锂离子电池镍钴锰三元正极材料研究进展
Recent Development on Ni-Co-Mn Ternary Cathode Material for Lithium-Ion Batteries
DOI: 10.12677/MS.2020.104026, PDF,    国家科技经费支持
作者: 肖广顺, 朱继平*:合肥工业大学,材料科学与工程学院,安徽 合肥
关键词: 锂离子电池镍钴锰三元正极材料制备方法改性研究Lithium-Ion Batteries Ni-Co-Mn Ternary Cathode Material Preparation Method Modification Research
摘要: 为缓解能源危机问题,近年来锂离子电池作为一种新能源得到了长足的发展。正极材料是决定锂离子电池性能的关键,吸引了大量科研人员对其展开研究,三元材料因其性能远优于单一组元的正极材料而备受关注。本文综述了三元正极材料的发展历程及其结构与反应机理,归纳比较了主流的制备方法及其对三元材料结构与性能的影响,概述了进一步提高三元正极材料性能的最新研究进展,对于开发制备高性能三元正极材料具有参考价值。
Abstract: In order to alleviate the energy crisis, lithium-ion batteries have developed rapidly as a new energy in recent years. The cathode material is the key to determine the performance of lithium-ion batteries, which has attracted extensive research. Ternary materials have attracted much attention due to the properties much better than that of single element cathode materials. The development, structure and reaction mechanism of ternary cathode materials are reviewed in this paper. The main preparation methods and their effects on the structure and properties of ternary materials are summarized and compared. The latest research progress on further improving the properties of ternary cathode materials is concluded. It is of reference value for the preparation of high performance ternary cathode materials.
文章引用:肖广顺, 朱继平. 锂离子电池镍钴锰三元正极材料研究进展[J]. 材料科学, 2020, 10(4): 201-215. https://doi.org/10.12677/MS.2020.104026

参考文献

[1] Armand, M. (1980) Materials for Advanced Batteries. Plenum Press, New York.
[2] Ebner, W., Fouchard, D. and Xie, L. (1994) The LiNiO2/Carbon Lithium-Ion Battery. Solid State Ionics Diffusion & Reactions, 69, 238-256. [Google Scholar] [CrossRef
[3] Mizushima, K., Jones, P.C., Wiseman, P.J., et al. (1980) LixCoO2 (0 < x ≤ 1): A New Cathode Material for Batteries of High Energy Density. Materials Research Bulletin, 15, 783-789. [Google Scholar] [CrossRef
[4] Davidson, I.J., McMillan, R.S., Murray, J.J., et al. (1995) Lithium-Ion Cell Based on Orthorhombic LiMnO2. Journal of Power Sources, 54, 232-235. [Google Scholar] [CrossRef
[5] 马璨, 吕迎春, 李泓. 锂离子电池基础科学问题(VII): 正极材料[J]. 储能科学与技术, 2014, 3(1): 53-65.
[6] Tsutomu, O. and Yoshinari, M. (2001) Layered Lithium Inser-tion Material of LiNi1/2Mn1/2O2: A Possible Alternative to LiCoO2 for Advanced Lithium-Ion Batteries. Chemistry Letters, 30, 744-745. [Google Scholar] [CrossRef
[7] Ying, J., Jiang, C. and Wan, C. (2004) Preparation and Characterization of High-Density Spherical LiCoO2 Cathode Material for Lithium Ion Batteries. Journal of Power Sources, 129, 264-269. [Google Scholar] [CrossRef
[8] Yang, H.X., Dong, Q.F., Hu, X.H., et al. (1999) Preparation and Characterization of LiNiO2 Synthesized from Ni(OH)2 and LiOH•H2O. Journal of Power Sources, 79, 256-261. [Google Scholar] [CrossRef
[9] Han, C.H., Kim, J.H., Paeng, S.H., et al. (2009) Electrochemical Characteristics of LiNiO2 Films Prepared for Charge Storable Electrode Application. Thin Solid Films, 517, 4215-4217. [Google Scholar] [CrossRef
[10] Liu, Q., Mao, D., Chang, C., et al. (2007) Phase Conversion and Morphology Evolution during Hydrothermal Preparation of Orthorhombic LiMnO2 Nanorods for Lithium Ion Battery Application. Journal of Power Sources, 173, 538-544. [Google Scholar] [CrossRef
[11] 唐仲丰. 锂离子电池高镍三元正极材料的合成、表征与改性研究[D]: [博士学位论文]. 合肥: 中国科学技术大学, 2018.
