高熵合金性能的研究现状
Research Status of High Entropy Alloy Performance
DOI: 10.12677/MEng.2018.51003, PDF,  被引量    国家自然科学基金支持
作者: 兰利娟, 顾莹莹, 濮天姣, 朱和国：南京理工大学材料科学与工程学院，江苏 南京
关键词: 高熵合金；力学性能；耐腐蚀性；氧化性；High Entropy Alloy； Mechanical Properties； Corrosion Resistance； Oxidation Resistance
摘要: 高熵合金是一种新型合金，具有高的强度与硬度、优异的耐磨性与耐腐蚀性及强的热稳定性和抗氧化性等特点，在航空航天、电子通信等领域具有巨大的应用潜力。本文综述了高熵合金的力学性能、耐腐蚀性能及其高温氧化性能的研究现状，分别讨论了性能的主要影响因素：合金元素、制备工艺、塑性变形及合金配比等，指出高熵合金性能研究中的不足，并对高熵合金性能研究的方向提出了展望。
Abstract: Due to its high strength, high hardness, excellent wear and corrosion resistance, good thermal stability at high temperatures and high oxidation resistance properties, high-entropy alloy is a new alloy with great development potential in areas such as aerospace and electronic communication. Research status on the properties of high-entropy alloys is reviewed, including mechanical properties, corrosion resistance and high temperature oxidation resistance. Main effective factors on properties are separately discussed, with alloy elements, preparation process, plastic defor-mation and alloy ratio included. The deficiencies existed in high-entropy alloys’ researches are summarized. The prospects of the properties of high-entropy alloys are also proposed.
文章引用：兰利娟, 顾莹莹, 濮天姣, 朱和国. 高熵合金性能的研究现状[J]. 冶金工程, 2018, 5(1): 17-24. https://doi.org/10.12677/MEng.2018.51003

参考文献

[1] Yeh, J.W., Chen, S.K., Lin, S., et al. (2004) Nanostructured High-Entropy Alloys with Multiple Principal Elements: Novel Alloy Design Concepts and Outcomes. Advanced Engineering Materials, 6, 299-303.
[Google Scholar] [CrossRef] 
[2] Zhou, Y.J., Zhang, Y., Wang, Y.L., et al. (2007) Solid Solution Alloys of AlCoCrFeNiTix with Excellent Room-Temperate Mechanical Properties. Applied Physics Letters, 90, 181 904.
[3] 卢素华. 原位自生高熵合金基复合材料组织级性能的研究[D]. 哈尔滨: 哈尔滨工业大学, 2008.
[4] Shu, F.Y., Wu, L., Zhao, H.Y., et al. (2018) Microstructure and High-Temperature Wear Mechanism of Laser Cladded CoCrBFeNiSi High-Entropy Alloy Amorphous Coating. Material Letters, 211, 235-238.
[Google Scholar] [CrossRef] 
[5] Zhang, Y., Liu, Y., Li, Y.X., et al. (2016) Microstructure and Mechanical Properties of a Refractory HfNbTiVSi0.5 High-Entropy Alloy Composite. Material Letters, 174, 82-85.
[Google Scholar] [CrossRef] 
[6] Huo, W.Y., Zhou, H., Fang, F., et al. (2018) Microstructure and Properties of Novel CoCrFeNiTax Eutectic High-Entropy Alloys. Journal of Alloys and Compounds, 735, 897-904.
[Google Scholar] [CrossRef] 
[7] 张东, 张宁. 物理学中的熵理论及其应用研究[J]. 北京联合大学学报(自然科学版), 2007, 21(1): 4-8.
[8] 李忠丽, 孙宏飞, 高鹏, 等. 新型多主元高熵合金的研究进展[J]. 热加工工艺, 2010, 39(8): 62-65.
[9] 郭娜娜, 孙宏飞, 高鹏, 等. 主元数对多主元高熵合金组织结构和性能的影响[J]. 新技术新工艺, 2011(6): 87-91.
