化学气相沉积法制备MoS2的研究进展
Research Progress on MoS2 Prepared by Chemical Vapor Deposition
摘要: 二维纳米结构的过渡族金属硫化物MoS2有着不同寻常的物理化学性质,在光电性能、可见光催化、润滑性和摩擦性方面有着广泛的应用价值。制备纳米结构MoS2有物理的和化学的方法,其中化学气相沉积是一种简便实用的生长大面积高质量MoS2的方法。本文详细讨论了化学气相沉积过程中反应时间、载气体流速、先驱体化学计量比和基体放置位置等因素对MoS2结构的影响。不同结构的MoS2其性质有决定性的影响,使得这种层状二维材料获得广泛的应用。
Abstract: Nanostructured MoS2, a two dimensional transition-metal dichalcogenides, has found extensive application in phtotoelectricity, visible light catalysts, lubricity and friction performance because of its unusual physical and chemical properties. Chemical vapor deposition is one of the most practical methods to prepare the large area and high quality MoS2 among all the physical or chemical methods. This paper reviews the effect of the reaction time, carrier gas flow rate, stoichiometric ratio of precursors and substrate position on the morphology and structure of MoS2. Two- dimensional layered MoS2 may find optimal utilizations since its property varies significantly with different structures.
文章引用:王洁, 陈秋月, 张永平. 化学气相沉积法制备MoS2的研究进展[J]. 材料化学前沿, 2017, 5(1): 1-10. https://dx.doi.org/10.12677/AMC.2017.51001

参考文献

[1] Remskar, M., Mrzel, A., Skraba, Z., et al. (2001) Self-Assembly of Subnanometer-Diameter Single-Wall MoS2 Nanotubes. Science, 292, 479-481. [Google Scholar] [CrossRef] [PubMed]
[2] Remskar, M. (2004) Inorganic Nanotubes. Advanced Materials, 16, 1497-1504. [Google Scholar] [CrossRef
[3] Nath, M., Govindaraj, A. and Rao, C.N.R. (2001) Simple Synthesis of MoS2 and WS2 Nanotubes. Advanced Materials, 13, 283-286. [Google Scholar] [CrossRef
[4] Rao, C.N.R. and Nath, M. (2003) Inorganic Nanotubes. Dalton Transactions, 2003, 1-24. [Google Scholar] [CrossRef
[5] Enyashin, A.N., Gemming, S., Bar-Sadan, M., et al. (2007) Structure and Stability of Molybdenum Sulfide Fullerenes. Angewandte Chemie International Edition, 46, 623-627. [Google Scholar] [CrossRef] [PubMed]
[6] Tian, Y., He, Y. and Zhu, Y. (2004) Low Temperature Synthesis and Characterization of Molybdenum Disulfide Nanotubes and Nanorods. Materials Chemistry and Physics, 87, 87-90. [Google Scholar] [CrossRef
[7] Han, S., Yuan, C., Luo, X., et al. (2015) Horizontal Growth of MoS2 Namowires by Chemical Vapour Deposition. RSC Advances, 5, 68283. [Google Scholar] [CrossRef
[8] Cheng, Y., Yao, K., Yang, Y., et al. (2013) Van der Waals Epitaxial Growth of MoS2 on SiO2/Si by Chemical Vapor Deposition. RSC Advances, 3, 17287-17293. [Google Scholar] [CrossRef
[9] Cao, Y., Luo, X., Han, S., et al. (2015) Influences of Carrier Gas Flow Rate on the Morphologies of MoS2 Flakes. Chemical Physics Letters, 631, 30-33. [Google Scholar] [CrossRef
[10] Radisavljevic, B., Radenovic, A., Brivio, J., et al. (2011) Single-Layer MoS2 Transistors. Nature Nanotechnology, 6, 147-150. [Google Scholar] [CrossRef] [PubMed]
[11] Mak, K.F., Lee, C., Hone, J., Shan, J. and Heinz, T. (2010) Atomically Thin MoS2: A New Direct-Gap Semiconductor. Physical Review Letters, 105, Article ID: 136805. [Google Scholar] [CrossRef
