四氢噻唑-2-硫酮-4-羧酸一步催化合成α-氨基膦酸酯类化合物
Thiazolidine-2-thione-4-carboxylic Acid Catalyzed One-Pot Synthesis of α-Aminophosphonates
DOI: 10.12677/JOCR.2018.62008, PDF,    国家自然科学基金支持
作者: 卢 懂, 罗海燕, 刘晨江*:新疆大学化学化工学院,石油天然气精细化工教育部&自治区重点实验室,新疆 乌鲁木齐
关键词: α-氨基膦酸酯四氢噻唑-2-硫酮-4-羧酸Kabachnik-Fields反应α-Aminophosphonates Thiazolidine-2-thione-4-carboxylic Acid Kabachnik-Fields Reaction
摘要: 本文以四氢噻唑-2-硫酮-4-羧酸作为一种可循环的有机催化剂,在无溶剂条件下催化芳香醛、苯胺和亚磷酸三甲酯得到了一系列α-氨基膦酸酯类化合物。该方法具有环境友好、操作简单的特点。
Abstract: In this paper, thiazolidine-2-thione-4-carboxylic acid is used as a recyclable organic catalyst to catalyze the reaction of aromatic aldehyde, aniline and phosphite under the solvent-free conditions, and a series of α-aminophosphonates are obtained. The method is characterized by friendly environment and simplicity of operation.
文章引用:卢懂, 罗海燕, 刘晨江. 四氢噻唑-2-硫酮-4-羧酸一步催化合成α-氨基膦酸酯类化合物[J]. 有机化学研究, 2018, 6(2): 52-56. https://doi.org/10.12677/JOCR.2018.62008

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