Bi系催化剂光催化氧化VOCs研究进展
Research Progress of Bi-Based Catalysts for Photocatalytic Oxidation of VOCs
DOI: 10.12677/HJCET.2020.102011, PDF,  被引量   
作者: 袁海燕：昆岳互联环境技术(江苏)有限公司，江苏 盐城；朱瑜瑜, 许 琦：盐城工学院化学化工学院，江苏 盐城
关键词: Bi系催化剂；挥发性有机物(VOCs)；光催化；结构调控；Bi-Based Catalyst； Volatile Organic Compounds (VOCs)； Photocatalysis； Structural Control
摘要: 挥发性有机污染物是一类对人体有毒有害的大气污染物。光催化降解技术由于反应条件温和、矿化率高和成本较低等优点，被广泛地应用于挥发性有机污染物的降解。光催化技术的关键在于催化剂成份的配伍、结构调控和稳定性能等。本论文综述了Bi系催化剂的结构和适合的禁带宽度，并通过掺杂、复合等手段来提高其光催化性能，并提出了研究方向。
Abstract: Volatile organic compounds (VOCs) have caused widespread concern about the harm to the en-vironment. Photocatalytic technology has become a popular method for degrading VOCs due to its simple method, high mineralization rate, and lower cost. Based on the introduction of VOCs and the mechanism of photocatalytic degradation, the applications of Bi-based catalysts are briefly described. Bi-based catalysts are ideal materials for degrading VOCs due to their unique layered structure and suitable forbidden band width. Through doping, recombination, etc. in order to improve its catalytic performance, some ideas for the future research direction of pho-tocatalytic degradation of VOCs are put forward.
文章引用：袁海燕, 朱瑜瑜, 许琦. Bi系催化剂光催化氧化VOCs研究进展[J]. 化学工程与技术, 2020, 10(2): 73-81. https://doi.org/10.12677/HJCET.2020.102011

参考文献

[1] Domingo, J.L., Rovira, J., Vilavert, L., et al. (2015) Health Risks for the Population Living in the Vicinity of an Integrated Waste Management Facility: Screening Environmental Pollutants. The Science of the Total Environment, 518, 363-370. [Google Scholar] [CrossRef] [PubMed]
[2] Weschler, C.J. (2006) Ozone’s Impact on Public Health: Contributions from Indoor Exposures to Ozone and Products of Ozone-Initiated Chemistry. Envi-ronmental Health Perspectives, 114, 1489-1496. [Google Scholar] [CrossRef] [PubMed]
[3] Liu, P., Wei, G., He, H., et al. (2019) The Catalytic Oxidation of For-maldehyde over Palygorskite-Supported Copper and Manganese Oxides: Catalytic Deactivation and Regeneration. Applied Surface Science, 464, 287-293. [Google Scholar] [CrossRef] 
[4] 汪智伟, 陈明功, 王旭浩, 等. 处理技术研究现状与进展[J]. 现代化工, 2018, 38(7): 79-83.
[5] Belaissaoui, B., Moullec, Y.L. and Favre, E. (2016) Energy Efficiency of a Hybrid Membrane/Condensation Process for VOC (Volatile Organic Compounds) Recovery from Air: A Generic Approach. Energy, 95, 291-302. [Google Scholar] [CrossRef] 
[6] 许伟, 刘军利, 孙康. 活性炭吸附法在挥发性有机物治理中的应用研究进展[J]. 化工进展, 2016, 35(4): 1223-1229.
[7] 关丽萍. 挥发性有机物(VOCs)末端控制技术实践与发展综述[J]. 现代化工, 2018, 38(9): 64-67.
[8] Nóbrega, P.H.A., Rohani, V. and Fulcheri, L. (2019) Non-Thermal Plasma Treatment of Volatile Organic Compounds: A Predictive Model Based on Experimental Data Analysis. Chemical Engineering Journal, 364, 37-44. [Google Scholar] [CrossRef] 
[9] Mo, J., Zhang, Y. and Xu, Q. (2013) Effect of Water Vapor on the By-Products and Decomposition Rate of PPB-Level Toluene by Photocatalytic Oxidation. Applied Catalysis B: Environmental, 132-133, 212-218. [Google Scholar] [CrossRef] 
[10] Li, J.J., Weng, B., Cai, S.C., et al. (2018) Efficient Promo-tion of Charge Transfer and Separation in Hydrogenated TiO2/WO3 with Rich Surface-Oxygen-Vacancies for Photodecomposition of Gaseous Toluene. Journal of Hazardous Materials, 342, 661-669. [Google Scholar] [CrossRef] [PubMed]
[11] Wang, Y., Yang, C., Chen, A., et al. (2019) Influence of Yolk-Shell Au@ TiO2 Structure Induced Photocatalytic Activity towards Gaseous Pollutant Degradation under Visible Light. Applied Catalysis B: Environmental, 251, 57-65. [Google Scholar] [CrossRef] 
[12] World Health Organization Regional Office for Copenhagen (1987) Air Quality Guidelines for Europe. WHO Regional Publications, European Series, No. 23.
