铋基宽光谱响应光催化材料的研究进展
Research Progress in Bismuth-Based Photocatalysts with Wide Spectral Response
DOI: 10.12677/HJCET.2020.106056, PDF,   
作者: 黄圣男, 朱德雨, 代嘉伟, 田雪松, 陈 嵘, 高 洪*:武汉工程大学化学与环境工程学院,绿色化工过程教育部重点实验室,新型反应器与绿色化学工艺湖北省重点实验室,湖北 武汉
关键词: 铋基光催化剂近红外宽光谱响应废水处理Bismuth-Based Photocatalysts Near-Infrared Light Wide Spectral Response Wastewater Treatment
摘要: 在污水处理中,基于半导体光催化法的高级氧化技术(AOPs)由于其高效、节能、可循环利用的优点而被广泛研究。然而大多数光催化剂仅能被紫外光激发,为了进一步利用光能节约能源,开发宽光谱响应的光催化剂显得尤为重要。众多光催化剂中,铋基光催化剂其特殊的能带结构使其具有良好的可见光甚至近红外光响应。本文重点概述了具有宽光谱响应的铋基光催化剂的制备方法,并系统地归纳了其改性手段及其在环境污染物去除方面的催化活性性能,最后对该类具有宽光谱响应的铋基光催化剂的发展方向进行了展望。
Abstract: Advanced oxidation technology (AOPs) based on semiconductor photocatalysis has been widely studied in wastewater treatment due to its advantages of high efficiency, energy saving and recycling. However, most photocatalysts can only be excited by ultraviolet light. It is crucial to develop photocatalysts with wide spectral response to further expand the light response range and save energy. Among many photocatalysts, bismuth-based photocatalysts have good response upon visible and even near-infrared light due to its special energy band structure. In this paper, the synthesis of bismuth-based photocatalysts with wide spectral response is given in outline, and the modification methods and their catalytic performance in the removal of environmental pollutants are systematically summarized. Finally, the development direction of bismuth-based photocatalysts with wide spectral response is prospected.
文章引用:黄圣男, 朱德雨, 代嘉伟, 田雪松, 陈嵘, 高洪. 铋基宽光谱响应光催化材料的研究进展[J]. 化学工程与技术, 2020, 10(6): 435-441. https://doi.org/10.12677/HJCET.2020.106056

参考文献

[1] Xu, L. and Wang, J. (2012) Magnetic Nanoscaled Fe3O4/CeO2 Composite as an Efficient Fenton-Like Heterogeneous Catalyst for Degradation of 4-Chlorophenol. Environmental Science & Technology, 46, 10145-10153. [Google Scholar] [CrossRef] [PubMed]
[2] Wang, L., Zhang, Q., Chen, B., Bu, Y, Chen, Y., Ma, J., Rosario-Ortiz, F.L. and Zhu, R. (2020) Some Issues Limiting Photo(cata)lysis Application in Water Pollutant Control: A Critical Review from Chemistry Perspectives. Water Research, 174, 115605. [Google Scholar] [CrossRef] [PubMed]
[3] Van Aken, P., Van den Broeck, R., Degrève, J. and Dewil, R. (2015) The Effect of Ozonation on the Toxicity and Biodegradability of 2,4-Dichlorophenol-Containing Wastewater. Chemical Engineering Journal, 280, 728-736. [Google Scholar] [CrossRef
[4] Wang, Y., Wei, Y., Song, W., Chen, C. and Zhao, J. (2018) Pho-tocatalytic Hydrodehalogenation for the Removal of Halogenated Aromatic Contaminants. ChemCatChem, 11, 258-268. [Google Scholar] [CrossRef
[5] Fujishima, A. and Honda, K. (1972) Electrochemical Photolysis of Water at a Semiconductor Electrode. Nature, 238, 37-38. [Google Scholar] [CrossRef] [PubMed]
[6] Li, J., Wu, X., Pan, W., Zhang, G. and Chen, H. (2018) Vacancy-Rich Monolayer BiO2−x as a Highly Efficient UV, Visible, and Near-Infrared Responsive Photocatalyst. Angewandte Chemie-International Edition, 57, 491-495. [Google Scholar] [CrossRef] [PubMed]
[7] Dai, Z., Qin, F., Zhao, H., Ding, J., Liu, Y. and Chen, R. (2016) Crystal Defect Engineering of Aurivillius Bi2MoO6 by Ce Doping for Increased Reactive Species Production in Pho-tocatalysis. ACS Catalysis, 6, 3180-3192. [Google Scholar] [CrossRef
[8] Hu, X., Zhao, H., Liang, Y. and Chen, R. (2019) Energy Level Mediation of (BiO)2CO3 Via Br Doping for Efficient Molecular Oxygen Activation and Ciprofloxacin Photodegradation. Applied Catalysis B: Environmental, 258, 117966. [Google Scholar] [CrossRef
