燃料电池用铂基氧还原催化剂的研究
Study on Pt-Based Oxygen Reduction Catalyst for Fuel Cells
DOI: 10.12677/HJCET.2019.95053, PDF,   
作者: 周红茹:上海捷氢科技有限公司,上海
关键词: 氧还原电催化剂燃料电池Oxygen Reduction Electrocatalyst Fuel Cell
摘要: 质子交换膜燃料电池因其环境适应性强、启动快、续驶里程长、加氢时间快等诸多优点,被视为未来汽车动力来源的终极解决方案。燃料电池大规模应用需要比碳载铂氧还原活性更高的电催化剂,并满足高耐久性和低成本的要求,铂基催化剂可以显著提高贵金属质量比活性,改善耐久性,从而降低电催化剂成本。本文总结了今年铂基氧还原催化剂的研究进展,对比不同的制备方法、形貌与暴露晶面对铂基催化剂的影响。
Abstract: Proton Exchange Membrane Fuel Cell (PEMFC) is regarded as the ultimate solution for future ve-hicle power source due to the strong environmental adaptability, fast start-up, long driving range and fast filling time. For the large scale applications of fuel cells, higher oxygen reduction activity, longer durability and lower cost of catalysts are needed than Pt/carbon catalysts. Pt-based catalysts increase significantly noble metal mass specific activity and improve the durability. These characteristics reduce the cost. This paper reviewed the recent achievements in the Pt-based oxy-gen reduction catalysts, compared and analyzed the effects of the synthetic processes, morphologies and facets and oxidation resistant support on mass specific activities and durabilities of alloy catalysts and core shell ones.
文章引用:周红茹. 燃料电池用铂基氧还原催化剂的研究[J]. 化学工程与技术, 2019, 9(5): 374-378. https://doi.org/10.12677/HJCET.2019.95053

参考文献

[1] Shao-Horn, Y., Sheng, W.C., Chen, S., et al. (2007) Instability of Supported Platinum Nanoparticles in Low-Temperature Fuel Cells. Topics in Catalysis, 46, 285-305. [Google Scholar] [CrossRef
[2] Stamenkovic, V., Schmidt, T.J., Ross, P.N., et al. (2002) Surface Composition Effects in Electrocatalysis: Kinetics of Oxygen Reduction on Well-Defined Pt3Ni and Pt3Co Alloy Surfaces. Journal of Physical Chemistry B, 106, 11970-11979. [Google Scholar] [CrossRef
[3] Chen, Z.W., Waje, M., Li, W.Z., et al. (2007) Supportless Pt and PtPd Nanotubes as Electrocatalysts for Oxygen-Reduction Reactions. Angewandte Chemie—International Edition, 46, 4060-4063. [Google Scholar] [CrossRef] [PubMed]
[4] Stamenkovic, V., Mun, B.S., Mayrhofer, K.J.J., et al. (2006) Changing the Activity of Electrocatalysts for Oxygen Reduction by Tuning the Surface Electronic Structure. Angewandte Chemie—International Edition, 45, 2897-2901. [Google Scholar] [CrossRef] [PubMed]
[5] Chen, Y., Liang, Z., Yang, F., Liu, Y. and Chen, S. (2011) Ni-Pt Core-Shell Nanoparticles as Oxygen Reduction Electrocatalysts: Effect of Pt Shell Coverage. Journal of Physical Chemistry C, 115, 24073-24079. [Google Scholar] [CrossRef
[6] Wang, G., Huang, B., Xiao, L., Ren, Z., Chen, H., Wang, D., Abruna, H.D., Lu, J. and Zhuang, L. (2014) Pt Skin on AuCu Intermetallic Substrate: A Strategy to Maximize Pt Utilization for Fuel Cells. Journal of the American Chemical Society, 136, 9643-9649. [Google Scholar] [CrossRef] [PubMed]
[7] Zhang, J., Yang, H.Z., Fang, J.Y., et al. (2010) Synthesis and Oxygen Reduction Activity of Shape-Controlled Pt3Ni Nanopolyhedra. Nano Letters, 10, 638-644. [Google Scholar] [CrossRef] [PubMed]
[8] Cui, C., Gan, L., Heggen, M., et al. (2013) Compositional Segregation in Shaped Pt Alloy Nanoparticles and Their Structural Behaviour during Electrocatalysis. Nature Materials, 12, 765-771. [Google Scholar] [CrossRef] [PubMed]
[9] Wu, J., Zhang, J., Peng, Z., et al. (2010) Truncated Octahedral Pt3Ni Ox-ygen Reduction Reaction Electrocatalysts. Journal of the American Chemical Society, 132, 4984-4985. [Google Scholar] [CrossRef] [PubMed]
