仿生超疏水表面应用及展望研究
Application and Prospect of Bionic Superhydrophobic Surface
DOI: 10.12677/MS.2020.109086, PDF,    科研立项经费支持
作者: 王 雷, 赵 爽*, 李文月：北京信息科技大学，仪器科学与光电工程系，北京；余 锦：中国科学院大学，光电学院，北京；中国科学院空天信息创新研究院，北京；何建国：中国科学院大学，光电学院，北京；中国科学院空天信息创新研究院，北京；中国科学院计算光学成像技术重点实验室，北京
关键词: 仿生；超疏水；工业化；表面湿润性；应用；Bionic； Superhydrophobic； Industrialization； Surface Wettability； Application
摘要: 超疏水表面是指液滴在其表面的接触角大于150˚的特殊湿润性表面，在近年来, 那些具有特殊润湿性的超疏水表面引起了一股研究热潮，由于其独特的润湿性能，有着减阻、防水、耐腐蚀等诸多优异性能，在工业及科研领域有着很高的研究和应用价值。本文基于近年来仿生超疏水研究进程，对比了传统超疏水材料加工方式与短脉冲激光加工的不同，以工业化为出发点，从多元化角度介绍分析了超疏水材料在不同的制备方法、不同的功能性应用和其中的潜在问题，并对超疏水材料的应用发展前景系统的进行展望探讨。
Abstract: Super-hydrophobic surface refers to a special wettability surface where the contact angle of the droplet on the surface is greater than 150°. In recent years, those super-hydrophobic surfaces with special wettability have caused a research boom due to their unique wetting properties. It has many excellent properties such as drag reduction, water resistance, corrosion resistance, etc., and has high research and application value in the field of industry and scientific research. Based on the research progress of biomimetic superhydrophobic materials in recent years, this paper compares the difference between traditional superhydrophobic material processing methods and short-pulse laser processing. Taking industrialization as the starting point, this paper introduces and analyzes the different preparation methods and functions of superhydrophobic materials from a diversified perspective. The application and potential problems, and the prospects for the application and development of superhydrophobic materials are systematically discussed.
文章引用：王雷, 余锦, 赵爽, 何建国, 李文月. 仿生超疏水表面应用及展望研究[J]. 材料科学, 2020, 10(9): 713-727. https://doi.org/10.12677/MS.2020.109086

参考文献

[1] 刘学英. 海洋涂料的现状及开发前策化[J]. 新型材料, 1991, 19(12): 8-11.
[2] Neinhuis, C. and Barthlott, W. (1997) Characterization and Distribution of Water-Repellent, Self-Cleaning Plant Surfaces. Annals of Botany, 79, 667-677. [Google Scholar] [CrossRef] 
[3] Koch, K., Bhushan, B. and Barthlott, W. (2008) Diversity of Structure, Morphology and Wetting of Plant Surfaces. Soft Matter, 4, 1943-1963. [Google Scholar] [CrossRef] 
[4] Feng, L., Li, S.H., Li, Y.S., et al. (2002) Super-Hydrophobic Surfaces: From Natural to Artificial. Advanced Materials, 14, 1857-1860. [Google Scholar] [CrossRef] 
[5] Roach, P., Shirtcliffe, N.J. and Newton, M.I. (2008) Progress in Super Hydrophobic Surface Development. Soft Matter, 4, 224-240. [Google Scholar] [CrossRef] 
[6] 邱宝玉. 仿生自清洁外墙涂料的制备[D]: [硕士学位论文]. 南昌: 南昌大学, 2006.
[7] 张梅, 孟军锋, 孙哲, 等. 低表面能涂层在飞机防除冰领域的研究进展与应用[J]. 现代涂料与涂装, 2010, 13(9): 10-15.
[8] 梁曦东, 王晶, 蔡元纪, 等. 复合绝缘子表面污层固着及其对绝缘性能的影响[J]. 高电压技术, 2013, 39(6): 1296-1303.
[9] Duparré, A., Flemming, M., Steinert, J., et al. (2002) Optical Coatings with Enhanced Roughness for Ultrahydrophobic, Low-Scatter Applications. Applied Optics, 41, 3294-3298. [Google Scholar] [CrossRef] 
[10] Zhang, H., Lamb, R. and Lewis, J. (2005) Engineering Nanoscale Roughness on Hydrophobic Surface-Preliminary Assessment of Fouling Behaviour. Science and Technology of Ad-vanced Materials, 6, 236-239. [Google Scholar] [CrossRef] 
[11] 金成锋. 基于天然纤维素物质纳米修饰的疏水材料的制备及性质研究[D]: [硕士学位论文]. 杭州: 浙江大学, 2012.