[9] Tang, H., Dai, Z.,Xie, X., Wen, Z. and Chen, R. (2019) Pro-motion of Peroxydisulfate Activation over Cu0.84Bi2.08O4 for Visible Light Induced Photodegradation of Ciprofloxacin in Water Matrix. Chemical Engineering Journal, 356, 472-482. [Google Scholar] [CrossRef
[10] Wang, H., Xie, Z., Wang, X. and Jia, Y. (2020) NaBiS2 as a Novel Indirect Bandgap Full Spectrum Photocatalyst: Synthesis and Application. Catalysts, 10, 413-423. [Google Scholar] [CrossRef
[11] Wang, H., Ding, J., Xu, H.,Qiao, L., Wang, X. and Lin, Y. (2019) One-Pot Synthesis of BiCuSO Nanosheets under Ambient Atmosphere as Broadband Spectrum Photocatalyst. Nano-materials (Basel), 9, 540. [Google Scholar] [CrossRef] [PubMed]
[12] Tian, J., Sang, Y., Yu, G., Jiang, H., Mu, X. and Liu, H. (2013) A Bi2WO6-Based Hybrid Photocatalyst with Broad Spectrum Photocatalytic Properties under UV, Visible, and Near-Infrared Irradiation. Advance Materials, 25, 5075-5080. [Google Scholar] [CrossRef] [PubMed]
[13] Lv, C., Chen, G., Zhou, X., Zhang, C., Wang, Z., Zhao, B. and Li, D. (2017) Oxygen-Induced Bi(5+)-Self-Doped Bi4V2O11 with a P-N Homojunction toward Promoting the Photocatalytic Performance. ACS Applied Materials & Interfaces, 9, 23748-23755. [Google Scholar] [CrossRef] [PubMed]
[14] Wang, W., Chen, X., Liu, G., Shen, Z., Xia, D., Wong, P.K. and Yu, J.C. (2015) Monoclinic Dibismuth Tetraoxide: A New Visible-Light-Driven Photocatalyst for Environmental Remedia-tion. Applied Catalysis B: Environmental, 176-177, 444-453. [Google Scholar] [CrossRef
[15] Meng, A., Zhang, L., Cheng, B. and Yu, J. (2019) Dual Cocat-alysts in TiO2 Photocatalysis. Advance Materials, 31, 1807660-1807691. [Google Scholar] [CrossRef] [PubMed]
[16] Chen, D., Cheng, Y., Zhou, N., Chen, P., Wang, Y., Li, K.,Huo, S., Cheng, P., Peng, P., Zhang, R., Wang, L., Liu, H., Liu, Y. and Ruan, R. (2020) Photocatalytic Degradation of Organic Pollutants Using TiO2-Based Photocatalysts: A Review. Journal of Cleaner Production, 268, 121725. [Google Scholar] [CrossRef
[17] Serpone, N. (2006) Is the Band Gap of Pristine TiO2 Narrowed by Anion- and Cation-Doping of Titanium Dioxide in Second-Generation Photocatalysts? Journal of Physical Chemistry B, 110, 24287-24293. [Google Scholar] [CrossRef] [PubMed]
[18] Liu, F., Leung, Y., Djurišić, A., Ng, A. and Chan, W. (2013) Native De-fects in ZnO: Effect on Dye Adsorption and Photocatalytic Degradation. The Journal of Physical Chemistry C, 117, 12218-12228. [Google Scholar] [CrossRef
[19] Sun, H., Yip, H., Jiang, Z., Ye, L., Lo, I. and Wong, P. (2018) Facile Synthesis of Oxygen Defective Yolk-Shell BiO2−x for Visible-Light-Driven Photocatalytic Inactivation of Escherichia coli. Journal of Materials Chemistry A, 6, 4997-5005. [Google Scholar] [CrossRef
[20] Wang, J., Zhang, Z., Wang, X., Shen, Y., Guo, Y., Wong, P. and Bai, R. (2018) Synthesis of Novel P-N Heterojunctionm-Bi2O4/BiOCl Nanocomposite with Excellent Photocatalytic Activity through Ion-Etching Method. Chinese Journal of Catalysis, 39, 1792-1803. [Google Scholar] [CrossRef
[21] Wang, M., Tan, G., Zhang, D., Li, B., Lv, L., Wang, Y., Ren, H., Zhang, X., Xia, A. and Liu, Y. (2019) Defect-Mediated Z-Scheme BiO2−x/Bi2O2.75 Photocatalyst for Full Spectrum Solar-Driven Organic Dyes Degradation. Applied Catalysis B: Environmental, 254, 98-112. [Google Scholar] [CrossRef
[22] Xia, D.H. and Lo, I.M.C. (2016) Synthesis of Magnetically Separable Bi2O4/Fe3O4 Hybrid Nanocomposites with Enhanced Photocatalytic Removal of Ibuprofen under Visible Light Irradiation. Water Research, 100, 393-404. [Google Scholar] [CrossRef] [PubMed]
