基于新型含氮配体构筑的Cu(I)配合物的合成、结构和光催化性能研究
Synthesis, Structure and Photocatalytic Property of Cu(I) Complex Based on a New N-Containing Donor
摘要: 在水热条件下利用含氮配体(HL)和CuCl2通过自主装反应成功制备了一个新的卤化亚铜配合物，[Cu(I)2(L)(μ3−Cl)]n(1)。利用单晶X-射线衍射，粉末X-射线衍射和元素分析等手段对化合物进行了表征。晶体结构分析表明该化合物是一个具有(3,6)-连接拓扑特征的三维骨架化合物，其中有机配体以五连接的方式与金属离子成键。此外，该化合物展示出了一定光催化性能，在紫外光照射下能够在7小时内将RhB溶液降解约47%，是一种潜在的光催化材料。
Abstract: A new cuprous chloride complex, [Cu(I)2(L)(μ3−Cl)]n(1) has been synthesized by the self-assembly of HL ligand and CuCl2 under hydrothermal condition. It was characterized by single crystal X-ray diffraction, powder X-ray diffraction and elemental analysis. Structural analysis shows that the title complex exhibits three-dimensional framework with the (3,6)-connected topological network. In addition, the complex displays photocatalytic performance to some extent, and can degrade RhB solution by about 47% within 7 hours under ultraviolet irradiation, which indicates that it may be a potential photocatalytic material.
文章引用：刘迎玉, 滕家雯, 曹慧, 孙玉, 谭鑫, 苏北浩, 袁刚. 基于新型含氮配体构筑的Cu(I)配合物的合成、结构和光催化性能研究[J]. 材料化学前沿, 2018, 6(4): 127-134. https://doi.org/10.12677/AMC.2018.64015

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