Flow and Mechanism Research. Journal of Solid State Chemistry, 338, Article 124863.
https://doi.org/10.1016/j.jssc.2024.124863
[39] Jrad, A., Al Sabeh, G., Hannouche, K., Al Natour, R., Haidar, O., Sammoury, H., et al. (2023) Critical Role of Defects in UiO-66 Nanocrystals for Catalysis and Water Remediation. ACS Applied Nano Materials, 6, 18698-18720.
https://doi.org/10.1021/acsanm.3c03787
[40] Fu, G., Wu, P., Zhang, S., Wang, L., Xu, M. and Huai, X. (2023) Improvement of Water Adsorption Performance of UiO-66 by Post-Synthetic Modification. Dalton Transactions, 52, 11671-11678.
https://doi.org/10.1039/d3dt01062g
[41] Fu, J., Liu, X., Huang, G. and Wang, Z. (2025) Multi-Strategy Optimized UiO-66 Composite for Simultaneous Efficient Adsorption and Visible-Light Degradation of Tetracycline in Wastewater. Chemical Engineering Journal, 505, Article 159260.
https://doi.org/10.1016/j.cej.2025.159260
[42] Liu, D., Chen, S., Wang, R., Li, L., Ji, J., Wu, T., et al. (2026) Bio-Based TEMPO-CNC Reinforced Fe-Doped UiO-66 with Hierarchical Porosity for Efficient Enrofloxacin Removal. Environmental Research, 290, Article 123475.
https://doi.org/10.1016/j.envres.2025.123475
[43] Liu, D., Wang, R., Wang, H., Ke, K., Li, L., Ji, J., et al. (2026) Engineering Cellulose Nanocrystal-Regulated UiO-66 as a Bifunctional Platform for Enhanced Fluoroquinolone Antibiotic Removal. Chemical Engineering Journal, 542, Article 178262.
https://doi.org/10.1016/j.cej.2026.178262
[44] Lu, W., Wang, C., Song, W., Zhang, Z., Xie, C. and Wang, J. (2024) High-Efficiency Photocatalytic Reduction of Cr(VI) by Z-Scheme Electron Transfer in UiO-66-NH2 @HDU-25 Heterojunctions. Journal of Materials Chemistry A, 12, 20149-20159.
https://doi.org/10.1039/d4ta03251a
[45] Wang, Q., Zheng, S., Ma, W., Qian, J., Huang, L., Deng, H., et al. (2024) Facile Synthesis of Direct Z-Scheme PPy/NH2-UiO-66 Heterojunction for Enhanced Photocatalytic Cr(VI) Reduction, Industrial Electroplating Wastewater Treatment, and Tetracycline Degradation. Applied Catalysis B: Environment and Energy, 344, Article 123669.
https://doi.org/10.1016/j.apcatb.2023.123669
[46] Huong, V.T., Duc, B.V., An, N.T., Anh, T.T.P., Aminabhavi, T.M., Vasseghian, Y., et al. (2024) 3D-Printed WO3-UiO-66@Reduced Graphene Oxide Nanocomposites for Photocatalytic Degradation of Sulfamethoxazole. Chemical Engineering Journal, 483, Article 149277.
https://doi.org/10.1016/j.cej.2024.149277
[47] Li, J., Liu, Y., Ai, Y., Alsaedi, A., Hayat, T. and Wang, X. (2018) Combined Experimental and Theoretical Investigation on Selective Removal of Mercury Ions by Metal Organic Frameworks Modified with Thiol Groups. Chemical Engineering Journal, 354, 790-801.
https://doi.org/10.1016/j.cej.2018.08.041
[48] Saha Chowdhury, S., Bera, B. and De, S. (2023) In-Situ Synthesis of Dual Functionalized MOF by Engineering Modulator Induced Defect for Efficient Remediation of Aqueous Mercury through Adsorption. Journal of Environmental Chemical Engineering, 11, Article 111332.
