油基钻井液乳液稳定性影响因素研究
The Influence Study on Stability of Oil-Based Drilling Fluids Emulsion
DOI: 10.12677/JOGT.2020.422016, PDF,    科研立项经费支持
作者: 何瑞兵, 谢 涛, 董平华:中海石油(中国)有限公司天津分公司,天津;刘雪婧, 耿 铁:中海油田服务股份有限公司油田化学事业部,河北 燕郊
关键词: 油基钻井液乳液微观形貌界面张力平均粒径稳定性Oil-Based Drilling Fluid Emulsion Microscopic Appearance Average Particle Size Stability
摘要: 为充分了解油基钻井液乳液稳定性影响因素,选择了界面张力值低的乳化剂PF-EMUL-2与PF-COAT-2配制乳液。研究了乳化剂浓度、油水比、内相盐浓度与种类、基液种类以及重晶石对乳液稳定性的影响。研究发现,3 wt% PF-EMUL-2与1 wt% PF-COAT-2复配时,随着油水比增大,乳液稳定性增强,与Na+离子相比,Ca2+离子能提高乳液滴的界面膜强度。高温老化后重晶石吸附部分乳化剂,造成乳化能力下降,因此高密度钻井液中需加入较多的乳化剂稳定乳液。这些研究为控制油基钻井液体系的稳定性提供理论基础。
Abstract: In order to fully understand the influence on the stability of oil-based drilling fluid emulsion, emulsifiers PF-EMUL-2 and PF-COAT-2 were selected to prepare emulsion. The influence of emul-sifier concentration, oil-water ratio, concentration and type of internal salt, type of base liquid and barite on emulsion stability were studied. The results show that, the emulsion stability increases with the increase of oil-water ratio, and compared with Na+, Ca2+ ions can improve the interfacial film strength of emulsion droplets. The study also shows that barite adsorbs some emulsifiers after high-temperature aging, which results in a decrease of emulsifying affection, so more emulsifiers should be added to stabilize the emulsion in high-density drilling fluid. All the studies provide theoretical basis for controlling the stability of oil-based drilling fluid system.
文章引用:何瑞兵, 刘雪婧, 谢涛, 耿铁, 董平华. 油基钻井液乳液稳定性影响因素研究[J]. 石油天然气学报, 2020, 42(2): 56-65. https://doi.org/10.12677/JOGT.2020.422016

参考文献

[1] 鄢捷年. 钻井液工艺学[M]. 北京: 石油大学出版社, 2012: 89-110.
[2] 王中华. 国内外油基钻井液研究与应用进展[J]. 断块油气田, 2011, 18(4): 533-537.
[3] 何涛, 李茂森, 杨兰平, 等. 油基钻井液在威远地区页岩气水平井中的应用[J]. 钻井液与完井液, 2012, 29(3): 1-5.
[4] 康毅力, 杨斌, 游利军, 等. 油基钻井完井液对页岩储层保护能力评价[J]. 天然气工业, 2013, 33(12): 99-104.
[5] 王旭东, 郭保雨, 张海青, 等. 抗高温油包水型乳化剂的研制与应用[J]. 钻井液与完井液, 2013, 30(4): 9-12.
[6] McLachlan, A.A. (2007) Synthesis and Characterization of the Solution Properties of Novel Amine Functional Surfactants.
[7] Zaera, F. (2011) Surface Chemistry at the Liq-uid/Solid Interface. Surface Science, 605, 1141-1145. [Google Scholar] [CrossRef
[8] 李明远, 吴肇亮. 石油乳状液[M]. 北京: 科学出版社, 2009: 72.
[9] Evans, N., Langlois, B., Audibert-Hayet, A., Dalmazzone, C. and Deballe, E. (2000) High Performance Emulsifiers for Synthetic Based Muds. SPE Annual Technical Conference and Exhibition, Dallas, 1-4 October 2000, SPE-63101-MS. [Google Scholar] [CrossRef
[10] Kang, W. and Wang, D. (2001) Emulsification Characteristic and De-Emulsifiers Action for Alkaline/Surfactant/Polymer Flooding. SPE Asia Pacific Improved Oil Recovery Conference, Kuala Lumpur, 6-9 October 2001, SPE-72138-MS. [Google Scholar] [CrossRef
[11] 许明标, 唐海雄, 曾晶, 等. 一种高效油基钻井液乳化剂的加量极限[J]. 石油天然气学报, 2009, 30(5X): 278-280.
[12] Burrows, K., Evans, J., Hall, J. and Kirsner, J. (2001) New Low Viscosity Ester Is Suitable for Drilling Fluids in Deepwater Applications. SPE/EPA/DOE Exploration and Production Environmental Conference, San Antonio, 26-28 February 2001, SPE-66553-MS. [Google Scholar] [CrossRef
[13] Messler, D., Kippie, D. and Webb, T. (2002) Improved Techniques of Deepwater SBM Displacements: A Case History. International Symposium and Exhibition on Formation Damage Con-trol, Lafayette, 20-21 February 2002, SPE-73711-MS. [Google Scholar] [CrossRef
[14] Aston, M., Mihalik, P., Tunbridge, J. and Clarke, S. (2002) Towards Zero Fluid Loss Oil Based Muds. Proceedings—SPE Annual Technical Conference and Exhibition, San Antonio, 29 Sep-tember-2 October 2002, 1021-1029. [Google Scholar] [CrossRef
[15] Growcock, F.B., Khan, A.M. and Simon, G.A. (2003) Application of Water-Based and Oil-Based Aphrons in Drilling Fluids. SPE International Symposium on Oilfield Chemistry, Houston, 5-7 February 2003, 79-85. [Google Scholar] [CrossRef
[16] Fimreite, G., Asko, A., Massam, J., Taugbol, K., Omland, T.H., Svanes, K., Kroken, W., Andreassen, E. and Saasen, A. (2004) Invert Emulsion Fluids for Drilling through Narrow Hydraulic Windows. SPE/IADC Drilling Conference, Dallas, 2-4 March 2004, SPE-87128-MS. [Google Scholar] [CrossRef