硼对铁基形状记忆合金组织与性能的影响
Influence of Boron on Microstructure and Properties of Fe Based Shape Memory Alloy
DOI: 10.12677/MS.2020.1011101, PDF,    科研立项经费支持
作者: 周 希, 王 静*, 肖秀婵, 李 玺：成都工业学院，四川 成都；叶 宇：四川省西冶奥兴铸造有限公司，四川 成都
关键词: Fe基形状记忆合金；硼(B)；组织；性能；Fe Based Shape Memory Alloy； Boron； Microstructure； Properties
摘要: 利用真空熔炼技术制备了添加硼和不添加硼(B)的Fe基形状记忆合金。利用扫描电镜(SEM)、能谱仪(EDS)、X射线衍射仪(XRD)对合金进行了微观结构和组成分析；研究了B对Fe基合金显微硬度、回复率和抗硫化氢腐蚀性能的影响。结果表明：实验制得的Fe基形状记忆合金具有较高的回复率，且随着压缩量的增加回复率逐渐减小；合金中加入B可促进组织细化和Cr23C6的析出；相比不添加B的Fe基形状记忆合金，含B合金的显微硬度提高了12.4%，回复率显著增加，并且在较大变形量下保证了合金更加稳定的形状记忆效应；在硫化氢腐蚀环境下，添加B的Fe形状记忆合金表面的可形成致密的氧化膜，有效降低硫化氢的腐蚀速率，提供其腐蚀性能。
Abstract: Vacuum melting technology was used to prepare Fe based shape memory alloy with addition of Boron or non-Boron. Scanning electron microscope (SEM), energy dispersive spectrometer (EDS) and X-ray diffraction (XRD) were used to study the microstructure and composition of the Fe based alloy. The effect of boron to the micro-hardness, shape recovery percentage and Hydrogen Sulfide corrosion properties of the obtained alloy were also analyzed. The results show that the produced Fe based shape memory alloy had good shape recovery ability. In addition, the shape recovery effect of the alloys decreased with compress deformation increasing, gradually. The addition of Boron can promote microstructure refinement and the precipitation of Cr23C6. Comparing with the alloy without Boron, the micro-hardness of alloy with addition of Boron increased 12.4% and exhibited a better shape recovery percentage, developing a more stable shape memory ability at larger deformation condition. The dense oxide film would form on the surface of the alloy with adding Boron, which could effectively decrease the corrosion rate by Hydrogen Sulfide.
文章引用：周希, 王静, 肖秀婵, 李玺, 叶宇. 硼对铁基形状记忆合金组织与性能的影响[J]. 材料科学, 2020, 10(11): 843-850. https://doi.org/10.12677/MS.2020.1011101

