高产率金属银纳米线的制备其薄膜性能研究
The Preparation of Silver Nanowires with High Yield and Research of Thin Film Performance
DOI: 10.12677/APP.2018.82010, PDF,    国家自然科学基金支持
作者: 钟东洲*：五邑大学信息工程学院，广东 江门；段 峰：五邑大学信息工程学院，广东 江门;五邑大学应用物理与材料学院，广东 江门；张舒颖, 杨为家, 何 鑫：五邑大学应用物理与材料学院，广东 江门
关键词: 银纳米线；水热法；油浴法；导电薄膜；Silver Nanowires； Hydrothermal Method； Oil Bath； Conductive Films
摘要: 本文利用水热法制备高产率金属银纳米线，以硝酸银为银源，表面活性剂聚乙烯吡咯烷酮为形貌导向剂，以铁的化合物为反应物。通过研究水热法条件，如反应物浓度、反应物种类和摩尔比等对纳米线产率和尺度的影响，筛选出最好的制作银纳米线方案。并将使用最佳配比水热法获得的银纳米线与油浴法获得的银纳米线相比较，利用X射线衍射仪表征样品的结构与纯度。利用不同长径比的银纳米线制备透明导电薄膜，利用紫外可见分光光度计和四探针测试仪表征薄膜的光电性能，在相同透过率的情况下，利用长径比更高的纳米线可获得电学性能更为优异的透明导电薄膜。
Abstract: In this paper, the high yield metal silver nanowires were prepared by hydrothermal method with silver nitrate as the silver source, the surfactant polyvinylpyrrolidone as the topical guide, and the iron compound as the reactant. The best preparation of silver nanowire was screened by hydrothermal conditions such as reactant concentration, reactant type and mole ratio. The silver nanowires obtained with the optimum ratio hydrothermal method were compared with the silver nanowires obtained by the oil bath method. And the structure and purity of the samples were analyzed by using X-ray diffraction instruments. Some transparent conductive film was prepared by using silver nanowires with different diameters. The photoelectric properties of the films were characterized by UV visible spectrophotometer and four-probe tester. The transparent conductive films with better electrical properties can be obtained by using a nanowire with excellent long diameter ratio at the same transmittance.
文章引用：钟东洲, 段峰, 张舒颖, 杨为家, 何鑫. 高产率金属银纳米线的制备其薄膜性能研究[J]. 应用物理, 2018, 8(2): 81-90. https://doi.org/10.12677/APP.2018.82010