[12] 俞会根, 北京汽车新能源汽车有限公司电驱动工程部. 三元正极材料Li[Ni-Co-Mn]O2的研究进展[J]. 电源技术, 2014, 38(9): 1749-1752.
[13] Liu, Z., Yu, A. and Lee, J.Y. (1999) Synthesis and Characterization of LiNi1−x−yCoxMnyO2 as the Cathode Materials of Secondary Lithium Batteries. Journal of Power Sources, 81-82, 416-419. [Google Scholar] [CrossRef
[14] Tsutomu, O. and Yoshinari, M. (2001) Novel Lithium In-sertion Material of LiCo1/3Ni1/3Mn1/3O2 for Advanced Lithium-Ion Batteries. Chemistry Letters, 30, 642-643. [Google Scholar] [CrossRef
[15] Kosova, N.V., Devyatkina, E.T. and Kaichev, V.V. (2007) LiNi1−x−yCoxMnyO2 (x=y=0.1, 0.2, 0.33) Cathode Materials Prepared Using Mechanical Activation: Structure, State of Ions, and Electrochemical Performance. Inorganic Materials, 43, 185-193. [Google Scholar] [CrossRef
[16] 董生德, 周园, 海春喜. 锂离子电池镍钴锰三元正极材料研究进展[J]. 电池, 2018, 48(4): 280-283.
[17] Hayner, C.M., Zhao, X. and Kung, H.H. (2012) Materials for Re-chargeable Lithium-Ion Batteries. Annual Review of Chemical and Biomolecular Engineering, 3, 445-471. [Google Scholar] [CrossRef] [PubMed]
[18] Chakraborty, A., Kunnikuruvan, S., Dixit, M., et al. (2020) Review of Computational Studies of NCM Cathode Materials for Li-Ion Batteries. Israel Journal of Chemistry, 60, 1-14. [Google Scholar] [CrossRef
[19] Hou, P., Yin, J., Ding, M., et al. (2017) Surface/Interfacial Structure and Chemistry of High-Energy Nickel-Rich Layered Oxide Cathodes: Advances and Perspectives. Small, 13, Article ID: 1701802. [Google Scholar] [CrossRef] [PubMed]
[20] Ryu, H.H., Park, K.J., Yoon, C.S., et al. (2018) Capacity Fading of Ni-Rich Li[NixCoyMn1–x–y]O2 (0.6 ≤ x ≤ 0.95) Cathodes for High-Energy-Density Lithium-Ion Batteries: Bulk or Surface Degradation? Chemistry of Materials, 30, 1155-1163. [Google Scholar] [CrossRef
[21] Longo, R.C., Kong, F., Liang, C., et al. (2016) Transition Metal Ordering Optimization for High-Reversible Capacity Positive Electrode Materials in the Li-Ni-Co-Mn Pseudoquaternary System. Journal of Physical Chemistry C, 120, 8540-8549. [Google Scholar] [CrossRef
[22] Liu, J., Qiu, W., Yu, L., et al. (2008) Synthesis and Electrochemical Characterization of Layered Li(Ni1/3Co1/3Mn1/3)O2 Cathode Materials by Low-Temperature Solid-State Reaction. Journal of Alloys and Compounds, 449, 326-330. [Google Scholar] [CrossRef
[23] Tan, L. and Liu, H. (2010) High Rate Charge-Discharge Properties of LiNi1/3Co1/3Mn1/3O2 Synthesized via a Low Temperature Solid-State Method. Solid State Ionics, 181, 1530-1533. [Google Scholar] [CrossRef
