过氧化氢催化活化体系消毒性能研究
Decontamination Efficiency of the Catalytic Activation System of Hydrogen Peroxide
DOI: 10.12677/HJCET.2019.93034, PDF,    国家科技经费支持
作者: 齐丽红, 杨金星, 张荣, 左国民*：中国人民解放军陆军防化学院，北京；孔令策：中国人民解放军防化研究院化学防护所，北京
关键词: 过碳酸钠；乙酰胍；合成；消毒；芥子气；Sodium Percarbonate； Acyl Guanidine； Synthesization； Decontamination； HD
摘要: 过氧化氢活化剂乙酰胍(ACG)已用于织物的漂染工艺研究，并表现出良好的低温反应性和漂染效果；因此，基于过氧化氢和乙酰胍活化反应生成更高活性物质的原理，本文在合成乙酰胍的基础上，考察固体过氧化氢过碳酸钠(SPC)和乙酰胍体系的活化性能和对特种危险化学品芥子气(HD)的消毒性能，为新型消毒剂的研发奠定基础。
Abstract: The use of acyl guanidine as an organic activator to enhance the bleaching performance of hydrogen peroxide for cellulosic materials had been studied. It’s reported that the new process might allow effective bleaching of cellulosic textiles to be achieved under relatively mild conditions. Therefore, the synthesis of acyl guanidine had been researched in this paper. Based on the activation theory where hydrogen peroxide and acyl guanidine would react to produce higher active chemical agent, the activation ability of SPC/ACG and the decontamination of HD had been investigated. The experimental results will help on the exploitation of a new decontaminant.
文章引用：齐丽红, 杨金星, 孔令策, 张荣, 左国民. 过氧化氢催化活化体系消毒性能研究[J]. 化学工程与技术, 2019, 9(3): 232-240. https://doi.org/10.12677/HJCET.2019.93034

参考文献

[1] Lim, S., Gürsoy, N.Ç., Hauser, P. and Hinks, D. (2004) Performance of a New Cationic Bleach Activator on a Hydrogen Peroxide Bleaching System. Coloration Technology, 120, 114-118. [Google Scholar] [CrossRef] 
[2] 王传好. 洗衣用漂白剂和漂白活化剂的研究进展[J]. 日用化学品科学, 1999(8): 177-180.
[3] Cai, J.Y., Evans, D.J. and Smith, S.M. (2000) Bleaching of Natural Fibers with Taed and Nobs Activated Peroxide Systems. The 10th Australian Cotton Conference, Brisbane, Australia, August 2000, 569-574.
[4] 杨栋, 王焕祥. 活化双氧水漂白体系新技术的近况[J]. 印染, 2007(2): 44-48.
[5] 郭华清, 张卉, 王双飞. 新型过氧化氢助漂剂的研究与发展[J]. 造纸化学品, 2004, 16(2): 11-13.
[6] Cassagne, T., Cristau, H., Delmas, G., et al. (2001) Destruction of Chemical Warfare Agents VX and soman by α-Nucleophiles as Oxidizing Agents. Heteroatom Chemistry, 12, 485-490. [Google Scholar] [CrossRef] 
[7] Lion, C., Hedayatullah, M., Charvy, C., et al. (1995) Nouveaux Decontaminants Generation “in Situ” d’un peracide par action d’un persel sur un initiateur, reactivite de ce peracide vis-a-vis du paraoxon[J]. Bulletin des Sociences Chimiques Belges, 104, 515-519. [Google Scholar] [CrossRef] 
[8] Qi, L.H., Zuo, G.M., Cheng, Z.X., Wang, L.Y. AND Zhou, C.H. (2013) Treatment of Chemical Warfare Agents by Combined Sodium Percarbonate with Tetraacetylethylenediamine Solution. Chemical Engineering Journal, 229, 197-205. [Google Scholar] [CrossRef] 
[9] Cai, J.Y. (2007) Guanidine Derivatives Used as Peroxide Activators for Bleaching Cellulosic Textiles. Coloration Technology, 123, 115-118. [Google Scholar] [CrossRef] 
[10] Greenhalgh, R. and Bannard, R.A.B. (1959) The Preparation of Triacetylguanidine and Its Transformation with Alcohol. Canadian Journal of Chemistry, 37, 1810-1812. [Google Scholar] [CrossRef]