不同臭氧预处理工艺组合常规工艺对西氿水中CODMn和UV254的去除效果
The Removal Performance of CODMn and UV254 in Xijiu Lake by Combination of Different Ozone Pretreatment Process and Conventional Process
DOI: 10.12677/WPT.2018.61002, PDF,    科研立项经费支持
作者: 王致远, 吴 敏, 高乃云:同济大学环境科学与工程学院,污染控制与资源化研究国家重点实验室,上海;吕药灵:上海城市建设设计研究总院(集团)有限公司,上海
关键词: CODMnUV254臭氧预处理组合工艺CODMn UV254 Ozone Pretreatment Combined Process
摘要: 常规工艺对西氿水中的CODMn和UV254处理效果不佳。并且,由于原水中较高的本底值,出水中的CODMnUV254已无法满足日趋严格的国家标准。因此考虑采用臭氧相关预处理工艺以保障出水水质。研究发现,采用常规工艺时,CODMnUV254的去除率分别为29.96%~33.73%和24.11%~37.89%;采用预臭氧(O3)–常规工艺时,预臭氧投加量为2.17 mg/L时,CODMn去除率在30.93%~38.11%,UV254去除率在32.04%~45.63%;采用O3/H2O2–常规工艺时,CODMn和UV254的去除率分别为48.78%~49.69% 和41.52%~49.38%;采用O3/UV预处理工艺时,与相同臭氧投加量的单一臭氧预处理单元相比,对CODMnUV254的去除率分别提高了4.74%~26.29%和7.34%~22.94%。
Abstract: The CODMn and UV254 in Xijiu Lake could be slightly removed by conventional process. Moreover, the CODMn and UV254 in effluent can’t satisfy the standard for drinking water quality of GB5749-2006 due to the high background level in raw water. Thus, it is to be considered to add with pretreatment process involved ozone to ensure water quality. It was founded by research that the removal efficiency of CODMn and UV254 was 29.96% - 33.73% and 24.11% - 37.89% respectively when conventional process was adopted, the quality of effluent can’t reach the standard stably. The removal efficiency of CODMn and UV254 was 30.93% - 38.11% and 32.04% - 45.63% respectively when combination of ozone and conventional process was adopted (the amount ozone was 2.17 mg/L). It was partly better than conventional process but still can’t reach the standard stably. The removal efficiency of CODMn and UV254 was 48.78% - 49.69% and 41.52% - 49.38% when combination of ozone/hydrogen peroxide and conventional process was adopted, the quality of effluent was better than first two process and more stable. Comparing with single ozone pre-treatment unit in same ozone amount, the removal efficiency of CODMn and UV254 was improved by 4.74% - 26.29% and 7.34% - 22.94%.
文章引用:王致远, 吕药灵, 吴敏, 高乃云. 不同臭氧预处理工艺组合常规工艺对西氿水中CODMn和UV254的去除效果[J]. 水污染及处理, 2018, 6(1): 7-17. https://doi.org/10.12677/WPT.2018.61002

参考文献

[1] 张娜, 刘永泽, 李若愚, 封莉, 马辉, 张立秋. 臭氧预氧化对焦化废水中有机污染物的去除规律研究[C]//2016全国水环境污染控制与生态修复技术高级研讨会论文集, 2016.
[2] 邱壮, 王锐, 金鹏康, 臭氧预氧化–混凝深度处理印染二级生化出水[J]. 印染, 2016(17): 15-19.
[3] 谭娟, 于衍真, 冯岩. 臭氧预氧化在废水处理中的研究进展[J]. 江苏化工, 2008, 36(1): 39-44.
[4] 赵亮, 李星, 杨艳玲. 臭氧预氧化技术在给水处理中的研究进展[J]. 供水技术, 2009(4): 6-10.
[5] 胡俊生, 任雪冬, 马广韬, 郝苓汀, 孙剑平. 臭氧高级氧化技术处理酸性红B染料废水[J]. 沈阳建筑大学学报(自然科学版), 2009, 25(2): 320-324.
[6] 刘芬, 魏东洋, 许振成, 李杰. 催化臭氧降解氯苯类化合物的研究进展[J]. 广东化工, 2009, 36(9): 62-63.
[7] Edwards, M. and Benjamin, M.M. (1991) A Mechanistic Study of Ozone-Induced Particle Destabilization. Journal of American Water Works Associa-tion, 83, 96-105.
[8] Siddiqui, M.S., Amy, G.L. and Murphy, B.D. (1997) Ozone Enhanced Removal of Natural Organic Matter from Drinking Water Sources. Water Research, 31, 3098-3106.
[Google Scholar] [CrossRef
[9] Yan, M., Wang, D., Shi, B., Wang, M. and Yan, Y. (2007) Effect of Pre-Ozonation on Optimized Coagulation of a Typical North-China Source Water. Chemosphere, 69, 1695-1702.
[Google Scholar] [CrossRef] [PubMed]
[10] Hicks (1991) Ozone in Water Treatment. New Zealand Engineering, 46, No 8.
[11] Yao, C.C.D. and Haag, W.R. (1991) Rate Constants for Direct Reactions of Ozone with Several Drinking Water Contaminants. Water Research, 25, 761-773.
[Google Scholar] [CrossRef
[12] Gogate, P.R. and Pandit, A.B. (2004) A Review of Imperative Technologies for Wastewater Treatment II: Hybrid Methods. Advances in Environmental Research, 8, 553-597.
[Google Scholar] [CrossRef
[13] 刘金泉, 李天增, 王发珍, 胡晓辉, 陈伟山. O3、H2O2/O3及UV/O3在焦化废水深度处理中的应用. 环境工程学报, 2009, 3(3): 501-505.