https://doi.org/10.1016/j.jece.2023.111332
[49] Zhao, P., Liu, N., Jin, C., Chen, H., Zhang, Z., Zhao, L., et al. (2019) UiO-66: An Advanced Platform for Investigating the Influence of Functionalization in the Adsorption Removal of Pharmaceutical Waste. Inorganic Chemistry, 58, 8787-8792.
https://doi.org/10.1021/acs.inorgchem.9b01172
[50] Wu, M., Zhang, Q., Zhang, Q., Wang, H., Wang, F., Liu, J., et al. (2022) Research Progress of UiO-66-Based Electrochemical Biosensors. Frontiers in Chemistry, 10, Article 842894.
https://doi.org/10.3389/fchem.2022.842894
[51] Cui, Y., Yue, Y., Qian, G. and Chen, B. (2012) Luminescent Functional Metal-Organic Frameworks. Chemical Reviews, 112, 1126-1162.
https://doi.org/10.1021/cr200101d
[52] Liu, J., Wang, X., Zhao, Y., Xu, Y., Pan, Y., Feng, S., et al. (2022) NH3 Plasma Functionalization of UiO-66-NH2 for Highly Enhanced Selective Fluorescence Detection of U(VI) in Water. Analytical Chemistry, 94, 10091-10100.
https://doi.org/10.1021/acs.analchem.2c01138
[53] Peng, M., Zeng, D., Lu, Y., Du, E., Zhang, Y. and Fu, J. (2025) A Highly Sensitive Method for Cr(VI) Sensing in Water with a Fluorescence Probe Constructed with the Defective UiO-66. Inorganica Chimica Acta, 577, Article 122492.
https://doi.org/10.1016/j.ica.2024.122492
[54] Ma, Y., Li, M., Gao, G., Luo, S., Cao, Y., Qi, X., et al. (2024) Coordination Compensated Metal-Organic Framework Fluorescent Sensor for Highly Selective and Sensitive Dual-Detection of Phosphate and Hydrogen Sulfide. Sensors and Actuators B: Chemical, 409, Article 135621.
https://doi.org/10.1016/j.snb.2024.135621
[55] Al-Shaeli, M., Smith, S.J.D., Jiang, S., Wang, H., Zhang, K. and Ladewig, B.P. (2021) Long-Term Stable Metal Organic Framework (MOF) Based Mixed Matrix Membranes for Ultrafiltration. Journal of Membrane Science, 635, Article 119339.
https://doi.org/10.1016/j.memsci.2021.119339
[56] Xu, R., Liu, X., Zhu, C., Pan, Y., Cheng, S., Ren, X., et al. (2023) UiO-66-NH2 MOF/Organosilica Mixed-Matrix Membrane for Water Desalination. Journal of Membrane Science, 685, Article 121913.
https://doi.org/10.1016/j.memsci.2023.121913
[57] Shen, Y., Sawyerr, F., Xu, L., Shen, S. and Zhou, X. (2024) Mixed Matrix Membranes by Post-Modified UiO-66-NH2 for Efficient Treatment of Dyeing Wastewater. Desalination and Water Treatment, 320, Article 100886.
https://doi.org/10.1016/j.dwt.2024.100886
[58] Kebede Gurmessa, B., Taddesse, A.M. and Teju, E. (2023) UiO-66 (Zr-MOF): Synthesis, Characterization, and Application for the Removal of Malathion and 2, 4-D from Aqueous Solution. Environmental Pollutants and Bioavailability, 35, Article 2222910.
https://doi.org/10.1080/26395940.2023.2222910
[59] Liu, P., Lyu, J. and Bai, P. (2023) One-Step Synthesis of Al-Doped UiO-66 Nanoparticle for Enhanced Removal of Organic Dyes from Wastewater. Molecules, 28, Article 2182.
https://doi.org/10.3390/molecules28052182
[60] Ji, S. and Abdel-Fattah, T.M. (2025) Advancing Arsenic Water Treatment Using UiO-66 and Its Functionalized Metal-Organic Framework Analogs. Nanomaterials, 15, Article 1621.