[13] Wei, W., Wang, S.X., Chatani, S., et al. (2008) Emission and Speciation of Non-Methane Volatile Organic Compounds from Anthropogenic Sources in China. Atmospheric Environment, 42, 4976-4988. [Google Scholar] [CrossRef] 
[14] Shah, K.W. and Li, W. (2019) A Review on Catalytic Nanomaterials for Volatile Organic Compounds VOC Removal and Their Applications for Healthy Buildings. Nanomaterials, 9, 910. [Google Scholar] [CrossRef] [PubMed]
[15] 李长英, 陈明功, 盛楠, 等. 挥发性有机物处理技术的特点与发展[J]. 化工进展, 2016, 35(3): 917-925.
[16] 杜鹏生, 姚建, 李毅, 等. 我国大气污染防治政策的评估与建议[J]. 四川环境, 2015, 34(1): 96-100.
[17] Fujishima, A. and Honda, K. (1972) Electrochemical Photolysis of Water at a Semiconductor Electrode. Nature, 238, 37-38. [Google Scholar] [CrossRef] [PubMed]
[18] 唐锋. 降解室内VOCs相关性研究[D]: [硕士学位论文]. 北京: 清华大学, 2010.
[19] Shayegan, Z., Lee, C.S. and Haghighat, F. (2018) TiO2 Photocatalyst for Removal of Volatile Organic Compounds in Gas Phase: A Review. Chemical Engineering Journal, 334, 2408-2439. [Google Scholar] [CrossRef] 
[20] Hoffmann, M.R., Martin, S.T., Choi, W., et al. (1995) Environmental Applications of Semiconductor Photocatalysis. Chemical Reviews, 95, 69-96. [Google Scholar] [CrossRef] 
[21] Mills, A. and Le Hunte, S. (1997) An Overview of Semiconductor Photocatalysis. Journal of Photochemistry and Photobiology A: Chemistry, 108, 1-35. [Google Scholar] [CrossRef] 
[22] Cai, K., Lv, S.Y., Song, L.N., et al. (2019) Facile Prep-aration of Ultrathin Bi2MoO6 Nanosheets for Photocatalytic Oxidation of Toluene to Benzaldehyde under Visible Light Irradiation. Journal of Solid State Chemistry, 269, 145-150. [Google Scholar] [CrossRef] 
[23] Sharma, K., Dutta, V., Sharma, S., et al. (2019) Recent Ad-vances in Enhanced Photocatalytic Activity of Bismuth Oxyhalides for Efficient Photocatalysis of Organic Pollutants in Water: A Review. Journal of Industrial and Engineering Chemistry, 78, 1-2. [Google Scholar] [CrossRef] 
[24] Guo, Y., Wang, P., Qian, J., et al. (2018) Phosphate Group Grafted Twinned BiPO4 with Significantly Enhanced Photocatalytic Activity: Synergistic Effect of Improved Charge Separation Efficiency and Redox Ability. Applied Catalysis B: Environmental, 234, 90-99. [Google Scholar] [CrossRef] 
[25] Park, Y., McDonald, K.J. and Choi, K.-S. (2013) Progress in Bismuth Vanadate Photoanodes for Use in Solar Water Oxidation. Chemical Society Reviews, 42, 2321-2337. [Google Scholar] [CrossRef] 
[26] 丁星, 杨祥龙, 熊中亮, 等. 铋系光催化剂去除环境污染物[J]. 化学进展, 2017, 29(9): 1115-1126.
[27] Zhang, L., Wang, H., Chen, Z., et al. (2011) Bi2WO6 Micro/Nano-Structures: Synthesis, Modifications and Visible-Light-Driven Photocatalytic Applications. Applied Catalysis B: Environmental, 106, 1-13. [Google Scholar] [CrossRef] 
[28] Gui, M.S., Zhang, W.D., Chang, Y.Q., et al. (2012) One-Step Hydrothermal Preparation Strategy for Nanostructured WO3/Bi2WO6 Heterojunction with High Visible Light Photocatalytic Activity. Chemical Engineering Journal, 197, 283-288. [Google Scholar] [CrossRef] 
[29] Kudo, A. and Hijii, S. (1999) H2 or O2 Evolution from Aqueous Solutions on Layered Oxide Photocatalysts Consisting of Bi3+ with 6s2 Configuration and d0 Transition Metal Ions. Chemistry Letters, 28, 1103-1104. [Google Scholar] [CrossRef] 
[30] Zhu, C., Liu, Y., Cao, H., et al. (2019) Insight into the Influence of Morphology of Bi2WO6 for Photocatalytic Degradation of VOCs under Visible Light. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 568, 327-333. [Google Scholar] [CrossRef] 
[31] Xie, T., Zhang, Y., Yao, W., et al. (2019) Synthesis of Bi-Deficient Monolayered Bi2WO6 Nanosheets with Enhanced Photocatalytic Activity under Visible Light Irradiation. Catalysis Science & Technology, 9, 1178-1188. [Google Scholar] [CrossRef] 
[32] 操芳芳. 新型复合BiOX(X=Cl、Br、I)光催化剂的制备及其光催化性能的研究[D]: [硕士学位论文]. 赣州: 江西理工大学, 2013.