[10] Oh, H.-S., Oh, J.-G., Haam, S., et al. (2008) On-Line Mass Spectrometry Study of Carbon Corrosion in Polymer Electrolyte Membrane Fuel Cells. Electrochemistry Communications, 10, 1048-1051. [Google Scholar] [CrossRef
[11] Debe, M.K., Schmoeckel, A.K., Vernstrom, G.D., et al. (2006) High Voltage Stability of Nanostructured Thin Film Catalysts for PEM Fuel Cells. Journal of Power Sources, 161, 1002-1011. [Google Scholar] [CrossRef
[12] Gancs, L., Kobayashi, T., Debe, M.K., et al. (2008) Crystal-lographic Characteristics of Nanostructured Thin-Film Fuel Cell Electrocatalysts: A HRTEM Study. Chemistry of Ma-terials, 20, 2444-2454. [Google Scholar] [CrossRef
[13] Van der Vliet, D., Wang, C., Debe, M., et al. (2011) Platinum-Alloy Nanostructured Thin Film Catalysts for the Oxygen Reduction Reaction. Electrochimica Acta, 56, 8695-8699. [Google Scholar] [CrossRef
[14] Debe, M.K. (2011) Advanced Cathode Catalysts and Supports for PEM Fuel Cells. Annual Merit Review DOE Hydrogen and Fuel Cells and Vehicle Technologies Programs.
[15] Choi, S.-I., Lee, S.-U., Kim, W.Y., Choi, R., Hong, K., Nam, K.M., Han, S.W. and Park, J.T. (2012) Composition-Controlled PtCo Alloy Nanocubes with Tuned Electrocatalytic Activity for Oxygen Reduction. ACS Applied Materials & Interfaces, 4, 6228-6234. [Google Scholar] [CrossRef] [PubMed]
[16] Wu, J., Gross, A. and Yang, H. (2011) Shape and Composition-Controlled Platinum Alloy Nanocrystals Using Carbon Monoxide as Reducing Agent. Nano Letters, 11, 798-802. [Google Scholar] [CrossRef] [PubMed]
[17] Zhang, J., Yang, H., Fang, J. and Zou, S. (2010) Synthesis and Oxygen Reduction Activity of Shape-Controlled Pt3Ni Nanopolyhedra. Nano Letters, 10, 638-644. [Google Scholar] [CrossRef] [PubMed]
[18] Salgado, J.R.C., Paganin, V.A., Gonzalez, E.R., et al. (2013) Characterization and Performance Evaluation of PtRu Electrocatalysts Supported on Different Carbon Materials for Direct Methanol Fuel Cells. International Journal of Hydrogen Energy, 38, 910-920. [Google Scholar] [CrossRef
[19] Wang, Y.J., Wilkinson, D.P., Guest, A., et al. (2013) Synthe-sis of Pd and Nb-Doped TiO2 Composite Supports and Their Corresponding Pt-Pd Alloy Catalysts by a Two-Step Pro-cedure for the Oxygen Reduction Reaction. Journal of Power Sources, 221, 232-241. [Google Scholar] [CrossRef
[20] Li, W.Q., Hu, Z.-Y., Zhang, Z.W., et al. (2019) Nano-Single Crystal Coalesced PtCu Nanospheres as Robust Bifunctional Catalyst for Hydrogen Evolution and Oxygen Reduction Reactions. Journal of Catalysis, 375, 164-170. [Google Scholar] [CrossRef
[21] He, C.Y., Zhang, S.K., Tao, J.Z., et al. (2018) One-Step Solid State Synthesis of PtCo Nanocubes/Graphene Nanocomposites as Advanced Oxygen Reduction Reaction Electrocatalysts. Journal of Catalysis, 362, 85-93. [Google Scholar] [CrossRef
[22] Wu, R.F., Tsiakaras, P. and Shen, P.K. (2019) Facile Synthesis of Bimetallic Pt-Pd Symmetry-Broken Concave Nanocubes and Their Enhanced Activity toward Oxygen Reduction Re-action. Applied Catalysis B: Environmental, 251, 49-56. [Google Scholar] [CrossRef
[23] Ding, J.T., Ji, S., Wang, H., et al. (2018) Nano-Engineered Intrapores in Nanoparticles of PtNi Networks for Increased Oxygen Reduction Reaction Activity. Journal of Power Sources, 374, 48-54. [Google Scholar] [CrossRef