[24] Yoon, C.S., Ryu, H.H., Park, G.T., et al. (2018) Extracting Maximum Capacity from Ni-Rich Li[Ni0.95Co0.025Mn0.025]O2 Cathodes for High-Energy-Density Lithium-Ion Batteries. Journal of Materials Chemistry A, 6, 4126-4132. [Google Scholar] [CrossRef
[25] Qiu, H., Wang, Y. and Ye, S. (2018) Rationally-Directed Synthesis and Characterization of Nickel-Rich Cathode Material for Lithium Ion Battery. Energy Technology, 6, 2419-2428. [Google Scholar] [CrossRef
[26] Ren, D., Shen, Y., Yang, Y., et al. (2017) Systematic Optimization of Battery Materials: Key Parameter Optimization for the Scalable Synthesis of Uniform, High-Energy, and High Stability LiNi0.6Mn0.2Co0.2O2 Cathode Material for Lithium-Ion Batteries. ACS Applied Materials & Interfaces, 9, 35811-35819. [Google Scholar] [CrossRef] [PubMed]
[27] Nam, K.M., Kim, H.J., Kang, D.H., et al. (2015) Ammonia-Free Coprecipitation Synthesis of a Ni-Co-Mn Hydroxide Precursor for High-Performance Battery Cathode Materials. Green Chemistry, 17, 1127-1135. [Google Scholar] [CrossRef
[28] Zhou, F., Xu, L. and Kong, J. (2017) Co-Precipitation Synthesis of Precursor with Lactic Acid Acting as Chelating Agent and the Electrochemical Properties of LiNi0.5Co0.2Mn0.3O2 Cathode Materials for Lithium-Ion Battery. Journal of Solid State Electrochemistry, 22, 943-952. [Google Scholar] [CrossRef
[29] Xu, L., Zhou, F., Kong, J., et al. (2017) Synthesis of Li(Ni0.6Co0.2Mn0.2)O2 with Sodium DL-Lactate as an Eco-Friendly Chelating Agent and Its Electrochemical Performances for Lithium-Ion Batteries. Ionics, 24, 2261-2273. [Google Scholar] [CrossRef
[30] 陈鹏, 肖冠, 廖世军. 具有不同组成的镍钴锰三元材料的最新研究进展[J]. 化工进展, 2016, 35(1): 166-174.
[31] Wu, Q., Zhao, L. and Wu, J. (2017) Effects of Chelating Agents on the Performance of Li1.2Mn0.54Ni0.13Co0.13O2 as Cathode Material for Li-Ion Battery Prepared by Sol-Gel Method. Journal of Sol-Gel Science and Technology, 82, 335-343. [Google Scholar] [CrossRef
[32] Lee, S.W., Kim, H., Kim, M.S., et al. (2016) Improved Electrochemical Performance of LiNi0.6Co0.2Mn0.2O2 Cathode Material Synthesized by Citric Acid Assisted Sol-Gel Method for Lithium Ion Batteries. Journal of Power Sources, 315, 261-268. [Google Scholar] [CrossRef
[33] Pişkin, B. and Aydinol, M.K. (2016) Development and Characterization of Layered Li(NixMnyCo1−x−y)O2 Cathode Materials for Lithium Ion Batteries. International Journal of Hydrogen Energy, 41, 9852-9859. [Google Scholar] [CrossRef
[34] Li, T., Li, X., Wang, Z., et al. (2015) Electrochemical Properties of LiNi0.6Co0.2Mn0.2O2 as Cathode Material for Li-Ion Batteries Prepared by Ultrasonic Spray Pyrolysis. Materials Letters, 159, 39-42. [Google Scholar] [CrossRef
[35] 邹邦坤, 丁楚雄, 陈春华. 锂离子电池三元正极材料的研究进展[J]. 中国科学: 化学, 2014, 44(7): 1104-1115.