[12] Splendiani, A., Sun, L., Zhang, Y., et al. (2010) Emerging Photoluminescence in Monolayer MoS2. Nano Letters, 10, 1271-1275. [Google Scholar] [CrossRef] [PubMed]
[13] Eda, G., Yamaguchi, H., Voiry, D., et al. (2011) Photoluminescence from Chemically Exfoliated MoS2. Nano Letters, 11, 5111-5116. [Google Scholar] [CrossRef] [PubMed]
[14] Radisavljevic, B., Whitwick, M.B. and Kis, A. (2011) Integrated Circuits and Logic Operations Based on Single-Layer MoS2. ACS Nano, 5, 9934-9938. [Google Scholar] [CrossRef] [PubMed]
[15] Yin, Z., Li, H., Li, H., et al. (2011) Single-Layer MoS2 Phototransistors. ACS Nano, 6, 74-80. [Google Scholar] [CrossRef] [PubMed]
[16] He, Q., Zeng, Z., Yin, Z., et al. (2012) Fabrication of Flexible MoS2 Thin-Film Transistor Arrays for Practical Gas-Sensing Applications. Small, 8, 2994-2999. [Google Scholar] [CrossRef] [PubMed]
[17] Liu, J., Zeng, Z., Cao, X., et al. (2012) Preparation of MoS2-Polyvinylpyrrolidone Nanocomposites for Flexible Nonvolatile Rewritable Memory Devices with Reduced Graphene Oxide Electrodes. Small, 8, 3517-3522. [Google Scholar] [CrossRef] [PubMed]
[18] Wang, H., Yu, L., Lee, Y.H., et al. (2012) Integrated Circuits Based on Bilayer MoS2 Transistors. Nano Letters, 12, 4674-4680. [Google Scholar] [CrossRef] [PubMed]
[19] Pu, J., Yomogida, Y., Liu, K.K., et al. (2012) Highly Flexible MoS2 Thin-Film Transistors with Ion Gel Dielectrics. Nano Letters, 12, 4013-4017. [Google Scholar] [CrossRef] [PubMed]
[20] Wang, Q.H., Kalantar-Zadeh, K., Kis, A., Coleman, J.N. and Strano, M.S. (2012) Electronics and Optoelectronics of Two-Dimensional Transition Metal Dichalcogenides. Nature Nanotechnology, 7, 699-712. [Google Scholar] [CrossRef] [PubMed]
[21] Zhang, Z.J., Zhang, J. and Xue, Q.J. (1994) Synthesis and Characterization of a Molybdenum Disulfide Nanocluster. The Journal of Physical Chemistry, 98, 12973-12977. [Google Scholar] [CrossRef
[22] Benavente, E., Santa, M.A., Mendizabal, F. and González, G. (2002) Intercalation Chemistry of Molybdenum Disulfide. Coordination Chemistry Reviews, 224, 87-109. [Google Scholar] [CrossRef
[23] Coleman, J.N., Lotya, M., Oneill, A., et al. (2011) Two-Dimensional Nanosheets Produced by Liquid Exfoliation of Layered Materials. Science, 331, 568-571. [Google Scholar] [CrossRef] [PubMed]
[24] Huang, X., Zeng, Z. and Zhang, H. (2013) Metal Dichalcogenide Nanosheets: Preparation, Properties and Applications. Chemical Society Reviews, 42, 1934-1946. [Google Scholar] [CrossRef] [PubMed]
[25] Fleischauer, P.D., Lince, J.R., Bertrand, P.A. and Bauer, R. (1989) Electronic Structure and Lubrication Properties of Molybdenum Disulfide: A Qualitative Molecular Orbital Approach. Langmuir, 5, 1009-1015. [Google Scholar] [CrossRef
[26] 王轩, 宋礼, 陈露, 宋欢欢, 张永平. 二硫化钼纳米片的研究进展[J]. 材料化学前沿, 2014, 2(4): 49-62.