[10] Qiu, X.W., Zhang, Y.P., He, L. and Liu, C.G. (2013) Microstructure and Corrosion Resistance of AlCrFeCuCo High Entropy Alloy. Journal of Alloys and Compounds, 549, 195-199.
[Google Scholar] [CrossRef] 
[11] 罗新民, 王翔, 陈康敏, 等. 激光冲击诱导的航空铝合金表层高熵结构及其抗蚀性[J]. 金属学报, 2015(1): 57.
[12] 郝建军, 张利, 马跃进, 等. 反应氮弧熔覆TiCN/Fe涂层工艺优化及耐磨性[J]. 材料热处理学报, 2013, 34(7): 165.
[13] 高家诚, 李锐. 高熵合金研究的新进展[J]. 功能材料, 2008, 39(7): 1059-1061.
[14] 刘 源, 陈 敏, 李言祥, 等. AlxCoCrCuFeNi 多主元高熵合金的微观结构和力学性能[J]. 稀有金属材料与工程, 2009, 38(9): 1602-1607.
[15] 温丽华, 寇宏超, 王一川, 等. AlxCoCrCuFeNi 多主元高熵合金的组织与力学性能[J]. 特种铸造及有色合金, 2009, 29(6): 579-581.
[16] 刘亮, 张越, 赵作福, 等. AlxCoCuFeNi高熵合金的组织结构与力学性能[J]. 特种铸造及有色合金, 2016, 36(6): 570-574.
[17] Zhao, Y.G., Mei, H., Dai, P.Q., Bo, W.U. and Zheng, W.M. (2010) Microstructures and Mechanical Properties of Ti 0.5 AlCoFeNiCrx High-Entropy Alloys. Journal of Materials Science and Engineering, No. 5, 753-756.
[18] Cai, J.B., Wu, Y.-J., Zhang, D.D. and Dai, P.Q. (2011) Microstructure and Mechanical Property of High-Entropy Alloy with Multi-Principal Elements. Rare Metals and Cemented Carbides, 39, 37-40.
[19] Rogal, Ł., Kalita, D., Tarasek, A., et al. (2017) Effect of SiC Nano-Particles on Microstructure and Mechanical Properties of the CoCrFeMnNi High Entropy Alloy. Journal of Alloys and Compounds, 708, 344-352.
[Google Scholar] [CrossRef] 
[20] Rogal, Ł., Kalita, D. and Litynska-Dobrzynska, L. (2017) CoCrFeMnNi High Entropy Alloy Matrix Nanocomposite with Addition of Al2O3. Intermetallics, 86, 104-109.
[Google Scholar] [CrossRef] 
[21] 黄祖凤, 张冲, 唐群华, 等. 退火对激光熔覆FeCoCrNiB高熵合金涂层组织结构与硬度的影响[J]. 表面技术, 2013, 42(1): 000009-13.
[22] Tang, Q.H., Cai, J.B., Wu, G.-F. and Dai, P.Q. (2011) Effects of Heat Treatment on Microstructure and Mechanical Properties of Al0.5CoCrFeNiB0.2 High-Entropy Alloy. Foundry, 60, 24-27.
[23] 唐群华, 赵亚光, 蔡建宾, 等. 时效处理对Al0.5CoCrFeNi高熵合金微观组织和力学性能的影响[J]. 有色金属(冶炼部分), 2011(4): 47-50.
[24] 刘宁, 张艳, 秦亮. 一种新型耐磨材料——高熵合金[J]. 材料导报, 2012, 26: 389-391.
[25] Chuang, M.H., Tsai, M.H. and Wang, W.R. (2011) Micro-structure and Wear Behavior of AlxCo1.5CrFeN1.5Tiy High-Entropy Alloys. Acta Materialia, 59, 6308-6317.
[Google Scholar] [CrossRef] 
[26] 范启超. AlFeCrNiCoCu系高熵合金及其复合材料组织及性能研究[D]: [硕士学位论文]. 哈尔滨: 哈尔滨工业大学, 2011.
