改性聚醚砜复合膜的制备及对腐殖酸去除性能研究
Fabrication of the Modified Polyethersulfone Nanocomposite Membrane for the Humic Acid Separation
DOI: 10.12677/HJCET.2017.74023, PDF,    科研立项经费支持
作者: 胡滋苗, 黄健*, 唐世刚:丽水学院化学化工系,浙江 丽水;韩守臣:浙江池河科技有限公司,浙江 丽水
关键词: 复合膜腐殖酸荷电改性分离Nanocomposite Membrane Humic Acid Charge Modification Separation
摘要: 将聚乙烯吡咯烷酮(PVP)修饰在介孔二氧化硅(MS)表面,制成MS-PVP纳米粒子,然后将其加入到聚醚砜中,利用相转化制备出PES/MS-PVP复合膜。利用场发射扫描电镜观察了复合膜的表面和断面形貌,并对复合膜的分离性能进行了测试。将复合膜表面进行荷电改性后,用于天然水体中腐殖酸(Humic Acid, HA)的分离,结果表明,荷电改性复合膜对HA的截留率达96%,可用于饮用水的深度处理。
Abstract: Polyvinylpyrrolidone (PVP) was modified on the surface of mesoporous silica (MS) to prepare MS-PVP nanoparticles, and then added to polyethersulfone. PES/MS-PVP composite membranes were fabricated by phase inversion. The surface and cross-sectional morphology of the composite films were observed by field emission scanning electron microscopy (SEM), and the separation performance of the composite films was investigated. Then the membrane surfaces were charge modified to enhance the separation performance for the (Humic Acid, HA); the results showed that the separation of HA was 96%, which could be used for the treatment of drinking water.
文章引用:胡滋苗, 黄健, 唐世刚, 韩守臣. 改性聚醚砜复合膜的制备及对腐殖酸去除性能研究[J]. 化学工程与技术, 2017, 7(4): 154-161. https://doi.org/10.12677/HJCET.2017.74023

参考文献

[1] Gao, X.L., Wang, H. and Wang, J. (2013) Surface Modified PSF UF Membrane by UV-Assisted Graft Polymerization of Capsaicin Derivative Moiety for Fouling and Bacterial Resistance. Journal of Membrane Science, 445, 146-155. [Google Scholar] [CrossRef
[2] Chen, B.L., Li, T. and Crittenden, J. (2013) High Performance Ultrafiltration Membrane Composed of PVDF Blended with Its Derivative Copolymer PVDF-g-PEGMA. Journal of Membrane Science, 445, 66-75. [Google Scholar] [CrossRef
[3] Kari, J.V., Nancy, H.L. and Yoram, C. (2013) Biofouling and Cleaning Effec-tiveness of Surface Nanostructured Reverse Osmosis Membranes. Journal of Membrane Science, 446, 472-481. [Google Scholar] [CrossRef
[4] Ratna, F.S., Yang, S.H. and Jaehoon, K. (2013) A New Strategy for Ultralow Biofouling Membranes: Uniform and Ultrathin Hydrophilic Coatings Using Liquid Carbon Dioxide. Journal of Membrane Science, 440, 88-97. [Google Scholar] [CrossRef
[5] Nuri, A., Berrin, A. and Nadir, D. (2013) Investigation of Characterization and Biofouling Properties of PES Membrane Containing Selenium and Copper Nanoparticles. Journal of Membrane Science, 437, 216-226. [Google Scholar] [CrossRef
[6] Zhang, G.L., Lu, S.F. and Zhang, L. (2013) Novel Polysulfone Hybrid Ultra-filtration Membrane Prepared with TiO2-g- HEMA and Its Antifouling Characteristics. Journal of Membrane Science, 436, 163-173. [Google Scholar] [CrossRef
