水系固态锌离子电池的制备与电化学性能研究
Preparation and Electrochemical Performance of Water-Based Solid-State Zinc Ion Batteries
DOI: 10.12677/NAT.2019.93009, PDF,    科研立项经费支持
作者: 袁 怡, 周永恒, 徐智渊, 张 雄*, 张传坤, 马亚楠, 曹明磊：湖北汽车工业学院理学院，湖北 十堰
关键词: 纳米α-MnO2；锌离子电池；固态电解质；Nano α-MnO2； Zinc Ion Battery； Solid Electrolyte
摘要: 水系固态锌离子电池(ZIB)因具有安全、柔性和低成本的特点，在可穿戴电子设备能源领域备受关注。开发具有高锌离子迁移率的固态电解质是水系固态锌离子电池研究的热点之一。本文以明胶、过硫酸钾、丙烯酰胺和 N,N’-亚甲基双丙烯酰胺为原料，采用自由基聚合反应，将聚丙烯酰胺枝接到明胶上，制备得到一种高机械强度和锌离子迁移率(0.37 mS•cm−1)的水系固态凝胶电解质。并以水热法制备得到的α-MnO2为正极材料，电沉积法合成的锌为负电极，组装得到三明治构型的水系固态锌离子电池。在3333 mA/g电流密度下首次放电比容量达到231.5 mAh/g，307 mA/g电流密度下最高比容量达314 mAh/g。
Abstract: The water-based solid state zinc ion battery (ZIB) has attracted much attention in the energy field of wearable electronic devices because of its safety, flexibility and low cost. The development of solid electrolytes with high zinc ion mobility is one of the hotspots for water-based solid state zinc ion batteries. In this paper, gelatin, potassium persulfate, acrylamide and N,N’-methylenebisacrylamide were used as raw materials, and the solid hydrogel electrolyte was prepared through grafting polyacrylamideonto gelatin via free radical polymerization method. The α-MnO2 fabricated by hydrothermal method was used as the positive electrode material, and the zinc synthesized by electrodeposition method was used as negative electrodematerial. As a result, a water-based solid zinc ion battery with a sandwich configuration was assembled. High ionic mobility of 0.37 mS•cm−1 was computed out from the electrochemical impedance spectroscopy. And at the current density of 3333 mA/g, the first specific discharge capacity reached 231.5 mAh/g, and the highest specific capacity at 307 mA/g current density reached 314 mAh/g.
文章引用：袁怡, 周永恒, 徐智渊, 张雄, 张传坤, 马亚楠, 曹明磊. 水系固态锌离子电池的制备与电化学性能研究[J]. 纳米技术, 2019, 9(3): 79-85. https://doi.org/10.12677/NAT.2019.93009