[12] 段薇. 棉织物超疏水表面的仿生制备与表征[D]: [硕士学位论文]. 合肥: 安徽大学, 2011.
[13] Guo, Z.G., Liu, W.M. and Su, B.L. (2008) Why So Strong for the Lotus Leaf? Applied Physics Letters, 93, Article ID: 201909. [Google Scholar] [CrossRef] 
[14] Zhang, X., Shi, F., Niu, J., et al. (2008) Superhydrophobic Surfaces: Form Structural Control to Functional Application. Journal of Mate-rials Chemistry, 18, 621-633. [Google Scholar] [CrossRef] 
[15] 周明. 仿生功能表面微结构的超快激光制备与应用研究[J]. 功能材料信息, 2009, 6(3): 14-19.
[16] 付德亮. 激光加工运动控制及数控编程的研究[D]: [硕士学位论文]. 青岛: 中国海洋大学, 2013.
[17] 韩雨洋, 张志攀, 曲良体. 激光结构化仿生表面[J]. 科学通报, 2019, 64(12): 1238-1253.
[18] Long, J., Zhong, M., Zhang, H., et al. (2015) Superhydrophilicity to Superhydrophobi-city Transition of Picosecond Laser Microstructured Aluminum in Ambient Air. Journal of Colloid and Interface Science, 441, 1-9. [Google Scholar] [CrossRef] 
[19] Barthlott, W. and Neinhuis, C. (1997) The Purity of Sacred Lotus or Es-cape from Contamination in Biological Surfaces. Planta, 202, 1-8. [Google Scholar] [CrossRef] 
[20] Jiang, L., Zhao, Y. and Zhai, J. (2004) A Lotus-Leaf-Like Superhydrophobic Surface: A Porous Microsphere/Nanofiber Composite Film Prepared by Electro-Hydrodynamics. Angewandte Chemie International Edition, 43, 4338-4341. [Google Scholar] [CrossRef] [PubMed]
[21] Akkan, C.K., Hür, D., Uzun, L. and Garipcan, B. (2016) Amino Acid Conjugated Self Assembling Molecules for Enhancing Surface Wettability of Fiber Laser Treated Titanium Surfaces. Applied Surface Science, 36, 284-291. [Google Scholar] [CrossRef] 
[22] 王中平, 孙振平, 金明. 表面物理化学[M]. 北京: 科学出版社, 2015.
[23] Pan, H., Luo, F., Lin, G., Wang, C., Dong, M., Liao, Y. and Zhao, Q.Z. (2015) Quasi-Superhydrophobic Porous Silicon Surface Fabricated by Ultrashort Pulsed-Laser Ablation and Chemical Etching. Chemical Physics Letters, 637, 159-163. [Google Scholar] [CrossRef] 
[24] Wenzel, R.N. (1936) Resistance of Solid Surfaces to Wetting by Water. Industrial & Engineering Chemistry, 28, 988-994. [Google Scholar] [CrossRef] 
[25] Baxter, S. and Cassie, B.D. (1944) Wettability of Porous Surfaces. Transactions of the Faraday Society, 40, 546-551. [Google Scholar] [CrossRef] 
[26] Wang, H., Zhou, H., Gestos, A., et al. (2013) Robust, Su-per-Amphiphobic Fabrie with Multiple Self-Healing Ability against Both Physical and Chemical Damages. ACS Applied Materials & Interfaces, 5, 1022-10226. [Google Scholar] [CrossRef] [PubMed]
[27] Wang, S., Feng, L. and Jiang, L. (2006) One-Step Solution-Immersion Process for the Fabrication of Stable Bionic Superhydrophobic Surfaces. Advanced Materials, 18, 767-770. [Google Scholar] [CrossRef] 
[28] Woo, K.C., Sung, M.K., Dong, J.K., et al. (2006) Formation of Superhydrophobic Surfaces by Biomimetic Silicification and Fluorination. Langmuir, 22, 11208-11213. [Google Scholar] [CrossRef] [PubMed]
[29] Yamauchi, G., Miller, J.D., Saito, H., et al. (1996) Wetting Characteristics of Newly Developed Water-Repellent Material. Colloids & Surfaces: A Physicochemical & Engineering Aspects, 116, 125-134. [Google Scholar] [CrossRef] 