[33] 张亚萍. Bi系异质结光催化剂的设计及其抗生素降解机理研究[D]: [硕士学位论文]. 青岛: 青岛科技大学, 2017.
[34] Feng, Y., Li, L., Li, J., et al. (2011) Synthesis of Mesoporous BiOBr 3D Microspheres and Their Photodecomposition for Toluene. Journal of hazardous materials, 192, 538-544. [Google Scholar] [CrossRef] [PubMed]
[35] Li, L., Yang, Y.W., Li, G.H., et al. (2006) Conversion of a Bi Nanowire Array to an Array of Bi-Bi2O3 Core-Shell Nanowires and Bi2O3 Nanotubes. Small, 2, 548-553. [Google Scholar] [CrossRef] [PubMed]
[36] Zhang, L., Wang, W., Yang, J., et al. (2006) Sonochemical Synthesis of Nanocrystallite Bi2O3 as a Visible-Light-Driven Photocatalyst. Applied Catalysis A: General, 308, 105-110. [Google Scholar] [CrossRef] 
[37] Wang, S., Guan, Y., Zeng, R., et al. (2019) Iodine-Deficient BiO1. 2I0. 6 Coupling with Bi2O3 for Degradation of Volatile Organic Compounds under Simulated Sunlight Irradiation. ChemSusChem, 12, 1-9. [Google Scholar] [CrossRef] [PubMed]
[38] Ai, Z., Huang, Y., Lee, S., et al. (2011) Monoclinic α-Bi2O3 Photocatalyst for Efficient Removal of Gaseous NO and HCHO under Visible Light Irradiation. Journal of Alloys and Compounds, 509, 2044-2049. [Google Scholar] [CrossRef] 
[39] 李东泽, 李石, 赵东风, 等. 用于VOCs降解的TiO2光催化剂的研究进展[J]. 现代化工, 2017, 37(11): 39-42.
[40] Guo, S., Li, X., Wang, H., et al. (2012) Fe-Ions Modified Mesoporous Bi2WO6 Nanosheets with High Visible Light Photocatalytic Activity. Journal of Colloid & Interface Science, 369, 373-380. [Google Scholar] [CrossRef] [PubMed]
[41] Sun, Z., Li, X., Guo, S., et al. (2013) One-Step Synthesis of Cl-Doped Pt (IV)/Bi2WO6 with Advanced Visible-Light Photocatalytic Activity for Toluene Degradation in Air. Journal of Colloid and Interface Science, 412, 31-38. [Google Scholar] [CrossRef] [PubMed]
[42] Qian, X., Yue, D., Tian, Z., et al. (2016) Carbon Quantum Dots Decorated Bi2WO6 Nanocomposite with Enhanced Photocatalytic Oxidation Activity for VOCs. Applied Catalysis B: Environmental, 193, 16-21. [Google Scholar] [CrossRef] 
[43] Luo, S., Ke, J., Yuan, M., et al. (2018) CuInS2 Quantum Dots Embedded in Bi2WO6 Nanoflowers for Enhanced Visible Light Photocatalytic Removal of Contaminants. Applied Catalysis B: Environmental, 221, 215-222. [Google Scholar] [CrossRef] 
[44] Wu, Z., Liu, J., Tian, Q., et al. (2017) Efficient Visible Light Formaldehyde Oxidation with 2D p-n Heterostructure of BiOBr/BiPO4 Nanosheets at Room Temperature. ACS Sustainable Chemistry & Engineering, 5, 5008-5017. [Google Scholar] [CrossRef] 
[45] Wang, Y., Jiang, S., Liu, F., et al. (2019) Study on Preparation and Toluene Removal of BiOI/Bi2WO6/ACF Photocatalyst. Applied Surface Science, 488, 161-169. [Google Scholar] [CrossRef] 
[46] Zhang, M., Lu, J., Zhu, C., et al. (2019) Photocatalytic Degradation of Gaseous Benzene with Bi2WO6/Palygorskite Composite Catalyst. Solid State Sciences, 90, 76-85. [Google Scholar] [CrossRef]