参考文献

[1] He, X., Zhang, M. and Yang, S.Y. (2012) Large Scale Synthesis of Silver Nanowires with High Aspect Ratios by Glucose and Fe3+. Advanced Materials Research, 529, 541-545. [Google Scholar] [CrossRef] 
[2] Karakawa, M., Tokuno, T., Nogi, M., Aso, Y. and Suganuma, K. (2017) Silver Nanowire Networks as a Transparent Printable Electrode for Organic Photovoltaic Cells. Electrochemistry, 85, 245-248. [Google Scholar] [CrossRef] 
[3] Chung, W.-H., Kim, S.-H. and Kim, H.-S. (2016) Welding of Silver Nanowire Networks via Flash White Light and UV-C Irradiation for Highly Conductive and Reliable Transparent Electrodes. Nature, 4, Article ID: 32086. [Google Scholar] [CrossRef] [PubMed]
[4] Liang, J.J., Li, L., Chen, D., Hajagos, T., Ren, Z., Chou, S.-Y., Hu, W. and Pei, Q.B. (2015) Intrinsically Stretchable and Transparent Thin-Film Transistors Based on Printable Silver Nanowires, Carbon Nanotubes and an Elastomeric Dielectric. Nature Communications, 6, Article ID: 7647. [Google Scholar] [CrossRef] [PubMed]
[5] Liu, Y., Zhang, J.M., Gao, H., Wang, Y., Liu, Q.X., Huang, S.Y., Guo, C.F. and Ren, Z.F. (2017) Capillary Force Induced Cold Welding in Silver-Nanowire-Based Flexible Transparent Electrodes. Nano Letters, 1, 2-6.
[6] Park, J.H., Hwang, G.-T., Kim, S., Seo, J., Park, H.-J., Yu, K., Kim, T.-S. and Lee, K.J. (2016) Flash-Induced Self-Limited Plasmonic Welding of Silver Nanowire Network for Transparent Flexible Energy Harvester. Advanced Materials, 3, 473.
[7] 王洁, 堵永国, 张楷力. 银纳米线透明电极的成膜及后处理综述[J]. 贵金属, 2016, 37(3): 1-2.
[8] 刘裕堃, 曹峰, 胡超, 秦天柱, 赵博为, 何桂美, 王娟. 银纳米线的溶剂热法制备及表征[J]. 化学生物与工程, 2017, 34(7): 35-37, 42.
[9] 李云飞, 冯晶. 还原石墨烯氧化物–银纳米线复合电极的制备与性能研究[D]: [硕士学位论文]. 长春: 吉林大学, 2015: 1-16.
[10] 鲍俊, 杜晓晴. 石墨烯/银纳米线复合透明电极的制备及其在有机电致发光器件中的应用[D]: [硕士学位论文]. 重庆: 重庆大学, 2016.
[11] 李志凌, 李晶泽, 王悦辉. 纳米银线–石墨烯基柔性透明导电薄膜的制备与性能研究[D]: [硕士学位论文]. 成都: 电子科技大学, 2016.
[12] 郑璐, 晋日亚. 石墨烯/银纳米复合材料的制备及其电化学应用研究[D]: [硕士学位论文]. 太原: 中北大学, 2016.
[13] 张骐, 郭金宝. 石墨烯/银纳米线复合透明电极材料的制备及液晶器件应用[D]: [硕士学位论文]. 北京: 北京化工大学, 2015.
[14] 钱君芝, 张丽. 石墨烯–银纳米复合材料的制备及性能研究[D]: [硕士学位论文]. 郑州: 郑州大学, 2015.
[15] 李云飞, 陈洋, 毕宴钢, 纪一鹏, 曾祥雯, 李阳, 程为军, 胡腾飞, 杨继萍, 杨海, 李传南. 还原石墨烯氧化物–银纳米线柔性复合电极的制备与性能研究[J]. 发光学报, 2015, 36(5): 545-551.
[16] Liang, J.J., Li, L., Tong, K., Ren, Z., Hu, W., Niu, X.F., Chen, Y.S. and Pei, Q.B. (2014) Silver Nanowire Percolation Network Soldered with Graphene Oxide at Room Temperature and Its Application for Fully Stretchable Polymer Light Emitting Diodes. ACS Nano, 8, 1590-1600.
[17] Song, T.-B., Chen, Y., Chung, C.-H., Yang, Y., Bob, B., Duan, H.-S., Li, G., Tu, K.-N., Huang, Y. and Yang, Y. (2014) Nanoscale Joule Heating and Electromigration Enhanced Ripening of Silver Nanowire Contacts. ACS Nano, 8, 2804-2811. [Google Scholar] [CrossRef] [PubMed]
[18] Sciacca, B., van de Groep, J., Polman, A. and Garnett, E.C. (2015) Solution-Grown Silver Nanowire Ordered Arrays as Transparent Electrodes. Advanced Materials, 5, 905-909.
[19] Choi, S., Park, J., Hyun, W., Kim, J., Kim, J., Lee, Y.B., Song, C., Hwang, H.J., Kim, J.H., Hyeon, T. and Kim, D.-H. (2015) Stretchable Heater Using Ligand-Exchanged Silver NanowireNanocomposite for Wearable Articular Thermotherapy. ACS Nano, 9, 6626–6633. [Google Scholar] [CrossRef] [PubMed]
[20] 罗超, 戴英. 水热法制备银纳米线及其生长机制的研究[J]. 西华大学学报: 自然科学版, 2008, 27(6): 70-72.
[21] 张卫纯, 樊济宇. 油浴中多羟基还原法快速合成银纳米线[J]. 材料导报, 2011(s2): 94-96.

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