累托石吸附处理含铅废水试验结果
Rectorite Adsorption Treatment Results of Lead-Containing Wastewater
DOI: 10.12677/JWRR.2020.93036, PDF,  被引量   
作者: 俞旭唯, 万 瑀, 王营茹:武汉工程大学化学与环境工程学院,湖北 武汉
关键词: 累托石含铅废水吸附处理试验结果Rectorite Lead-Containing Wastewater Adsorption Treatment Experiment Results
摘要: 选取累托石作为吸附剂用于废水中铅离子的去除,探究铅离子初始浓度、吸附剂投加量、反应时间、温度等因素对铅离子去除的影响。实验结果表明:REC吸附处理Pb(II)的最佳条件为:初始浓度100 mg•L−1、累托石用量5 g•L−1、吸附温度25℃、吸附时间40 min,Pb(II)去除率可达62.12%。累托石吸附Pb(II)能较好地拟合Langmuir模型,该材料吸附处理铅离子过程更加符合准二级动力学模型。累托石对Pb(II)的去除过程以化学吸附为主导,反应过程与累托石表面的活性位点和吸附质之间的离子交换速率、表面沉淀有关。
Abstract: The rectorite was applied to remove lead-containing ion of wastewater in laboratory experiment. The influencing factors such as the initial lead ion concentration, rectorite dosage, reaction time and the temperature were investigated. The experiment results and optimal conditions for rectorite adsorption treatment of Pb(II) are that the initial concentration, rectorite dosage, adsorption temperature and time are 100 mg∙L−1, 25˚C, 5 g∙L−1 and 40 min, respectively. The removal rate of lead ion can reach 62.12%. The adsorption isotherm was well described by Langmuir model and the process of adsorption kinetic data fitted a pseudo-second-order model. The removal process of rectorite for Pb(II) was dominated by chemical adsorption and related to the ion exchange and surface precipitation between the active sites on rectorite surface and adsorbate.
文章引用:俞旭唯, 万瑀, 王营茹. 累托石吸附处理含铅废水试验结果[J]. 水资源研究, 2020, 9(3): 344-352. https://doi.org/10.12677/JWRR.2020.93036

参考文献

[1] TIAN, Z., ZHANG, L., SHI, G., SANG, X., and NI, C. The synthesis of modified alginate flocculants and their properties for removing heavy metal ions of wastewater. Journal of Applied Polymer Science, 2018, 135(31): 46577. [Google Scholar] [CrossRef
[2] 邓曼君, 王学江, 成雪君, 景焕平, 赵建夫. 鸟粪石天然沸石复合材料对水中铅离子的去除[J]. 环境科学, 2019, 40(3): 1310-1317. DENG Manjun, WANG Xuejiang, CHENG Xuejun, JING Huanping, and ZHAO Jianfu. Removal of lead ions from water by struvite natural zeolite composite. Environmental Science, 2019, 40(3): 1310-1317. (in Chinese)
[3] LI, S., WANG, W., LIANG, F., and ZHANG, W. X. Heavy metal removal using nanoscale zero-valent iron (nZVI): Theory and application. Jour-nal of Hazardous Materials, 2017, 322: 163-171. [Google Scholar] [CrossRef] [PubMed]
[4] 杨海, 黄新, 林子增, 何秋玫, 丁炜. 离子交换法处理重金属废水的研究进展[J]. 应用化工, 2019, 48(7): 1675-1680. YANG Hai, HUANG Xin, LIN Zizeng, HE Qiumei, and DING Wei. Research progress in the treatment of heavy metal waste-water by ion exchange. Applied Chemical Industry, 2019, 48(7): 1675-1680. (in Chinese)
[5] 范先媛, 谢升昌, 刘红, 丁俊霞, 卢琦, 薛壮壮, 等. 4A分子筛去除水中Pb2+、Cd2+、Zn2+、Cu2+性能和机理[J]. 环境科学与技术, 2019, 42(5): 46-52. FAN Xianyuan, XIE Shengchang, LIU Hong, DING Junxia, LU Qi, XIE Zhuangzhuang, et al. Performances and mechanism for Pb2+, Cd2+, Zn2+ and Cu2+ removal from aqueous solution by 4A-molecular sieve. Environmental Science & Technology, 2019, 42(5): 46-52. (in Chinese)
[6] MEI, H., YU, S., TAN, X., WANG, S., CHEN, C., and LI, J. Evaluation of the influence of environmental conditions on the removal of Pb(II) from wastewater by Ca-Rectorite. Separation Science and Technology, 2015, 50(15): 2257-2266. [Google Scholar] [CrossRef
