糠醛选择性加氢成糠醇的催化及理论研究
Catalysis and Theoretical Study on Selective Hydrogenation of Furfural to Furfuryl Alcohol
DOI: 10.12677/AMC.2020.84009, PDF,   
作者: 岑 洁*, 张云奕：浙江师范大学含氟新材料研究所，浙江 金华
关键词: 糠醛；选择性加氢；糠醇；理论化学；Furfural； Selective Hydrogenation； Furfuryl Alcohol； Computational Chemistry
摘要: 糠醛是一种重要的生物质燃料生产的中间体。对糠醛进行选择性加氢得到糠醇是工业与生产中重要的化学反应之一。传统的Cr催化剂对环境污染大，所以急切需要开发低碳环保并且具有高选择性的催化剂来进行糠醛的选择性加氢反应。本文从实验化学和理论计算化学领域，总结了近年来部分国内外用于糠醛选择性加氢成糠醇的催化剂，并从理论化学层面揭示反应机理，为之后该反应提供实验与理论的指导与支撑。
Abstract: Furfural is an important intermediate in the production of biomass fuels. Selective hydrogenation of furfural to obtain furfuryl alcohol is one of the important chemical reactions in industry and production. Traditional Cr catalysts have a great environmental pollution, so there is an urgent need to develop low-carbon, environmentally friendly and highly selective catalysts for the selective hydrogenation of furfural. This article summarizes some domestic and foreign catalysts used in the selective hydrogenation of furfural to furfuryl alcohol from the fields of experimental chemistry and theoretical computational chemistry, and reveals the reaction mechanism from the theoretical chemistry level to provide experimental and theoretical guidance and support for the subsequent reaction.
文章引用：岑洁, 张云奕. 糠醛选择性加氢成糠醇的催化及理论研究[J]. 材料化学前沿, 2020, 8(4): 70-75. https://doi.org/10.12677/AMC.2020.84009

参考文献

[1] Kriegler, E., Bauer, N., Popp, A., Humpenöder, F., Leimbach, M., Strefler, J., Baumstark, L., Bodirsky, B. L., Hilaire, J., Klein, D., Mouratiadou, I., Weindl, I., Bertram, C., Dietrich, J.-P., Luderer, G., Pehl, M., Pietzcker, R., Piontek, F., Lotze-Campen, H., Biewald, A., Bonsch, M., Giannousakis, A., Kreidenweis, U., Müller, C., Rolinski, S., Schultes, A., Schwanitz, J., Stevanovic, M., Calvin, K., Emmerling, J., Fujimori, S. and Edenhofer, O. (2017) Fossil-Fueled Development (SSP5): An Energy and Resource Intensive Scenario for the 21st Century. Global Environmental Change, 42, 297-315.
[Google Scholar] [CrossRef] 
[2] Climent, M.J., Velty, A. and Corma, A. (2002) Design of a Solid Catalyst for the Synthesis of a Molecule with Blossom Orange Scent. Green Chemistry, 4, 565-569.
[Google Scholar] [CrossRef] 
[3] Durndell, L.J., Zou, G., Shangguan, W., Lee, A.F. and Wilson, K. (2019) Structure-Reactivity Relations in Ruthenium Catalysed Furfural Hydrogenation. ChemCatChem, 11, 3927-3932.
[Google Scholar] [CrossRef] 
[4] Barakat, A., de Vries, H. and Rouau, X. (2013) Dry Fractionation Process as an Important Step in Current and Future Lignocellulose Biorefineries: A Review. Bioresource Technology, 134, 362-373.
[Google Scholar] [CrossRef] [PubMed]
[5] Taylor, M.J., Durndell, L.J., Isaacs, M.A., Parlett, C.M.A., Wilson, K., Lee, A.F. and Kyriakou, G. (2016) Highly Selective Hydrogenation of Furfural over Supported Pt Nanoparticles under Mild Conditions. Applied Catalysis B: Environmental, 180, 580-585.