参考文献

[1] Zhang, X., Zhang, B., Peng, K.L., Shen, X.C., Wu, G.T., Yan, Y.C., Luo, S.J., Lu, X., Wang, G.Y., Gu, H.S. and Zhou, X.Y. (2018) Spontaneously Promoted Carrier Mobility and Strengthened Phonon Scattering in p-Type YbZn2Sb2 via a Nanocompositing Approach. Nano Energy, 43, 159-167. [Google Scholar] [CrossRef] 
[2] Zhou, X., Yan, Y., Lu, X., Zhu, H., Han, X., Chen, G. and Ren, Z. (2018) Routes for High-Performance Thermoelectric Materials. Materials Today, 21, 974-988. [Google Scholar] [CrossRef] 
[3] Sun, H., Xie, S., Li, Y., Jiang, Y., Sun, X., Wang, B. and Peng, H. (2016) Large-Area Supercapacitor Textiles with Novel Hierarchical Conducting Structures. Advanced Materials, 28, 8431-8438. [Google Scholar] [CrossRef] [PubMed]
[4] Kou, L., Huang, T., Zheng, B., Han, Y., Zhao, X., Gopalsamy, K., Sun, H. and Gao, C. (2014) Coaxial Wet-Spun Yarn Supercapacitors for High-Energy Density and Safe Wearable Electronics. Nature Communica-tions, 5, Article No. 3754. [Google Scholar] [CrossRef] [PubMed]
[5] Yu, D., Zhai, S., Jiang, W., Goh, K., Wei, L., Chen, X., Jiang, R. and Chen, Y. (2015) Transforming Pristine Carbon Fiber Tows into High Performance Solid-State Fiber Supercapacitors. Advanced Materials, 27, 4895-4901. [Google Scholar] [CrossRef] [PubMed]
[6] Yang, P.H., Liu, K., Chen, Q., Mo, X.B., Zhou, Y.S., Li, S., Feng, G. and Zhou, J. (2016) Wearable Thermocells Based on Gel Electrolytes for the Utilization of Body Heat. Angewandte Chemie International Edition, 55, 12050-12053. [Google Scholar] [CrossRef] [PubMed]
[7] Janek, J. and Zeier, W.G. (2016) A Solid Future for Battery Development. Nature Energy, 1, Article No. 16141. [Google Scholar] [CrossRef] 
[8] Zhou, G., Li, F. and Cheng, H.M. (2014) Progress in Flexible Lithium Batteries and Future Prospects. Energy & Environmental Science, 7, 1307-1338. [Google Scholar] [CrossRef] 
[9] Liu, W., Song, M.S., Kong, B. and Cui, Y. (2017) Flexible and Stretchable Energy Storage: Recent Advances and Future Perspectives. Advanced Ma-terials, 29, Article ID: 1603436. [Google Scholar] [CrossRef] [PubMed]
[10] Wang, X., Lu, X., Liu, B., Chen, D., Tong, Y. and Shen, G. (2014) Flexible Energy-Storage Devices: Design Consideration and Recent Progress. Advanced Materials, 26, 4763-4782. [Google Scholar] [CrossRef] [PubMed]
[11] Li, L., Peng, S., Wu, H.B., Yu, L., Madhavi, S. and Lou, X.W.D. (2015) A Flexi-ble Quasi-Solid-State Asymmetric Electrochemical Capacitor Based on Hierarchical Porous V2O5 Nanosheets on Carbon Nanofibers. Advanced Energy Materials, 5, Article ID: 1500753. [Google Scholar] [CrossRef] 
[12] Huang, Y., Zhu, M., Huang, Y., Pei, Z., Li, H., Wang, Z., Xue, Q. and Zhi, C. (2016) Multifunctional Energy Storage and Conversion Devices. Advanced Materials, 28, 8344-8364. [Google Scholar] [CrossRef] [PubMed]
[13] Huang, Y., Li, H., Wang, Z., Zhu, M., Pei, Z., Xue, Q., Huang, Y. and Zhi, C. (2016) Nanostructured Polypyrrole as a Flexible Electrode Material of Supercapacitor. Nano Energy, 22, 422-438. [Google Scholar] [CrossRef] 
[14] Goodenough, J.B. and Park, K.S. (2013) The Li-Ion Rechargeable Battery: A Perspective. Journal of the American Chemical Society, 135, 1167-1176. [Google Scholar] [CrossRef] [PubMed]
[15] Shen, Y. and Kordesch, K. (2000) The Mechanism of Capacity Fade of Rechargeable Alkaline Manganese Dioxide Zinc Cells. Journal of Power Sources, 87, 162-166. [Google Scholar] [CrossRef] 
[16] Li, H., Xu, C., Han, C., Chen, Y., Wei, C., Li, B. and Kang, F. (2015) Enhancement on Cycle Performance of Zn Anodes by Activated Carbon Modification for Neutral Rechargeable Zinc Ion Batteries. Journal of the Electrochemical Society, 162, A1439-A1444. [Google Scholar] [CrossRef] 
[17] Gaikwad, A.M., Whiting, G.L., Steingart, D.A. and Arias, A.C. (2011) Highly Flexi-ble, Printed Alkaline Batteries Based on Mesh-Embedded Electrodes. Advanced Materials, 23, 3251-3255. [Google Scholar] [CrossRef] [PubMed]
[18] Wang, Z., Wu, Z., Bramnik, N. and Mitra, S. (2014) Fabrication of High-Performance Flexible Alkaline Batteries by Implementing Multiwalled Carbon Nanotubes and Copolymer Separator. Advanced Materials, 26, 970-976. [Google Scholar] [CrossRef] [PubMed]
[19] Xu, C., Li, B., Du, H. and Kang, F. (2012) Energetic Zinc Ion Chemistry: The Re-chargeable Zinc Ion Battery. Angewandte Chemie International Edition, 51, 933-935. [Google Scholar] [CrossRef] [PubMed]
[20] Pan, H., Shao, Y., Yan, P., Cheng, Y., Han, K., Nie, Z., Wang, C., Yang, J., Li, X., Bhattacharya, P., Muellerand, K.T. and Liu, J. (2016) Reversible Aqueous Zinc/Manganese Oxide Energy Storage from Conversion Reactions. Nature Energy, 1, Article No. 16039. [Google Scholar] [CrossRef] 
[21] Lee, B., Yoon, C.S., Lee, H.R., Chung, K.Y., Cho, B.W. and Oh, S.H. (2014) Electrochemically-Induced Reversible Transition from the Tunneled to Layered Poly-morphs of Manganese Dioxide. Scientific Reports, 4, Article No. 6066. [Google Scholar] [CrossRef] [PubMed]
[22] Huang, Y., Zhu, M., Pei, Z., Xue, Q., Wang, Z., Liu, Z., Tang, Z., Wang, Y., Kang, F., Li, B. and Zhi, C. (2018) An Extremely Safe and Wearable Solid-State Zinc Ion Battery Based on a Hierarchical Structured Polymer Elec-trolyte. Energy & Environmental Science, 11, 941-951. [Google Scholar] [CrossRef] 

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