利用LIBS对AlCl3溶液定量分析
Quantitative Analysis of AlCl3 Solution Using LIBS
摘要: 本文中利用激光诱导等离子体击穿光谱方法对AlCl3溶液进行了定量分析。在实验中以Al作为内标元素,将配置好不同的浓度的AlCl3溶液以射流方式产生等离子体,利用内标法和谱线–浓度法进行定量分析发现谱线面积–浓度法效果比内标法好,尤其是浓度低自吸收强时利用谱线面积–浓度法进行定标比较精确。
Abstract: In this paper, the AlCl3 solution was quantitatively analyzed by laser induced plasma breakdown spectroscopy (laser-induced plasma breakdown spectroscopy). Using Al as internal standard ele-ments in the experiment, the configuration of different concentrations of AlCl3 solution to produce plasma jet, the use of internal standard method and the spectral concentration method for quanti-tative analysis found that the spectral line area Binet concentration method standard method espe-cially good effect of low concentration of strong self absorption when using line area concentration method for calibration is more accurate.
文章引用:奥布力喀斯木·祖农, 拜合提妮萨·艾力, 阿拜·艾力哈孜, 戴康, 普拉提·艾合买提. 利用LIBS对AlCl3溶液定量分析[J]. 应用物理, 2018, 8(3): 151-156. https://doi.org/10.12677/APP.2018.83018

参考文献

[1] 章婷婷, 舒嵘, 刘鹏希, 万雄. 远程激光诱导击穿光谱技术分析岩石元素成分[J]. 光谱学与光谱分析, 2017, 37(2): 594-598.
[2] 余克强, 赵艳茹, 刘飞, 彭继宇, 何勇. 激光诱导击穿光谱技术在土壤元素检测中的应用[J]. 光谱学与光谱分析, 2016, 36(3): 827-833.
[3] 黄基松, 陈巧玲, 周卫东. 激光诱导击穿光谱技术分析土壤中的Cr和Sr [J]. 光谱学与光谱分析, 2009, 29(11): 3126-3129.
[4] 付杰, 樊仲维, 郭喜庆, 等. 钢靶等离子体光谱时域分布特性研究[J]. 中国激光, 2017(3): 1-12.
[5] 钱燕, 钟厦, 何勇, Whiddon, R., 王智化, 岑可法. 激光波长对煤激光诱导击穿光谱特性影响的试验研究[J]. 光谱学与光谱分析, 2017, 37(6): 1890-1895.
[6] Cáceres, J.O., López, J.T., Telle, H.H., et al. (2001) Quantitative Analysis of Trace Metal Ions in Ice Using Laser-Induced Breakdown Spectroscopy. Spectrochimica Acta Part B Atomic Spectroscopy, 56, 831-838. [Google Scholar] [CrossRef
[7] López-Claros, M., Aglio, M.D., Gaudiuso, R., et al. (2017) Double Pulse Laser Induced Breakdown Spectroscopy of a Solid in Water: Effect of Hydrostatic Pressure on Laser Induced Plasma, Cavitation Bub-ble and Emission Spectra. Spectrochimica Acta Part B Atomic Spectroscopy, 133, 63-71. [Google Scholar] [CrossRef
[8] 陈凯, 陆继东, 李俊彦. 钢液中多元素的LIBS实时定量分析[J]. 光谱学与光谱分析, 2011, 31(3): 823-826.
[9] 宋超, 张亚维, 高勋. 基于激光诱导击穿光谱技术的混合溶液重金属元素检测[J]. 光谱学与光谱分析, 2017, 37(6): 1885-1889.