MXene基吸波材料设计与研究进展
Design Strategies and Research Progress of MXene-Based Microwave Absorbing Materials
DOI: 10.12677/ms.2026.1610202, PDF,    科研立项经费支持
作者: 王 崴, 王婉琼, 李志标, 王金辉, 张玉晶*:南京理工大学材料科学与工程学院,江苏 南京;顾贤科*:安徽开阳科技有限公司,安徽 芜湖;奇瑞汽车股份有限公司,安徽 芜湖
关键词: MXene基吸波材料;电磁波吸收;阻抗匹配;异质结构;MXene-Based Microwave Absorbing Materials; Electromagnetic Wave Absorption; Impedance Matching; Heterostructure
摘要: 随着第五代/第六代移动通信技术的快速发展,电磁辐射污染问题日益严峻,研发轻质宽频高效吸波材料已成为迫切需要。MXene作为新型二维过渡金属碳化物/氮化物,凭借其独特层状结构与优异导电性在电磁吸波领域备受关注,但其过高的电导率导致阻抗匹配较差,单一损耗机制限制了吸波性能。本文系统综述了MXene基吸波材料的最新研究进展,从磁性氧化物复合、磁性金属复合和三维多孔结构构筑三方面阐述了多元异质结构设计与多重损耗协同对吸波性能的增强机制。研究表明,通过引入磁性组分优化阻抗匹配、构建异质界面增强极化损耗、设计三维网络促进多重散射,可显著提升吸波性能,最小反射损耗可达−61.3 dB,有效吸收带宽达7.04 GHz。最后展望了该领域面临的环境稳定性、多功能集成及规模化制备等挑战与发展方向。
Abstract: With the rapid advancement of fifth-generation (5G) and sixth-generation (6G) mobile communication technologies, electromagnetic radiation pollution has become increasingly severe, driving an urgent demand for lightweight, broadband, and high-efficiency microwave absorbing materials. MXene, as an emerging class of two-dimensional transition metal carbides/nitrides, has attracted considerable attention in the field of electromagnetic wave absorption due to its unique layered structure and exceptional electrical conductivity. However, the excessively high conductivity of pristine MXene leads to poor impedance matching, and its single loss mechanism restricts the overall absorption performance. This review systematically summarizes the recent progress in MXene-based microwave absorbing materials, elaborating on the enhancement mechanisms of microwave absorption performance through multicomponent heterostructure design and synergistic multiple loss effects from three perspectives: magnetic oxide compounding, magnetic metal compounding, and three-dimensional porous structure construction. It is demonstrated that the microwave absorption performance can be significantly improved by introducing magnetic components to optimize impedance matching, constructing heterointerfaces to intensify polarization loss, and designing three-dimensional networks to promote multiple scattering, achieving a minimum reflection loss of −61.3 dB and an effective absorption bandwidth of 7.04 GHz. Finally, the challenges and future directions in this field, including environmental stability, multifunctional integration, and scalable fabrication, are prospected.
文章引用:王崴, 王婉琼, 李志标, 王金辉, 顾贤科, 张玉晶. MXene基吸波材料设计与研究进展[J]. 材料科学, 2026, 16(10): 173-183. https://doi.org/10.12677/ms.2026.1610202

参考文献

[1] Elmahaishi, M.F., Azis, R.S., Ismail, I. and Muhammad, F.D. (2022) A Review on Electromagnetic Microwave Absorption Properties: Their Materials and Performance. Journal of Materials Research and Technology, 20, 2188-2220.
https://doi.org/10.1016/j.jmrt.2022.07.140
[2] Fang, G., Liu, C., Xu, G., Xiao, A., Peng, K., Zhang, Y., et al. (2019) Enhanced Microwave Absorption Properties of Zr4+-Doped Fe3O4 for Coordinated Impedance Matching and Attenuation Performances. Journal of Alloys and Compounds, 790, 316-325.
https://doi.org/10.1016/j.jallcom.2019.03.159
[3] 孙嘉豪. SiO2包覆碳纤维的介电调控及其宽频电磁波吸收性能的研究[D]: [硕士学位论文]. 哈尔滨: 哈尔滨工业大学, 2022.
[4] Naguib, M., Kurtoglu, M., Presser, V., Lu, J., Niu, J., Heon, M., et al. (2011) Two‐Dimensional Nanocrystals Produced by Exfoliation of Ti3AlC2. Advanced Materials, 23, 4248-4253.
https://doi.org/10.1002/adma.201102306
[5] Naguib, M., Mochalin, V.N., Barsoum, M.W. and Gogotsi, Y. (2014) 25th Anniversary Article: MXenes: A New Family of Two‐Dimensional Materials. Advanced Materials, 26, 992-1005.
https://doi.org/10.1002/adma.201304138
[6] Naguib, M., Mashtalir, O., Carle, J., Presser, V., Lu, J., Hultman, L., et al. (2012) Two-Dimensional Transition Metal Carbides. ACS Nano, 6, 1322-1331.
https://doi.org/10.1021/nn204153h
[7] Xiang, G., Chen, M., Ni, Z., Shen, Y. and Xu, L. (2021) Synthesis of a Hollow-Structured Flower-Like Fe3O4@MoS2 Composite and Its Microwave-Absorption Properties. RSC Advances, 11, 20180-20190.
https://doi.org/10.1039/d1ra02095a
[8] Xiong, D., Li, X., Bai, Z. and Lu, S. (2018) Recent Advances in Layered Ti3C2Tx MXene for Electrochemical Energy Storage. Small, 14, Article ID: 1703419.