[Google Scholar] [CrossRef] 
[6] Li, H., Zhang, S. and Luo, H. (2004) A Ce-Promoted Ni-B Amorphous Alloy Catalyst (Ni-Ce-B) for Liquid-Phase Furfural Hydrogenation to Furfural Alcohol. Materials Letters, 58, 2741-2746.
[Google Scholar] [CrossRef] 
[7] Nagaraja, B.M., Siva Kumar, V., Shasikala, V., Padmasri, A.H., Sreedhar, B., David Raju, B. and Rama Rao, K.S. (2003) A Highly Efficient Cu/MgO Catalyst for Vapour Phase Hydrogenation of Furfural to Furfuryl Alcohol. Catalysis Communications, 4, 287-293.
[Google Scholar] [CrossRef] 
[8] Mandalika, A., Qin, L., Sato, T.K. and Runge, T. (2014) Integrated Biorefinery Model Based on Production of Furans Using Open-Ended High Yield Processes. Green Chemistry, 16, 2480-2489.
[Google Scholar] [CrossRef] 
[9] Katz, S.A. and Salem, H. (1993) The Toxicology of Chromium with Respect to Its Chemical Speciation: A Review Journal of Applied Toxicology, 13, 217-224.
[10] Sitthisa, S., Sooknoi, T., Ma, Y., Balbuena, P.B. and Resasco, D.E. (2011) Kinetics and Mechanism of Hydrogenation of Furfural on Cu/SiO2 Catalysts. Journal of Catalysis, 277, 1-13.
[Google Scholar] [CrossRef] 
[11] Li, F., Cao, B., Ma, R., Liang, J., Song, H. and Song, H. (2016) Performance of Cu/TiO2-SiO2 Catalysts in Hydrogenation of Furfural to Furfuryl Alcohol. The Canadian Journal of Chemical Engineering, 94, 1368-1374.
[Google Scholar] [CrossRef] 
[12] Radhakrishan, R., Do, D.M., Jaenicke, S., Sasson, Y. and Chuah, G.-K. (2011) Potassium Phosphate as a Solid Base Catalyst for the Catalytic Transfer Hydrogenation of Aldehydes and Ketones. ACS Catalysis, 1, 1631-1636.
[Google Scholar] [CrossRef] 
[13] Dalpozzo, R. (2015) Magnetic Nanoparticle Supports for Asymmetric Catalysts. Green Chemistry, 17, 3671-3686.
[Google Scholar] [CrossRef] 
[14] Wang, F. and Zhang, Z. (2016) Catalytic Transfer Hydrogenation of Furfural into Furfuryl Alcohol over Magnetic γ-Fe2O3@HAP Catalyst. ACS Sustainable Chemistry & Engineering, 5, 942-947.
[15] Chen, L., Luque, R. and Li, Y. (2017) Controllable Design of Tunable Nanostructures inside Metal-Organic Frameworks. Chemical Society Reviews, 46, 4614-4630.
[Google Scholar] [CrossRef] 
[16] Chughtai, A.H., Ahmad, N., Younus, H. A., Laypkov, A. and Verpoort, F. (2015) Metal-Organic Frameworks: Versatile Heterogeneous Catalysts for Efficient Catalytic Organic Transformations. Chemical Society Reviews, 44, 6804-6849.
[Google Scholar] [CrossRef] 
[17] Long, Y., Song, S., Li, J., Wu, L., Wang, Q., Liu, Y., Jin, R. and Zhang, H. (2018) Pt/CeO2@MOF Core@Shell Nanoreactor for Selective Hydrogenation of Furfural via the Channel Screening Effect. ACS Catalysis, 8, 8506-8512.
[Google Scholar] [CrossRef] 
[18] Shi, Y., Zhu, Y., Yang, Y., Li, Y.-W. and Jiao, H. (2015) Exploring Furfural Catalytic Conversion on Cu(111) from Computation. ACS Catalysis, 5, 4020-4032.
[Google Scholar] [CrossRef] 
[19] Wang, S., Vorotnikov, V. and Vlachos, D.G. (2014) Coverage-Induced Conformational Effects on Activity and Selectivity: Hydrogenation and Decarbonylation of Furfural on Pd(111). ACS Catalysis, 5, 104-112.