Co(Salphen)线型聚合物用于催化2,3,6-三甲基苯酚氧化
Co(Salphen) Linear Polymer for Catalyzing the Oxidation of 2,3,6-Trimethylphenol
DOI: 10.12677/SSC.2019.72003, PDF,   
作者: 张 合, 潘春跃*：中南大学化学化工学院，湖南 长沙
关键词: Suzuki偶联；Co(Salphen)；线型聚合物；2；3；6-三甲基苯酚；Suzuki Coupling； Co(Salphen)； Linear Polymer； 2；3；6-Trimethylphenol
摘要: 以含溴的Co(Salphen) (双水杨醛缩邻苯二胺合钴)和1,4-苯二硼酸通过Suzuki偶联合成了一种含有Co(Salphen)的线型聚合物，其分子量通过凝胶渗透色谱测定，该聚合物用于催化2,3,6-三甲基苯酚氧化，24 h 2,3,6-三甲基苯酚的转化率可以达到99%，且该催化剂可以循环使用3次无明显的转化率和选择性下降。
Abstract: A linear polymer containing Co(Salphen) was synthesized by Suzuki coupling with bromine-containing Co(Salphen) and 1,4-benzenediboronic acid. The molecular weight was determined by gel permeation chromatography. The polymer was used to catalyze the oxidation of 2,3,6-trimethylphenol, the conversion of 2,3,6-trimethylphenol could reach 99% at 24 h and the catalyst could be recycled for 3 times without significant reduction in conversion.
文章引用：张合, 潘春跃. Co(Salphen)线型聚合物用于催化2,3,6-三甲基苯酚氧化[J]. 合成化学研究, 2019, 7(2): 11-17. https://doi.org/10.12677/SSC.2019.72003

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