含缺陷位金属有机骨架材料的研究进展
Recent Research Progresses on Defective Metal-Organic Frameworks
DOI: 10.12677/JAPC.2018.72008, PDF,    国家科技经费支持
作者: 杜荣飞, 吴结宇, 傅仰河*：浙江师范大学含氟新材料研究所，浙江 金华
关键词: 缺陷位；金属有机骨架材料；孔隙率；稳定性；酸性；Structural Defects； Metal-Organic Frameworks； Porosity； Stability； Acidity
摘要: 金属有机骨架材料(MOFs)作为一种新型的多孔配位聚合物，在近二十年已经被大量研究工作者研究。目前研究表明缺陷位会存在于多种MOFs材料中，含缺陷位的MOFs材料的理化性质与完美晶体相比有明显的不同。本文重点阐述了缺陷位对MOFs材料的孔道结构、热稳定性和材料酸性的影响，并对其发展趋势作了展望。
Abstract: Metal-organic frameworks (MOFs), as a new type of porous coordination polymers, continue to receive abundant attention since their first synthesis about two decades ago. The few recent studies of defective MOFs have focused either on the nature of defect inclusion itself or on how defects influence their physicochemical properties such as catalytic activity and guest sorption. This paper focused on the recent research process and the problems of structural defects in MOFs, which have a well-established role in enhancing and controlling the properties of materials. Meanwhile, the developing trends of this method were also prospected.
文章引用：杜荣飞, 吴结宇, 傅仰河. 含缺陷位金属有机骨架材料的研究进展[J]. 物理化学进展, 2018, 7(2): 64-69. https://doi.org/10.12677/JAPC.2018.72008

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