分子印迹聚合物在水体中的应用
Application of Molecularly Imprinted Polymer in Water
摘要: 分子印迹聚合物是以分子印迹技术为基础制备出的一种聚合物，具有特定的专一识别性，操作简单，可连续化操作。首先对分子印迹聚合物主要制备方法，包括原位聚合，共混法，表面修饰与电化学聚合法进行了评述，而后介绍了分子印迹聚合物分别在无机组分和有机组分中的应用研究进展，分析了分子印迹聚合物的现有缺陷以及以后的发展前景。
Abstract: The molecularly imprinted polymer is a polymer prepared on the basis of molecular imprinting technology, which has specific recognition, simple operation and continuous operation. Firstly, the main preparation methods of molecularly imprinted polymers, including in-situ polymerization, blending, surface modification and electrochemical polymerization, were reviewed. Then the ap-plication progress of molecularly imprinted polymers in inorganic and organic components was introduced. Existing defects of molecularly imprinted polymers and future development prospects are also analyzed.
文章引用：蒋育杉, 张林楠, 蒋赟. 分子印迹聚合物在水体中的应用[J]. 环境保护前沿, 2019, 9(2): 129-135. https://doi.org/10.12677/AEP.2019.92020

参考文献

[1] 杨座国, 许振良, 邴乃慈. 分子印迹膜的研究进展[J]. 化工进展, 2006, 25(2): 131-135.
[2] 管萍, 胡小玲. 红霉素分子印迹膜的制备及性能研究[J]. 功能材料, 2010, 41(S2): 379-382.
[3] 王小骥, 刘威, 薛腾, 等. 选择性吸附Cd2＋的磁性印迹壳聚糖球粒[J]. 合肥工业大学学报: 自然科学版, 2015(6): 837-841.
[4] Liu, W. and Wang, B. (2009) Preparation and Application of Norfloxacin-MIP/Polysulfone Blending Molecular Imprinted Polymer Membrane. Journal of Applied Polymer Science, 113, 1125-1132. [Google Scholar] [CrossRef] 
[5] 吕春晖, 方国臻, 王硕. 恩诺沙星分子印迹聚合物膜的制备及吸附性能研究[J]. 现代食品科技, 2017(11): 134-139.
[6] Li, W., et al. (2018) A Surface Plasmon Resonance-Based Optical Fiber Probe Fabricated with Electropolymerized Molecular Imprinting Film for Melamine Detection. Sensors, 18, 828-834. [Google Scholar] [CrossRef] [PubMed]
[7] 王靖宇, 刘敬勇. 吸附剂在工业废水重金属处理中的应用研究进展[J]. 安徽农学通报, 2011, 17(16): 128-130.
[8] 李倩倩, 李义久, 相波. 高分子螯合剂在重金属废水处理中的应用[J]. 工业水处理, 2004, 24(7): 5-8.
[9] Jusoh, A., Shiung, L.S. and Noor, M. (2007) A Simulation Study of the Removal Efficiency of Granular Activated Carbon on Cadmium and Lead. Desalination, 206, 9-16. [Google Scholar] [CrossRef] 
[10] Kang, K.C., Kim, S.S., Choi, J.W., et al. (2008) Sorption of Cu2+ and Cd2+ onto Acid- and Base-Pretreated Granular Activated Carbon and Activated Carbon Fiber Samples. Journal of Industrial and Engineering Chemistry, 14, 13l-135. [Google Scholar] [CrossRef] 
[11] 刘坪鑫. Mo(VI)离子印迹吸附剂去除水中污染物的研究[D]: [硕士学位论文]. 哈尔滨: 哈尔滨工程大学, 2004.