[27] Smorygo, O., Vomnin, S., Bertrand, P. and Smurov, I. (2004) Fabrication of Thick Molybdenum Disulphide Coatings by Thermal-Diffusion Synthesis. Tribology Letters, 17, 723-726. [Google Scholar] [CrossRef
[28] Wang, H., Xu, B., Liu, J. and Zhuang, D. (2005) Microstructures and Tribological Pmperties on the Composite MoS2 Films Prepared by a Novel Two-Step Method. Materials Chemistry and Physics, 91, 494-499. [Google Scholar] [CrossRef
[29] Benameur, M.M., Radisavljevic, B., Heron, J.S., Sahoo, S., Berger, H. and Kis, A. (2011) Visibility of Dichalcogenide Nanolayers. Nanotechnology, 22, Article ID: 125706. [Google Scholar] [CrossRef] [PubMed]
[30] Wang, J., Lauwerens, W., Wieers, E., Stals, L.M., He, J. and Celis, J.P. (2001) Structure and Tribological Properties of MoSx Coatings Prepared by Bipolar DC Magnetron Sputtering. Surface and Coatings Technology, 139, 143-152. [Google Scholar] [CrossRef
[31] Sen, R., Govindaraj, A., Suenaga, K., et al. (2001) Encapsulated and Hollow Closed-Cage Structures of WS2 and MoS2 Prepared by Laser Ablation at 450-1050˚C. Chemical Physics Letters, 340, 242-248. [Google Scholar] [CrossRef
[32] Chhowalla, M. and Amaratunga, G.A.J. (2000) Thin Films of Full-erenc-Like MoS2 Nanoparticles with Ultra-Low Friction and Wear. Nature, 40, 164-167. [Google Scholar] [CrossRef] [PubMed]
[33] Zhang, S.L., Choi, H.H., Yue, H. and Yang, W. (2014) Controlled Exfoliation of Molybdenum Disulfide for Developing Thin Film Humidity Sensor. Current Applied Physics, 14, 264-268. [Google Scholar] [CrossRef
[34] Hwang, H., Kim, H. and Cho, J. (2011) MoS2 Nanoplates Consisting of Disordered Graphene-Like Layers for High Rate Lithium Battery Anode Materials. Nano Letters, 11, 4826-4830. [Google Scholar] [CrossRef] [PubMed]
[35] Wang, X., Ding, J., Yao, S., et al. (2014) High Supercapacitor and Adsorption Behaviors of Flower-Like MoS2 Nanostructures. Journal of Materials Chemistry A, 2, 15958-15963. [Google Scholar] [CrossRef
[36] Bezverkhy, I., Afanasiev, P. and Lacroix, M. (2000) Aqueous Preparation of Highly Dispersed Molybdenum Sulfide. Inorganic Chemistry, 39, 5416-5417. [Google Scholar] [CrossRef] [PubMed]
[37] Bezverkhy, I., Afanasiev, P. and Lacroix, M. (2005) Promotion of Highly Loaded MoS2/Al2O3 Hydrodesulfurization Catalysts Prepared in Aqueous Solution. Journal of Catalysis, 230, 133-139. [Google Scholar] [CrossRef
[38] Afanasiev, P., Geantet, C., Thomazeau, C. and Jouget, B. (2000) Molybdenum Polysulfide Hollow Microtubules Grown at Room Temperature from Solution. Chemical Communications, 2000, 1001-1002. [Google Scholar] [CrossRef
[39] Afanasiev, P. and Bezverkhy, I. (2003) Genesis of Vesicle-Like and Tubular Morphologies in Inorganic Precipitates: Amorphous Mo Oxysulfides. The Journal of Physical Chemistry B, 107, 2678-2683. [Google Scholar] [CrossRef
[40] Muijsers, J.C., Weber, T., Vanhardeveld, R.M., Zandbergen, H.W. and Niemantsverdriet, J.W. (1995) Sulfidation Study of Molybdenum Oxide Using MoO3/SiO2/Si (100) Model Catalysts and Mo-IV 3-Sulfur Cluster Compounds. Journal of Catalysis, 157, 698-705. [Google Scholar] [CrossRef
[41] Wang, X. and Zhang, Y. (2016) Tuning the Structure of MoO3 Nanoplates via MoS2 Oxidation. Philosophical Magazine Letters, 96, 347-354. [Google Scholar] [CrossRef
[42] Wang, X., Zhang, Y.P. and Chen, Z.Q. (2016) Effect of MoO3 Constituents on the Growth of MoS2 Nanosheets by Chemical Vapor Deposition. Materials Research Express, 3, Article ID: 065014.
[43] Wang, X., Zhang, Y.P. and Chen, Z.Q. (2016) Morphological Evolution of MoS2 Nanosheets by Chemical Vapor Deposition. Chalcogenide Letters, 13, 351-357.