[7] ABDI, G., ALIZADEH, A., ZINADINI, S., and MORADI, G. Removal of dye and heavy metal ion using a novel synthetic polyethersulfone nanofiltration membrane modified by magnetic graphene oxide/metfor•min-1 hybrid. Journal of Membrane Science, 2018, 552: 326-335.[CrossRef
[8] 吴楠, 王三反, 宋小三, 李乐卓, 张雪. 电化学/水解/接触氧化/离子交换处理有机金属废水[J]. 中国给水排水, 2019, 35(16): 94-96+102. WU Nan, WANG Sanfan, SONG Xiaosan, LI Lezhuo, and ZHANG Xue. Treatment of organometallic wastewater by electro-chemistry, hydrolytic acidification, biological contact oxidation and ion exchange process. China Water & Wastewater, 2019, 35(16): 94-96+102. (in Chinese)
[9] HUANG, Y., WU, D., WANG, X., HUANG, W., LAWLESS, D., and FENG, X. Re-moval of heavy metals from water using polyvinylamine by polymer-enhanced ultrafiltration and flocculation. Separation and Purification Technology, 2016, 158: 124-136.[CrossRef
[10] HOU, T., DU, H., YANG, Z., TIAN, Z., SHEN, S., SHI, Y., et al. Flocculation of different types of combined contaminants of antibiotics and heavy metals by thermo-responsive flocculants with various architectures. Separation and Purification Technology, 2019, 223: 123-132.[CrossRef
[11] BAO, T., DAMTIE, M. M., WU, K., WEI, X. L., ZHANG, Y., CHEN, J., et al. Rectorite-supported nano-Fe3O4 composite materials as catalyst for P-chlorophenol degradation: Preparation, characterization, and mechanism. Applied Clay Science, 2019, 176, 66-77.[CrossRef
[12] ZENG, L., CHEN, Y., ZHANG, Q., GUO, X., PENG, Y., XIAO, H., et al. Adsorption of Cd(II), Cu(II) and Ni(II) ions by cross-linking chitosan/rectorite nano-hybrid composite microspheres. Carbohydrate Polymers, 2015, 130: 333-343. [Google Scholar] [CrossRef] [PubMed]
[13] SHEN, Y., YU, X., and WANG, Y. Facile synthesis of modified recto-rite (M-REC) for effective removal of anionic dye from water. Journal of Molecular Liquids, 2019, 278: 12-18. [Google Scholar] [CrossRef
[14] 李东, 杜卫刚, 郭迎卫, 蒋金龙, 谭立强. 钠基累托石对模拟废水中Ni2+的吸附研究[J]. 非金属矿, 2018, 41(5): 79-82. LI Dong, DU Weigang, GUO Yingwei, JIANG Jinlong, and TAN Liqiang. Study on the sorption of Ni2+ onto Na-rectorite from simulated wastewater. Non-Metallic Mines, 2018, 41(5): 79-82. (in Chinese)
[15] WANG, N., FENG, Z., MA, X., and ZHENG, P. The modification of rectorite with carbon layers and trisodium trimetaphosphate for the removal of Pb2+. Applied Clay Science, 2017, 146: 115-121.[CrossRef
[16] MA, J., LUO, J., LIU, Y., WEI, Y., CAI, T., YU, X., et al. Pb(II), Cu(II) and Cd(II) removal using a humic substance-based double network hydrogel in individual and multicomponent systems. Journal of Materials Chemistry A, 2018, 6(41): 20110-20120. [Google Scholar] [CrossRef
[17] 卜帅宾, 孟昭福, Yek S, 张梦飞, 王腾, 任爽, 等. Cu2+和Pb2+在BS-12两性修饰膨润土上的吸附及其交互作用[J]. 环境科学, 2019, 40(10): 4611-4619. BU Shuaibin, MENG Zhaofu, YEK S, ZHANG Mengfei, WANG Teng, REN Shuang, et al. Adsorption and interaction of Cu2+ and Pb2+ on BS-12 amphoteric modified bentonites. Environmental Science, 2019, 40(10): 4611-4619. (in Chinese)