低品位氧化锌烟尘还原–精馏技术制备超细锌粉
Study on Preparation of Superfine Zinc Powder with the Reduction-Distillation Technique from Low-Grade Zinc Oxide Dust
DOI: 10.12677/MEng.2020.73022, PDF,    科研立项经费支持
作者: 毕婷婷*:云南省生态环境工程评估中心,云南 昆明;夏 妮, 李桥龙, 罗 通:中国电建集团北京勘测设计研究院有限公司,北京;谢容生#:云南东曼环保科技有限公司,云南 昆明
关键词: 氧化锌烟尘低品位超细锌粉有价金属Zinc Oxide Dust Low-Grade Superfine Zinc Powder Valuable Metals
摘要: 采用还原–精馏技术对低品位氧化锌烟尘制备超细锌粉进行了工业化试验。结果表明,超细锌粉的含锌纯度高达99.991%,锌直收率为93.199%。元素平衡结果表明,锌主要富集于产品超细锌粉中,铅元素主要富集于高铅锌中,其占比为92.32%。利用低品位氧化锌烟尘制备超细锌粉工艺可行,有价金属回收效果显著,能够为氧化锌烟尘高附加资源化利用提供参考。
Abstract: Industrialization test of preparation of superfine zinc powder with the reduction-distillation technique from low-grade zinc oxide dust was carried out. The results showed that the purity of zinc in superfine zinc powder was 99.991%, and the direct yield of zinc was 93.199%. Moreover, the results of element balance indicated that zinc was mainly concentrated in superfine zinc powder, and lead was mainly concentrated in high lead and zinc, accounting for 92.32%. It was feasible to prepare superfine zinc powder from low-grade zinc oxide dust, and the recovery effect of valuable metals was remarkable. This study provides a reference for the high additional resource utilization of zinc oxide dust.
文章引用:毕婷婷, 夏妮, 李桥龙, 罗通, 谢容生. 低品位氧化锌烟尘还原–精馏技术制备超细锌粉[J]. 冶金工程, 2020, 7(3): 155-162. https://doi.org/10.12677/MEng.2020.73022

参考文献

[1] 侯新刚, 王胜, 王玉棉. 超细活性锌粉的制备与表征[J]. 粉末冶金工业, 2004, 14(1): 10-13.
[2] 伍祥武. 优级细锌粉的生产实践[J]. 有色金属(冶炼部分), 2002(3): 42-44.
[3] 刘全民, 王彦军, 张鑫, 等. 锌粉制备技术现状与趋势[J]. 南方金属, 2015(1): 1-3, 36.
[4] 林峰, 雷晓旭, 王进保, 等. 超细锌粉的制备及其应用前景[J]. 材料保护, 2013, 46(5):48-51.
[5] 王子谦, 王乐津. 锌锭反射炉法生产锌粉实践[J]. 有色冶炼, 1998, 27(1): 20-21.
[6] 彭容秋. 锌冶金[M]. 长沙: 中南大学出版社, 2005.
[7] 赵杨, 邢杰, 安俊菁, 等. 回转窑还原焙烧锌冶炼污泥与烟尘回收研究[J]. 有色金属(冶炼部分), 2017(2): 11-15.
[8] 森维, 彭林, 雷胜, 等. 高铅氧化锌烟尘综合回收的生产实践与设计改进[J]. 有色金属(冶炼部分), 2015(1): 11-14.
[9] 李哲雄, 王成彦, 尹锡矛, 等. 从含锗氧化锌烟尘中提取锌锗[J]. 有色金属(冶炼部分), 2017(9): 45-47, 53.
[10] Zhang, L.B., Ma, A., Liu, C., et al. (2014) Di-electric Properties and Temperature Increase Characteristics of Zinc Oxide Dust from Fuming Furnace. Transactions of Nonferrous Metals Society of China, 24, 4004-4011. [Google Scholar] [CrossRef
[11] Li, X., Zhang, Y., Qin, B., et al. (2010) Indium Recovery from Zinc Oxide Flue Dust by Oxidative Pressure Leaching. Transactions of Nonferrous Metals Society of China, 20, s141-s145. [Google Scholar] [CrossRef
[12] 谢容生, 谢天鉴, 刘维维, 等. 锌冶炼石膏渣还原分解热力学分析[J]. 环境科学与技术, 2018, 41(2): 151-156.