https://doi.org/10.1002/smll.201703419
[9] Wyatt, B.C., Rosenkranz, A. and Anasori, B. (2021) 2D MXenes: Tunable Mechanical and Tribological Properties. Advanced Materials, 33, Article ID: 2007973.
https://doi.org/10.1002/adma.202007973
[10] Karahan, H.E., Goh, K., Zhang, C., Yang, E., Yıldırım, C., Chuah, C.Y., et al. (2020) MXene Materials for Designing Advanced Separation Membranes. Advanced Materials, 32, Article ID: 1906697.
https://doi.org/10.1002/adma.201906697
[11] Iqbal, A., Sambyal, P. and Koo, C.M. (2020) 2D MXenes for Electromagnetic Shielding: A Review. Advanced Functional Materials, 30, Article ID: 2000883.
https://doi.org/10.1002/adfm.202000883
[12] Tsounis, C., Kumar, P.V., Masood, H., Kulkarni, R.P., Gautam, G.S., Müller, C.R., et al. (2022) Advancing MXene Electrocatalysts for Energy Conversion Reactions: Surface, Stoichiometry, and Stability. Angewandte Chemie International Edition, 62, e202210828.
https://doi.org/10.1002/anie.202210828
[13] Li, X., You, W., Xu, C., Wang, L., Yang, L., Li, Y., et al. (2021) 3D Seed-Germination-Like MXene with in Situ Growing CNTs/Ni Heterojunction for Enhanced Microwave Absorption via Polarization and Magnetization. Nano-Micro Letters, 13, Article No. 157.
https://doi.org/10.1007/s40820-021-00680-w
[14] Abdolhosseinzadeh, S., Jiang, X., Zhang, H., Qiu, J. and Zhang, C. (2021) Perspectives on Solution Processing of Two-Dimensional MXenes. Materials Today, 48, 214-240.
https://doi.org/10.1016/j.mattod.2021.02.010
[15] 徐慧宁, 黎杰, 崔志刚, 等. MXene材料在交通领域的应用进展[J]. 哈尔滨工业大学学报, 2025, 57(12): 141-155.
[16] Swapnalin, J., Koneru, B., Banerjee, P., Natarajan, S. and Franco, A. (2022) Multilayer Intercalation: MXene/Cobalt Ferrite Electromagnetic Wave Absorbing Two-Dimensional Materials. Journal of Physics and Chemistry of Solids, 168, Article ID: 110797.
https://doi.org/10.1016/j.jpcs.2022.110797
[17] Zhang, X., Wang, H., Hu, R., Huang, C., Zhong, W., Pan, L., et al. (2019) Novel Solvothermal Preparation and Enhanced Microwave Absorption Properties of Ti3C2Tx MXene Modified by in Situ Coated Fe3O4 Nanoparticles. Applied Surface Science, 484, 383-391.
https://doi.org/10.1016/j.apsusc.2019.03.264
[18] Liu, P., Yao, Z., Ng, V.M.H., Zhou, J., Kong, L.B. and Yue, K. (2018) Facile Synthesis of Ultrasmall Fe3O4 Nanoparticles on MXenes for High Microwave Absorption Performance. Composites Part A: Applied Science and Manufacturing, 115, 371-382.
https://doi.org/10.1016/j.compositesa.2018.10.014
[19] He, J., Liu, S., Deng, L., Shan, D., Cao, C., Luo, H., et al. (2020) Tunable Electromagnetic and Enhanced Microwave Absorption Properties in CoFe2O4 Decorated Ti3C2 MXene Composites. Applied Surface Science, 504, Article ID: 144210.
https://doi.org/10.1016/j.apsusc.2019.144210
[20] Pan, F., Yu, L., Xiang, Z., Liu, Z., Deng, B., Cui, E., et al. (2021) Improved Synergistic Effect for Achieving Ultrathin Microwave Absorber of 1D Co Nanochains/2D Carbide MXene Nanocomposite. Carbon, 172, 506-515.
https://doi.org/10.1016/j.carbon.2020.10.039
[21] Wen, C., Li, X., Zhang, R., Xu, C., You, W., Liu, Z., et al. (2022) High-Density Anisotropy Magnetism Enhanced Microwave Absorption Performance in Ti3C2Tx MXene@Ni Microspheres. ACS Nano, 16, 1150-1159.
https://doi.org/10.1021/acsnano.1c08957
[22] Cui, Y., Liu, Z., Zhang, Y., Liu, P., Ahmad, M., Zhang, Q., et al. (2021) Wrinkled Three-Dimensional Porous MXene/Ni Composite Microspheres for Efficient Broadband Microwave Absorption. Carbon, 181, 58-68.
https://doi.org/10.1016/j.carbon.2021.05.022
[23] Cheng, H., Pan, Y., Li, W., Liu, C., Shen, C., Liu, X., et al. (2023) Facile Design of Multifunctional Melamine Foam with Ni-Anchored Reduced Graphene Oxide/MXene as Highly Efficient Microwave Absorber. Nano Today, 52, Article ID: 101958.
https://doi.org/10.1016/j.nantod.2023.101958
[24] Zhang, Y., Han, M., Hu, R., Zhang, P., Pan, L. and Sun, Z. (2024) Sandwiched MXene/Polyimide Composite Foams for Multiscale Microwave Absorption. Science China Materials, 67, 272-278.
https://doi.org/10.1007/s40843-023-2682-3
[25] Sun, T., Liu, Z., Li, S., Liu, H., Chen, F., Wang, K., et al. (2021) Effective Improvement on Microwave Absorbing Performance of Epoxy Resin-Based Composites with 3D MXene Foam Prepared by One-Step Impregnation Method. Composites Part A: Applied Science and Manufacturing, 150, Article ID: 106594.
https://doi.org/10.1016/j.compositesa.2021.106594