https://doi.org/10.3390/nano15211621
[61] Huo, J., Xu, L., Chen, X., Zhang, Y., Yang, J.E., Yuan, B., et al. (2019) Direct Epitaxial Synthesis of Magnetic Fe3O4@UiO-66 Composite for Efficient Removal of Arsenate from Water. Microporous and Mesoporous Materials, 276, 68-75.
https://doi.org/10.1016/j.micromeso.2018.09.017
[62] Bůžek, D., Adamec, S., Lang, K. and Demel, J. (2021) Metal-Organic Frameworks vs. Buffers: Case Study of UiO-66 Stability. Inorganic Chemistry Frontiers, 8, 720-734.
https://doi.org/10.1039/d0qi00973c
[63] Li, Y. and Wang, W.X. (2024) Toxic Effects and Action Mechanism of Metal-Organic Framework UiO-66-NH2 in Microcystis Aeruginosa. Environmental Pollution, 346, Article 123595.
https://doi.org/10.1016/j.envpol.2024.123595
[64] Chakraborty, S., Dhumal, P., Mikulska, I., Pham, S., Ellis (Bradford), L., Menon, D., et al. (2025) Biotic Transformation of Abiotically Stable Nanoscale UiO-66 Metal-Organic Framework by Daphnia magna Results in Chronic Reproductive Toxicity. ACS Nano, 19, 41874-41887.
https://doi.org/10.1021/acsnano.5c16532
[65] Yang, G., Wu, Q., Xiao, G. and Ye, X. (2025) UiO-66-(COOH)2 Decorated Collagen Fiber Membranes for High-Efficiency Separation of Cationic Surfactant-Stabilized Oil/Water Emulsions: Toward Sustainable and Robust Wastewater Treatment. Polymers, 17, Article 2879.
https://doi.org/10.3390/polym17212879
[66] Eltaweil, A.S., Mamdouh, I.M., Abd El-Monaem, E.M. and El-Subruiti, G.M. (2021) Highly Efficient Removal for Methylene Blue and Cu2+ onto UiO-66 Metal-Organic Framework/Carboxylated Graphene Oxide-Incorporated Sodium Alginate Beads. ACS Omega, 6, 23528-23541.
https://doi.org/10.1021/acsomega.1c03479
[67] Moaty, S.A.A., Kotp, A.A., Salah, A.M., Farghali, A.A. and Eldin, Z.E. (2025) Application of UiO-66 MOF for Rifampicin Removal and Post-Adsorption Antimicrobial Activity against MRSA. Scientific Reports, 15, Article No. 25768.
https://doi.org/10.1038/s41598-025-10145-4
[68] Zhang, X., Dong, Q., Wang, Y., Zhu, Z., Guo, Z., Li, J., et al. (2022) Water-Stable Metal-Organic Framework (UiO-66) Supported on Zirconia Nanofibers Membrane for the Dynamic Removal of Tetracycline and Arsenic from Water. Applied Surface Science, 596, Article 153559.
https://doi.org/10.1016/j.apsusc.2022.153559
[69] Hou, C., Wei, N., Liang, Q., Tan, Y., Li, X. and Feng, J. (2024) Nano-Pesticide Delivery System Based on UiO-66 with pH Sensitivity for Precise Control of Spodoptera frugiperda. Pest Management Science, 81, 798-808.
https://doi.org/10.1002/ps.8483
[70] Meng, C., Lu, Z., Huang, G. and Wang, Z. (2026) Chitosan Aerogel Composited with Cu-Functionalized UiO-66-NO2 as Recyclable Adsorption of Primary Aromatic Amines in Wastewater. Water, 18, Article 971.
https://doi.org/10.3390/w18080971
[71] Cao, M. and Yang, W. (2024) Synthesis of Magnetic UiO-66-NH2@EDTA-GO and Mechanism Study of Simultaneous Adsorption of Pb(II) and Organic Dyes from Water. Reaction Chemistry & Engineering, 9, 317-338.
https://doi.org/10.1039/d3re00399j