[30] Puretskiy, N. and Ionov, L. (2011) Synthesis of Robust Raspberry-Like Particles Using Polymer Brushes. Langmuir, 27, 3006-3011. [Google Scholar] [CrossRef] [PubMed]
[31] Tian, N., et al. (2018) Mechanically Robust and Thermally Stable Colorful Superamphiphobic Coatings. Frontiers in Chemistry, 6, 144. [Google Scholar] [CrossRef] [PubMed]
[32] Cui, Z., et al. (2009) A Facile Dip-Coating Process for Preparing Highly Durable Superhydrophobic Surface with Multi-Scale Structures on Paint Films. Journal of Colloid & Interface Science, 337, 531-537. [Google Scholar] [CrossRef] [PubMed]
[33] Brown, P.S. and Bhushan, B. (2015) Mechanically Durable, Su-peroleophobic Coatings Prepared by Layer-by-Layer Technique for Anti-Smudge and Oil-Water Separation. Scientific Reports, 5, Article No. 8701. [Google Scholar] [CrossRef] [PubMed]
[34] Xu, Q.F., Mondal, B. and Lyons, A.M. (2011) Fabricating Superhydro-phobic Polymer Surfaces with Excellent Abrasion Resistance by a Simple Lamination Templating Method. Acs Applied Materials & Interfaces, 3, 3508-3514. [Google Scholar] [CrossRef] [PubMed]
[35] Chao, X., Yang, L., Pan, H., et al. (2012) Fabrication, Temperature Sta-bility and Characteristics of Pb(ZrxTiy)O3- Pb(Zn1/3Nb2/3)O3-Pb(Ni1/3Nb2/3)O3 Piezoelectric Ceramics Bimorph. Ceramics International, 38, 3377-3382. [Google Scholar] [CrossRef] 
[36] 罗晓民, 魏梦媛, 曹敏. 耐腐蚀超疏水铜网的制备及其在油水分离中的应用[J]. 材料工程, 2018, 46(5): 96-102.
[37] 范伟博, 刘艳花, 王顺花, 强小虎, 冯利邦. 镁合金表面超疏水化及耐腐蚀性能[J]. 化工新型材料, 2013, 41(8): 67-69.
[38] Bharathidasan, T., Kumar, S.V., Bobji, M.S., et al. (2014) Effect of Wettability and Surface Roughness on Ice-Adhesion Strength of Hydrophilic, Hydrophobic and Superhydrophobic Surfaces. Applied Surface Science, 314, 241-250. [Google Scholar] [CrossRef] 
[39] 张迅, 曾华荣, 田承越, 马晓红, 熊青. 大气压等离子体制备超疏水表面及其防冰抑霜研究[J]. 电工技术学报, 2019, 34(24): 5289-5296.
[40] 向美苏, 李非, 张延宗. 溶胶凝胶法制备甲基三甲氧基硅烷-γ-(2,3-环氧丙氧)丙基三甲氧基硅烷复合超疏水涂层[J]. 涂料工业, 2017, 47(1): 1-5.
[41] Wang, D., Liu, Y., Liu, X., et al. (2009) Towards a Tunable and Switchable Water Adhesion on a TiO2 Nanotube Film with Patterned Wettability. Chemical Communications, No. 45, 7018-7020. [Google Scholar] [CrossRef] [PubMed]
[42] Verplanck, N., Galopin, E., Camart, J., et al. (2007) Reversible Electro-wetting on Superhydrophobic Silicon Nanowires. Nano Lettles, 7, 813-817. [Google Scholar] [CrossRef] [PubMed]
[43] Yoshimitsu, Z., Nakajima, A., Watanabe, T. and Hashimoto, K. (2002) Effects of Surface Structure on the Hydrophobicity and Sliding Behavior of Water Droplets. Langmuir, 18, 5818-5822. [Google Scholar] [CrossRef] 
[44] Choi, C.H., Ulmanella, U., Kim, J., et al. (2006) Effective Slip and Friction Reduction in Nanograted Superhydrophobic Microchannels. Physics of Fluids, 18, Article ID: 087105. [Google Scholar] [CrossRef] 
[45] Wang, D., Sun, Q., Hokkanen, M.J., et al. (2020) Design of Robust Su-perhydrophobic Surfaces. Nature, 582, 55-59. [Google Scholar] [CrossRef] [PubMed]

为你推荐