参考文献

[1] 张招贤, 钛电极工学[M]. 北京: 冶金工业出版社, 2003.
[2] Marauyama, T. and Kubo, K. (2011) Ferrous (Fe-Based) Shape Memory Alloys (SMAs): Properties, Processing and Applications. In: Yamauchi, K., et al., Eds., Shape Memory and Superelastic Alloys: Applications and Technologies, Woodhead Publishing Ltd., Cambridge, 141-159. [Google Scholar] [CrossRef] 
[3] Wang, C.P., Wen, Y.H., Peng, H.B., et al. (2011) Factors Affecting Recovery Stress in Fe-Mn-Si-Cr-Ni-C Shape Memory Alloys. Materials Science and Engineering: A, 528, 1125-1130. [Google Scholar] [CrossRef] 
[4] 程晓敏, 梅丽君, 吴兴文, 等. 热处理工艺对Fe-Mn-Si-Cr-Ni合金形状记忆效应的影响[J]. 金属热处理, 2009, 34(2): 56-58.
[5] Zhang, X.Y., Zhang, J.W. and Wang, W.K. (2000) Crystallization Process of an Amorphous Sm8Fe85Si2C5 Alloy under High Pressure. Journal of Magnetism and Materials, 219, 199-205. [Google Scholar] [CrossRef] 
[6] 杨军, 邓龙江, 王昕, 等. 快速凝固对Fe-Mn-Si系形状记忆合金组织与性能的影响[J]. 功能材料, 2011, 42(4): 711-713.
[7] 杨军, 扬眉, 王平, 等. 热-机械循环训练对Fe-15Mn-4Si-8Cr-4Ni形状记忆合金耐腐蚀性能和低温松弛的影响[J]. 金属功能材料, 2009, 16(6): 5-7.
[8] 张林. 时效免训练对Fe-Mn-Si基形状记忆合金性能的影响[D]: [硕士学位论文]. 天津: 天津大学, 2012.
[9] 耿永红. 时效调控型Fe-Ni-Co-Al-Ta-B合金的热弹性马氏体相变研究[D]: [博士学位论文]. 上海: 上海交通大学, 2015.
[10] 张成燕, 宋帆, 王珊玲, 等. Mn含量对Fe-Mn-Si-Cr-Ni合金记忆效应的影响机制[J]. 金属学报, 2015, 51(2): 201-208.
[11] 陈淑娟, 何国球, 马行驰, 等. Fe-Mn-Si系形状记忆合金研究近况[J]. 材料导报, 2006, 20(12): 66-69.
[12] Stanford, N. and Dunne, D.P. (2010) Effect of Si on the Reversibility of Stress-Induced Martensite in Fe-Mn-Si Shape Memory Alloys. Acta Materialia, 58, 6752-6762. [Google Scholar] [CrossRef] 
[13] Miyazaki, S., Kakeshita, T., Nishida, M., et al. (2013) Pro-ceedings of the International Conference on Martensitic Transformations (ICOMAT-2011). Journal of Alloys and Compounds, 577, S1.
[14] 杨光山, 康福伟, 马宝霞, 等. Cr和RE对Fe-Mn-Si-C合金形状记忆效应的影响规律[J]. 机械工程师, 2008(1): 62-64.
[15] 陈晓敏, 周小芳, 吴兴文. Fe-Mn-Si基形状记忆效应及腐蚀性[J]. 中国水运, 2006, 4(12): 27-29.
[16] 胡锐, 付恒志, 李金山, 等. Ni含量与与变形量对Fe基形状记忆合金记忆效应的影响[J]. 材料热处理学报, 2006, 27(4): 11-14.
[17] Liu, W.B., Wen, Y.H., Li, N., et al. (2009) Effect of Electropulsing Treatment on Stress-Induced ε Martensite Transformation of a Pre-Deformed Fe17Mn5Si8Cr5Ni0.5NbC Alloy. Mate-rials Science and Engineering A, 507, 114-116. [Google Scholar] [CrossRef] 
[18] 刘文博, 李宁, 杨世洲, 等. 电脉冲处理对FeMnSiCrNiNbC合金NbC析出及记忆效应的影响[J]. 稀有金属材料与工程, 2009, 38(1): 164-167.
[19] Yang, S.Z., Li, N., Wen, Y.H., et al. (2013) Effects of Ageing with Electric Pulse Treatment on Shape Memory Effect and Precipitation of Cr23C6 Carbide in a Pre-Deformed Fe-Mn-Si-Cr-Ni-C Alloy. Rare Metal Materials and Engineering, 42, 238-242. [Google Scholar] [CrossRef] 
[20] 杨光山. C、Cr、Ni、RE及热处理对Fe-Mn-Si形状记忆合金记忆效应的影响研究[D]: [硕士学位论文]. 哈尔滨: 哈尔滨理工大学, 2008.
[21] Wang, T.P., Lin, H.C., Lin, K.M., et al. (2008) Effects of Slight Re Addition on a Fe-25Mn-6Si-5Cr Shape Memory Alloy. Journal of Computa-tional and Theoretical Nanoscience, 5, 1753-1757. [Google Scholar] [CrossRef] 
[22] Lin, K.M., Chen, J.H., Lin, C.C., et al. (2014) Optimization of Shape Memory Effect in Fe-Mn-Si-Cr-Re Shape Memory Alloys. Journal of Materials Engineering and Performance, 23, 2327-2332. [Google Scholar] [CrossRef] 
[23] 向学渊, 何国求, 莫德峰, 等. Fe-15Mn-5Si-9Cr-5Ni形状记忆合金回复性能及微观结构演变[J]. 材料导报, 2009, 23(1): 51-53.
[24] 叶邦斌, 彭华备, 雄隆荣, 等. 形变时效对不同Cr含量Fe-Mn-Si-Cr-Ni-C合金记忆效应的影响[J]. 材料热处理学报, 2009, 30(3): 10-13.

为你推荐