[12] Esen, C., Raziye, H., Feyzio?lu, et al. (2014) Poly(hydroxyethyl methacrylate-co-methacryloylglutamic acid) Nanospheres for Adsorption of Cd2+ Ions from Aqueous Solutions. Journal of Nanoparticle Research, 16, 1-11. [Google Scholar] [CrossRef] 
[13] Girija, P. and Beena, M. (2014) Sorption of Trace Amounts of Pb(II) Ions on an Ion Imprinted Interpenetrating Polymer Network Based on Alginic Acid and Crosslinked Polyacrylamide. Separation Science and Technology, 49, 1053-1061. [Google Scholar] [CrossRef] 
[14] Liu, Y., Chen, R., Yuan, D., et al. (2015) Thermal-Responsive Ion-Imprinted Polymer Based on Magnetic Mesoporous Silica SBA-15 for Selective Removal of Sr(II) from Aqueous Solution. Colloid and Polymer Science, 293, 109-123. [Google Scholar] [CrossRef] 
[15] Ge, H. and Fan, X. (2011) Adsorption of Pb2+ and Cd2+ onto a Novel Activated Carbon-Chitosan Complex. Chemical Engineering & Technology, 34, 1745-1752. [Google Scholar] [CrossRef] 
[16] Peng, S., Meng, H., Ou, Y.Y., et al. (2014) Nanoporous Magnetic Cellulose-Chitosan Composite Microspheres: Preparation Characterization and Application for Cu(II) Adsorption. Industrial & Engineering Chemistry Research, 53, 2106-2113. [Google Scholar] [CrossRef] 
[17] Yang, H., Yuan, B., Lu, Y.B., et al. (2009) Preparation of Magnetic Chitosan Microspheres and Its Applications in Wastewater Treatment. Science in China Series B: Chemistry, 52, 249-256. [Google Scholar] [CrossRef] 
[18] Monier, M., Ayad, D.M., Latif, D.A., et al. (2012) Adsorption of Cu(II), Cd(II) and Ni(II) Ions by Cross-Linked Magnetic Chitosan-2-Minopyridine Glyoxal Schiff’s Base. Colloids and Surfaces B: Bioniterfaces, 94, 250-258. [Google Scholar] [CrossRef] [PubMed]
[19] Zhang, S., Zhou, Y.F., Nie, W.Y., et al. (2012) Preparation of Fe3O4/Chitosan/Poly(acrylic acid) Composite Particles and Its Application in Adsorbing Copper Ion (II). Cellulose, 19, 2081-2091. [Google Scholar] [CrossRef] 
[20] Cen, S., Li, W., Xu, S., et al. (2017) Application of Magnetic Cd2+ Ion-Imprinted Mesoporous Organosilica Nanocomposites for Mineral Wastewater Treatment. RSC Advances, 7, 7996-8003. [Google Scholar] [CrossRef] 
[21] Sikiti, P., Msagati, T.A., Mamba, B.B., et al. (2014) Synthesis and Characterization of Molecularly Imprinted Polymers for the Remediation of PCBs and Dioxins in Aqueous Environments. Journal of Environmental Health Science Engineering, 12, 82-90. [Google Scholar] [CrossRef] 
[22] Yu, P., Sun, Q. and Li, J.F. (2015) Selective Removal of 2,4-Dichlorophenol in Aqueous Solutions by Nanoparticles Modified Yeast Using Miniemulsion Imprinting Polymerization. Journal of Environmental Chemical Engineering, 3, 797-806. [Google Scholar] [CrossRef] 
[23] Fan, W., Zhang, X., Zhang, Y., et al. (2017) Functional Organic Material for Roxarsone and Its Derivatives Recognition via Molecular Imprinting. Journal of Molecular Recognition, 31, 1-9.
[24] Zhang, Y., Shang, J., Song, Y., et al. (2017) Selective Fenton-Like Oxidation of Methylene Blue on Modified Fe-Zeolites Prepared via Molecular Imprinting Technique. Water Science & Technology: A Journal of the International Association on Water Pollution Research, 75, 659-669. [Google Scholar] [CrossRef] [PubMed]
[25] Hu, Y., Wang, C., Li, X., et al. (2017) Preparation and Application of Epitope Magnetic Molecularly Imprinted Polymers for Enrichment of Sulfonamide Antibiotics in Water. Electrophoresis, 38, 2462-2467. [Google Scholar] [CrossRef] [PubMed]
[26] Lin, Z., Zhang, Y., Su, Y., et al. (2018) Selective Extraction of Bisphenol a from Water by One-Monomer Molecularly Imprinted Magnetic Nanoparticles. Journal of Separation Science, 41, 2029-2036. [Google Scholar] [CrossRef] [PubMed]
[27] Guo, H., Liu, Y., Ma, W., et al. (2018) Surface Molecular Imprinting on Carbon Microspheres for Fast and Selective Adsorption of Perfluorooctane Sulfonate. Journal of Hazardous Materials, 348, 29-38. [Google Scholar] [CrossRef] [PubMed]
[28] Abbasi Ghaeni, F., Karimi, G., Mohsenzadeh, M.S., et al. (2018) Preparation of Dual-Template Molecularly Imprinted Nanoparticles for Organophosphate Pesticides and Their Application as Selective Sorbents for Water Treatment. Separation Science and Technology, 53, 2517-2526. [Google Scholar] [CrossRef]