Fe3O4 NPs@MIL-53的直接自组装制备以及催化性能
DSA Preparation of Fe3O4 NPs@MIL-53 and atalytic Performance
DOI: 10.12677/HJCET.2018.84027, PDF,   
作者: 袁纯明:吉林省能源信息中心,吉林 长春;王元瑞, 李亚丰*:长春工业大学化学工程学院,吉林 长春
关键词: 直接自组装单分散的纳米离子MIL-53环氧化Directing Self-Assembly Mono-Disperse Nano-article MIl-53 Epoxidation
摘要: 通过直接自组装的方法制备了Fe3O4 NPs@MIL-53复合材料,并且通过PXRD,FTIR,TEM以及77 K下的N2吸附进行了表征。结果显示Fe3O4 NPs是被嵌入到MIL-53骨架结构中并被固定在晶格内部。Fe3O4 NPs@MIL-53复合材料对苯乙烯催化环氧化有高的选择性。PRXD证明了Fe3O4 NPs@MIL-53复合材料的酸稳定性。
Abstract: The Fe3O4 NPs@MIL-53 composite has been prepared by method of directing self-assembly (DSA) and characterized by PXRD, FTIR, TEM and N2 adsorption at 77 K. The results show that Fe3O4 NPs are embedded into the framework of MIL-53 and locked inside by the lattice of MIL-53. The catalytic performance exhibits that Fe3O4 NPs@MIL-53 composite can selectively catalyze the styrene epoxidation. PXRD testifies the acidic stability of Fe3O4 NPs@MIL-53 composite.
文章引用:袁纯明, 王元瑞, 李亚丰. Fe3O4 NPs@MIL-53的直接自组装制备以及催化性能[J]. 化学工程与技术, 2018, 8(4): 216-222. https://doi.org/10.12677/HJCET.2018.84027

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