[44] Cao, Y., Luo, X., Yuan, C., et al. (2015) Morphology Engineering of Monolayer MoS2 by Adjusting Chemical Environment during Growth. Physica E: Low-Dimensional Systems and Nanostructures, 74, 292-296. [Google Scholar] [CrossRef
[45] Han, S., Luo, X., Cao, Y., et al. (2015) Morphology Evolution of MoS2 Nanorods Grown by Chemical Vapor Deposition. Journal of Crystal Growth, 430, 1-6. [Google Scholar] [CrossRef
[46] Smith, R.J., King, P.J., Lotya, M., et al. (2011) Large-Scale Exfoliation of Inorganic Layered Compounds in Aqueous Surfactant Solutions. Advanced Maters, 23, 3944-3948. [Google Scholar] [CrossRef] [PubMed]
[47] Lee, H.S., Min, S.W., Chang, Y.G., et al. (2012) MoS2 Nanosheet Phototransistors with Thickness-Modulated Optical Energy Gap. Nano Letters, 12, 3695-3700. [Google Scholar] [CrossRef] [PubMed]
[48] Yang, H., Huang, C., Li, X., Shi, R. and Zhang, K. (2005) Luminescent and Photocatalytic Properties of Cadmium Sulfide Nanoparticles Synthesized via Microwave Irradiation. Materials Chemistry and Physics, 90, 155-158. [Google Scholar] [CrossRef
[49] Payen, E., Hubaut, R., Kasztelan, S., Poulet, O. and Grimblot, J. (1994) Morphology Study of MoS2- and WS2-Based Hydrotreating Catalysts by High-Resolution Electron Microscopy. Journal of Catalysis, 147, 123-132. [Google Scholar] [CrossRef
[50] Miremadi, B.K. and Morrison, S.R. (1987) High Activity Catalyst from Exfoliated MoS2. Journal of Catalysis, 103, 334-345. [Google Scholar] [CrossRef
[51] Cizaire, L., Vacher, B., Le Mogne, T., et al. (2002) Mechanisms of Ultra-Low Friction by Hollow Inorganic Fullerene-Like MoS2 Nanoparticles. Surface and Coatings Technology, 160, 282-287. [Google Scholar] [CrossRef
[52] Yu, L.G., Zhang, P.Y. and Du, Z.L. (2000) Tribological Behavior and Structural Change of the LB Film of MoS2 Nanoparticles Coated with Dialkyldithiophosphate. Surface Coatings Technology, 130, 110-115. [Google Scholar] [CrossRef
[53] Chen, Z., Liu, X., Liu, Y., Selda, G. and Luo, J. (2015) Ultrathin MoS2 Nanosheets with Superior Extreme Pressure Property as Boundary Lubricants. Science Reports, 5, Article Number: 12869.
[54] Hu, J.J., Bultman, J.E. and Zabinski, J.S. (2006) Microstructure and Lubrication Mechanism of Multilayered MoS2/ Sb2O3 Thin Films. Tribology Letters, 21, 169-174. [Google Scholar] [CrossRef
[55] Rapoport, L., Nepomnyashchy, O., Verdyan, A., et al. (2004) Polymer Nanocomposites with Fullerene-Like Solid Lubricant. Advanced Engineering Materials, 6, 44-48. [Google Scholar] [CrossRef
[56] Hu, K.H., Wang, J., Schraube, S., et al. (2007) Tribological Behavior of Self-Lubrication Bearing Materials of Steel- Copper-Polyoxymethylene Containing MoS2-IC Nanoparticles. ASME/STLE 2007 International Joint Tribology Conference, San Diego, 22-24 October 2007, 787-789. [Google Scholar] [CrossRef
[57] Wang, J., Hu, K.H., Xu, Y.F. and Hu, X.G. (2008) Structural, Thermal, and Tribological Properties of Intercalated Polyoxymethylene/Molybdenum Disulfide Nanocomposites. Journal of Applied Polymer Science, 110, 91-96. [Google Scholar] [CrossRef
[58] Liu, W.M., Huang, C.X., Gao, L., Wang, J. and Dang, H. (1991) Study of the Friction and Wear Properties of MoS2-Filled Nylon 6. Wear, 151, 111-118. [Google Scholar] [CrossRef