V对2205双相不锈钢钢筋组织和耐蚀性能影响研究
Effect of Vanadium on Microstructure and Corrosion Resistance of 2205 Duplex Stainless Steel
DOI: 10.12677/MEng.2018.53017, PDF,    国家科技经费支持
作者: 孙 秀, 胡建文:河北科技大学材料学院,河北 石家庄;杨忠民, 陈 颖:钢铁研究总院工程用钢研究所,北京;李晓滨, 吕尚霖:中冶建筑研究总院有限公司,北京
关键词: 微合金元素V2205双相不锈钢临界点蚀电位Microalloying Element V 2205 Duplex Stainless Steel Critical Pitting Point
摘要: 本文对比了V微合金化2205双相不锈钢钢筋和不含V的2205双相不锈钢钢筋经过不同固溶处理的组织和电化学腐蚀性能,结果表明:含V的2205不锈钢钢筋在950℃固溶处理时组织中的脆性相比不含V的2205不锈钢钢筋组织中的脆性相显著减少,在1000℃~1050℃温度区间内,含V的2205钢筋和不含V的2205钢筋的微观组织中都没有σ相等脆性相析出,添加V有抑制脆性相析出的作用。含V的2205不锈钢钢筋的临界点蚀电位高于不含V的2205不锈钢钢筋的临界点蚀电位,添加V提高了2205双相不锈钢的耐腐蚀性能。
Abstract: The microstructure and electrochemical corrosion resistance of V microalloyed 2205 duplex stainless steels bar and 2205 duplex stainless steels bar without V were investigated for solution treatment and holding time respectively. The results show that the 2205 stainless steel rein-forcement containing V was solution treated at 950˚C. The brittleness of the structure was signifi-cantly reduced compared with that of 2205 stainless steel without V. In the temperature range of 1000˚C~1050˚C, there is no σ brittle phase in the two kinds of 2205 stainless steel bars. The addi-tion of microalloying V inhibited the brittle phase precipitation. The critical pitting point of 2205 stainless steel with V is higher than the critical pitting point of 2205 stainless steel without V, which improves the corrosion resistance of 2205 duplex stainless steel.
文章引用:孙秀, 杨忠民, 陈颖, 胡建文, 李晓滨, 吕尚霖. V对2205双相不锈钢钢筋组织和耐蚀性能影响研究[J]. 冶金工程, 2018, 5(3): 122-130. https://doi.org/10.12677/MEng.2018.53017

参考文献

[1] 武英杰, 申鹏, 颜海涛. 双相不锈钢的国内外研究进展[J]. 科技创新导报, 2010(28): 41.
[2] Olsson, L. (1994) 60 Years of Duplex Stainless Steel Applications. National Association of Corrosion Engineers International Annual Con-ference, Baltimore, 28 February-4 March 1994.
[3] 王刚, 郭幼丹, 郭雷, 等. 双相不锈钢的发展特点及其应用[J]. 科技与创新, 2015(7): 91-92.
[4] 刘复兴. S32205双相不锈钢中σ相的析出及其对力学性能的影响[J]. 钢铁, 2010, 45(7): 62-65 + 93.
[5] 刘雄, 何燕霖, 丁秀平, 等. 高温时效对2205双相不锈钢中σ相析出行为的影响[J]. 材料热处理学报, 2010, 31(3): 48-51.
[6] Angelini, E. and De Benedetti, B. (2004) Microstructural Evolution And-localized Corrosion Resistance of an Aged Super Duplex Stainless Steel. Corrosion Science, 46, 1351-1367. [Google Scholar] [CrossRef
[7] 肖纪美. 不锈钢的金属学问题[M]. 北京: 冶金工业出版社, 2006.
[8] 杨才福, 王瑞珍, 陈雪慧, 译. 钒在微合金钢中的作用[M]. 北京: 冶金工业出版社, 2015.
[9] Ras, M.H. and Pistorius, P.C. (2002) Possible Mechanisms for the Improvement by Vanadium of the Pitting Corrosion Re-sistance of 18% Chromium Ferritic Stainless Steel. Corrosion Science, 44, 2479-2490. [Google Scholar] [CrossRef