[27] Hsu, C.J., Yeh, J.W. and Chen, S.K. (2004) Wear Resistance and High Temperature Compression Strength of FCC CuCoNiCrAl0.5Fe Alloy with Boron Addition. Metallurgical and Materials Transactions A, 35, 1465-1469.
[Google Scholar] [CrossRef] 
[28] Wu, J.M., Lin, S.J. and Yeh, J.W. (2006) Adhesive Wear Be-havior of AlxCoCrCuFeNi High-Entropy Alloys as a Function of Aluminum Content. Wear, 261, 513-519.
[Google Scholar] [CrossRef] 
[29] Hsu, C.Y., Sheu, T.S. and Yeh, J.W. (2010) Effect of Iron Con-tent on Wear Behavior of AlCoCrFexMo0.5Ni High-Entropy Alloys. Wear, 268, 653-659.
[Google Scholar] [CrossRef] 
[30] 叶海梅, 杨文超, 庞文超, 杨剑冰, 湛永钟. Ti元素对CoCuFeNiVTix高熵合金耐磨性能的影响[J]. 广西大学学报(自然科学版), 2017, 42(3): 1187-1911.
[31] 谢红波, 刘贵仲, 郭景杰, 周敏, 刘德飘, 毛炜乾. Al元素对AlxFeCrCoCuV高熵合金组织及摩擦性能的影响[J]. 材料工程, 2016(44): 65-70.
[32] 卢易枫, 冯春丽. 机械振动对高熵合金烛台组织和性能的影响分析[J]. 热加工工艺, 2016, 45(7): 63-65.
[33] Huang, C., Zhang, Y., Vilar, R., et al. (2012) Dry Sliding Wear Behavior of Laser Clad TiVCrAlSi High Entropy Alloy Coatings on Ti-6Al-4V Substrate. Materials & Design, 41, 338-343.
[Google Scholar] [CrossRef] 
[34] 杨晓宁, 邓伟林, 黄晓波, 等. 高熵合金制备方法进展[J]. 热加工工艺, 2014, 43(22): 30-33.
[35] 张琪, 饶湖常, 沈志博, 黄祖凤, 戴品强. WC颗粒对激光熔覆FeCoCrNiB高熵合金涂层组织结构与耐磨性影响[J]. 热加工工艺, 2014, 43(18): 147-155.
[36] 安旭龙, 刘其斌, 郑波. 碳化钨对激光熔覆高熵合金的影响[J]. 强激光与粒子束, 2014, 26(12): 129001.
[37] 史一功, 寇宏超, 段海涛, 等. AlCoCrFeNiCu高熵合金在过氧化氢介质中的摩擦磨损性能[J]. 摩擦学学报, 2011, 31(4): 381-387.
[38] 胡成平, 赵亚林, 王杰鹏, 等. 高浓度过氧化氢中AlCoCrFeNiCu的摩擦学性能研究[J]. 摩擦学学报, 31(5): 439-446.
[39] 范太云, 唐群华, 陈文哲, 戴品强, 吴波. 塑性变形对Al0.5FeCoCrNi高熵合金组织结构和性能的影响[J]. 材料科学与工程学报, 2013, 31(2): 258-263.
[40] Xyla, A.G. and Koutsoukos, P.G. (1987) Effect of Diphpsphonates on the Precipitation of Calcium Carbonate in Aqueous Solutions. Journal of Chmical Social Farady Translates, 183, 1477-1453.
[41] 吴香发, 何杰, 邢雅丽, 杨万芳. 重制CaCO3的表面性质及在PVC制品中的应用[J]. 聚氯乙烯, 2005(12): 15-17.
[42] 钱军民, 金志浩. 我国CaCO3填料表面改性即在塑料中的应用[J]. 合成树脂及塑料, 2002(19): 59-62.
[43] Zhang, A., Han, J., Su, B. and Meng, J. (2017) A Novel CoCrFeNi High Entropy Alloy Matrix Self-Lubricating Composite. Journal of Alloys and Compounds, 725, 700-710.