[7] Razmjou, A., Mansouri, J. and Chen, V. (2011) The Effects of Mechanical and Chemical Modification of TiO2 Nanoparticles on the Surface Chemistry, Structure and Fouling Performance of PES Ultrafiltration Membranes. Journal of Membrane Science, 378, 73-84. [Google Scholar] [CrossRef
[8] Yan, L., Li, Y.S. and Xiang, C.B. (2005) Preparation of Poly (Vinylidene Fluoride) Ultrafiltration Membrane Modified by Nano-Sized Alumina (Al2O3) and Its Antifouling Research. Polymer, 46, 7701-7706. [Google Scholar] [CrossRef
[9] Huang, J., Zhang, K.S. and Wang, K. (2012) Fabrication of Polyethersul-fone-Mesoporous Silica Nanocomposite Ultrafiltration Membranes with Antifouling Properties. Journal of Membrane Science, 423-424, 362-370. [Google Scholar] [CrossRef
[10] Wu, G., Gan, S. and Cui, L. (2008) Preparation and Characterization of PES/TiO2 Composite Membranes. Applied Surface Science, 254, 7080-7086. [Google Scholar] [CrossRef
[11] Yang, Y., Zhang, H. and Wang, P. (2007) The Influence of Nano-Sized TiO2 Fill-ers on the Morphologies and Properties of PSF UF Membrane. Journal of Membrane Science, 288, 231-238. [Google Scholar] [CrossRef
[12] Mansourpanah, Y., Madaeni, S.S. and Rahimpour, A. (2009) Formation of Appro-priate Sites on Nanofiltration Membrane Surface for Binding TiO2 Photo-Catalyst: Performance, Characterization, and Fouling-Resistant Capability. Journal of Membrane Science, 330, 297-306. [Google Scholar] [CrossRef
[13] Rahimpour, A., Madaeni, S.S., Taheri, A.H., et al. (2008) Coupling TiO2 Nanoparticles with UV Irradiation for Modification of Polyethersulfone Ultra-filtration Membranes. Journal of Membrane Science, 313, 158-169. [Google Scholar] [CrossRef
[14] Irani, M., Keshtkar, A.R. and Mousavian, M.A. (2011) Removal of Cd(II) and Ni(II) from Aqueous Solution by PVA/TEOS/TMPTMS Hybrid Membrane. Chemical Engineering Journal, 175, 251-259. [Google Scholar] [CrossRef
[15] Wu, Z.X., Li, Q., Feng, D., et al. (2010) Ordered Mesoporous Crystalline-γ-Al2O3 with Variable Architecture and Porosity from a Single Hard Template. Journal of the American Chemical Society, 132, 12042-12050. [Google Scholar] [CrossRef] [PubMed]
[16] Deng, Z., Chen, M., Zhou, S., et al. (2006) A Novel Method for the Fabrication of Mon-odisperse Hollow Silica Spheres. Langmuir, 22, 6403-6407. [Google Scholar] [CrossRef] [PubMed]
[17] Cheng, X.J., Chen, M., Wu, L.M., et al. (2006) Novel and Facile Method for the Preparation of Monodispersed Titania Hollow Spheres. Langmuir, 22, 3858-3863. [Google Scholar] [CrossRef] [PubMed]
[18] Chen, M., Hu, L., Xu, J., et al. (2011) ZnO Hollow Sphere Nanofilm Based High Per-formance and Low Cost Photodetector. Small, 7, 2449-2453.
[19] 彭茜, 王平, 殷永泉. 不同pH值下腐殖酸反渗透膜污染中的界面相互作用解析[J]. 中国环境科学, 2011, 31(4): 616-621.
[20] 喻瑶, 许光红, 林洁. 太湖原水中膜污染物质的确定与表征[J]. 中国环境科学, 2012, 32(11): 2067-2074.
[21] 侯娟, 邵嘉慧, 何义亮. 荷电超滤膜对天然有机物去除及膜污染行为的影响[J]. 环境科学, 2010, 31(6): 1525- 1531.
[22] 丁一, 梁恒国, 刘滔. 天然有机物在超滤过程中的膜污染和膜清洗[J]. 西南给排水, 2004, 26(3): 11-12.