[36] Yang, C., Huang, J., Huang, L., et al. (2013) Electrochemical Performance of LiCo1/3Mn1/3Ni1/3O2 Hollow Spheres as Cathode Material for Lithium Ion Batteries. Journal of Power Sources, 226, 219-222. [Google Scholar] [CrossRef
[37] Xiong, W., Jiang, Y., Yang, Z., et al. (2014) High-Performance Hierarchical LiNi1/3Mn1/3Co1/3O2 Microspheres Synthesized via a Facile Template-Sacrificial Route. Journal of Alloys and Compounds, 589, 615-621. [Google Scholar] [CrossRef
[38] Li, J., Xiong, S., Liu, Y., et al. (2013) Uniform LiNi1/3Co1/3Mn1/3O2 Hollow Microspheres: Designed Synthesis, Topotactical Struc-tural Transformation and Their Enhanced Electrochemical Performance. Nano Energy, 2, 1249-1260. [Google Scholar] [CrossRef
[39] Li, Y., Wu, C., Bai, Y., et al. (2016) Hierarchical Mesoporous Lithium-Rich Li[Li0.2Ni0.2Mn0.6]O2 Cathode Material Synthesized via Ice Templating for Lithium-Ion Battery. ACS Applied Materials & Interfaces, 8, 18832-18840. [Google Scholar] [CrossRef] [PubMed]
[40] Zang, Y., Ding, C.-X., Wang, X.-C., et al. (2015) Molybdenum-Doped Lithium-Rich Layered-Structured Cathode Material Li1.2Ni0.2Mn0.6O2 with High Specific Capacity and Improved Rate Performance. Electrochimica Acta, 168, 234-239. [Google Scholar] [CrossRef
[41] Liu, D., Fan, X., Li, Z., et al. (2019) A Cation/Anion Co-Doped Li1.12Na0.08Ni0.2Mn0.6O1.95F0.05 Cathode for Lithium Ion Batteries. Nano Energy, 58, 786-796. [Google Scholar] [CrossRef
[42] Li, X., Zhang, K., Wang, M., et al. (2018) Dual Functions of Zirconium Modification on Improving the Electrochemical Performance of Ni-Rich LiNi0.8Co0.1Mn0.1O2. Sustainable Energy & Fuels, 2, 413-421. [Google Scholar] [CrossRef
[43] Mi, C., Han, E., Li, L., et al. (2018) Effect of Iron Doping on LiNi0.35Co0.30Mn0.35O2. Solid State Ionics, 325, 24-29. [Google Scholar] [CrossRef
[44] Lu, C., Yang, S., Wu, H., et al. (2016) Enhanced Electrochemical Performance of Li-Rich Li1.2Mn0.52Co0.08Ni0.2O2 Cathode Materials for Li-Ion Batteries by Vanadium Doping. Elec-trochimica Acta, 209, 448-455. [Google Scholar] [CrossRef
[45] Qin, C., Cao, J., Chen, J., et al. (2016) Improvement of Electrochemical Performance of Nickel Rich LiNi0.6Co0.2Mn0.2O2 Cathode Active Material by Ultrathin TiO2 Coating. Dalton Trans, 45, 9669-9675. [Google Scholar] [CrossRef
[46] Mao, L., Ai, L., Li, S., et al. (2018) Improved Electrochemical Properties of Nickel Rich LiNi0.6Co0.2Mn0.2O2 Cathode Materials by Al2O3 Coating. [Google Scholar] [CrossRef
[47] Li, S., Fu, X., Zhou, J., et al. (2016) An Effective Approach to Improve the Electrochemical Performance of LiNi0.6Co0.2Mn0.2O2 Cathode by an MOF-Derived Coating. Journal of Materials Chemistry A, 4, 5823-5827. [Google Scholar] [CrossRef
[48] Kong, J.Z., Wang, S.S., Tai, G.A., et al. (2016) Enhanced Electrochemical Performance of LiNi0.5Co0.2Mn0.3O2 Cathode Material by Ultrathin ZrO2 Coating. Journal of Alloys and Compounds, 657, 593-600. [Google Scholar] [CrossRef
[49] Kong, J.Z., Ren, C., Tai, G.A., et al. (2014) Ultrathin ZnO Coating for Improved Electrochemical Performance of LiNi0.5Co0.2Mn0.3O2 Cathode Material. Journal of Power Sources, 266, 433-439. [Google Scholar] [CrossRef
[50] He, J.R., Chen, Y.F., Li, P.J., et al. (2014) Synthesis and Electrochemical Properties of Graphene-Modified LiCo1/3Ni1/3Mn1/3O2 Cathodes for Lithium Ion Batteries. RSC Advances, 4, 2568-2572. [Google Scholar] [CrossRef
[51] Cho, W., Kim, S.M., Song, J.H., et al. (2015) Improved Electrochemical and Thermal Properties of Nickel Rich LiNi0.6Co0.2Mn0.2O2 Cathode Materials by SiO2 Coating. Journal of Power Sources, 282, 45-50. [Google Scholar] [CrossRef
[52] Liu, S., Wu, H., Huang, L., et al. (2016) Synthesis of Li2Si2O5-Coated LiNi0.6Co0.2Mn0.2O2 Cathode Materials with Enhanced High-Voltage Electrochemical Properties for Lithium-Ion Batteries. Journal of Alloys & Compounds, 674, 447-454. [Google Scholar] [CrossRef