[Google Scholar] [CrossRef] 
[44] Zhang, A., Han, J., Su, B., Li, P. and Meng, J. (2017) Micro-structure, Mechanical Properties and Tribological Performance of CoCrFeNi High Entropy Alloy Matrix Self-Lubricating Composite. Materials and Design, 114, 253-263.
[Google Scholar] [CrossRef] 
[45] 牛雪莲, 王立久, 孙丹. AlxFeCoCrNiCu(x = 0.25、0.5、1.0)高熵合金的组织结构和电化学性能研究[J]. 功能材料, 2013(4): 532-535.
[46] 谢红波, 刘贵仲, 郭景杰. Zr元素对AlFeCrCoCuZrx高熵合金组织及腐蚀性能的影响[J]. 材料工程, 2016(44): 44-49.
[47] 徐右睿. FeCoNiCrCux高熵合金之抗腐蚀性研究[D]. 基隆: 海洋大学, 2004.
[48] 李伟, 刘贵仲, 郭景杰. AlFeCuCoNiCrTix高熵合金的组织结构及电化学性能[J]. 特种铸造及有色合金, 2009, 29(10): 941-944.
[49] 李伟, 刘贵仲, 郭景杰. AlxFeCo-NiCrTi系高熵合金的组织结构及电化学性能研究[J]. 铸造, 2009(58): 431-435.
[50] 黄艺娜, 唐群华, 戴品强. 轧制变形对Al0.3CoCrFeNi高熵合金显微组织和性能的影响[J]. 机械工程材料, 2015(38): 51-54.
[51] 任伟才, 彭国胜, 陈康华, 等. 轧制变形对Al-Zn-Mg-Cu合金组织与力学性能以及腐蚀性能的影响[J]. 粉末冶金材料科学与工程, 2013, 18(6): 807-813.
[52] 温鑫, 金国, 庞学佳, 等. 热处理对真空热压烧结NiCrCoTiV高熵合金组织结构及耐腐蚀性能的影响[J]. 材料导报B: 研究篇, 2017, 31(6): 79-83.
[53] 洪丽华. 高熵合金高温氧化和高温腐蚀特性的研究[D]: [硕士学位论文]. 福州: 福州大学, 2014.
[54] Zhang, H., Wang, Q.T., Tang, Q.H. and Dai, P.Q. (2013) High Temperature Oxidation Property of Al0.5FeCoCrNi(Si0.2,Ti0.5) High Entropy Alloys. Corrosion& Protection, 34, 561-565.
[55] 吴波, 赵春凤, 杨上金. AlCoCrFeNiTi0.5高熵合金的高温氧化行为[J]. 稀有金属材料与工程, 2015(12): 3228-3233.
[56] 谢红波, 刘贵仲, 郭景杰, 等. 添加Al对AlxFeCrCoCuTi高熵合金组织与高温氧化性能的影响[J]. 稀有金属, 2016, 40(4): 315-321.
[57] 郑必举, 蒋业华, 胡文. 铝含量对AlxCrFeCoCuNi高熵合金涂层抗氧化性能的影响[J]. 应用激光, 2016(1): 18-22.
[58] Zhou, F., Liu, Q. and Zheng, B. (2016) Effects of Silicon and Aluminum Addition on Microstructure and Properties of MoFeCrTiW High-Entropy Alloy Coating. Chinese Journal of Lasers, 27.
[59] 谢红波, 刘贵仲, 郭景杰. Mn、V、Mo、Ti、Zr元素对AlFeCrCoCu-X高熵合金组织与高温氧化性能的影响[J]. 中国有色金属学报, 2015(1): 103-110.
[60] Zhang, C., Huang, B. and Dai, P. (2016) Effects of Chromium Content on Oxidation Behavior of FeCoCrxNiB High-Entropy Alloy Coatings. China Surface Engineering, 29, 32-38.

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