[23] Jia, Y., Li, S., Ma, H., Gao, J., Zhu, G., Zhang, F., Park, J.Y., Cha, S., Bae, J.S. and Liu, C. (2019) Oxygen Vacancy Rich Bi2O4-Bi4O7-BiO2−x Composites for UV-Vis-NIR Activated High Efficient Photocatalytic Degradation of Bisphenol A. Journal of Hazardous Materials, 382, 121121. [Google Scholar] [CrossRef] [PubMed]
[24] Li, J., Li, Y., Zhang, G., Huang, H. and Wu, X. (2019) One-Dimensional/Two-Dimensional Core-Shell-Structured Bi2O4/BiO2−x Heterojunction for Highly Efficient Broad Spectrum Light-Driven Photocatalysis: Faster Interfacial Charge Transfer and Enhanced Molecular Oxygen Activation Mechanism. ACS Applied Materials & Interfaces, 11, 7112-7122. [Google Scholar] [CrossRef] [PubMed]
[25] Jin, J., Sun, J.,Lv, K., Guo, X., Liu, J., Bai, Y., Huang, X., Liu, J. and Wang, J. (2020) Oxygen-Vacancy-Rich BiO2−x/Ag3PO4/CNT Composite for Polycyclic Aromatic Hydrocarbons (Pahs) Removal Via Visible and Near-Infrared Light Irradiation. Industrial & Engineering Chemistry Research, 59, 5725-5735. [Google Scholar] [CrossRef
[26] Li, L., Liu, Z., Guo, L., Fan, H. and Tao, X. (2019) NaBiO3/BiO2−x Composite Photocatalysts with Post-Illumination “Memory” Activity. Materials Letters, 234, 30-34. [Google Scholar] [CrossRef
[27] Zhang, H., Zheng, H., Wang, Y., Yan, R., Luo, D. and Jiang, W. (2019) KBiO3 as an Effective Visible-Light-Driven Photocatalyst: Stability Improvement by in Situ Constructing KBiO3/BiOX (X = Cl, Br, I) Heterostructure. Industrial & Engineering Chemistry Research, 58, 1875-1887. [Google Scholar] [CrossRef
[28] Fu, J., Xu, Q., Low, J., Jiang, C. and Yu, J. (2019) Ultrathin 2D/2D WO3/G-C3N4 Step-Scheme H2-Production Photocatalyst. Applied Catalysis B: Environmental, 243, 556-565. [Google Scholar] [CrossRef
[29] Connor, P.A. and McQuillan, A.J. (1999) Phosphate Adsorption onto TiO2 from Aqueous Solutions:  An in Situ Internal Reflection Infrared Spectroscopic Study. Langmuir, 15, 2916-2921. [Google Scholar] [CrossRef
[30] Chen, P., Zhang, Q., Zheng, X., Tan, C., Zhuo, M., Chen, T., Wang, F., Liu, H., Liu, Y., Feng, Y., Lv, W. and Liu, G. (2019) Phosphate-Modified m-Bi2O4 Enhances the Absorption and Photocatalytic Activities of Sulfonamide: Mechanism, Reactive Species, and Reactive Sites. Journal of Hazardous Materials, 384, 121443. [Google Scholar] [CrossRef] [PubMed]
[31] Hu, X., Zhao, H., Liang, Y., Chen, F., Li, J. and Chen, R. (2020) Broad-Spectrum Response NCQDs/Bi2O2CO3 Heterojunction Nanosheets for Ciprofloxacin Photodegradation: Unraveling the Unique Roles of NCQDs upon Different Light Irradiation. Chemosphere, 264, 128434. [Google Scholar] [CrossRef] [PubMed]
[32] Chen, F., Liu, L.L., Zhang, Y.J., Wu, J.H., Huang, G.X., Yang, Q., Chen, J.J. and Yu, H.Q. (2020) Enhanced Full Solar Spectrum Photocatalysis by Nitrogen-Doped Graphene Quantum Dots Decorated BiO2−x Nanosheets: Ultrafast Charge Transfer and Molecular Oxygen Activation. Applied Catalysis B: Environmental, 277, 119218. [Google Scholar] [CrossRef
[33] Li, J., Wang, J., Zhang, G., Li, Y. and Wang, K. (2018) En-hanced Molecular Molecular Oxygen Activation of Ni2+-Doped BiO2−x Nanosheets under UV, Visible and Near-Infrared Irradiation: Mechanism and DFT Study. Applied Catalysis B: Environmental, 234, 167-177. [Google Scholar] [CrossRef
[34] Mao, Y., Wang, P., Li, L., Chen, Z., Wang, H., Li, Y. and Zhan, S. (2020) Unravelling the Synergy between Oxygen Vacancies and Oxygen Substitution in BiO2−x for Efficient Molecu-lar-Oxygen Activation. Angewandte Chemie-International Edition, 59, 3685-3690. [Google Scholar] [CrossRef] [PubMed]
[35] Li, Y., Cheng, Z., Yao, L., Yang, S. and Zhang, Y. (2019) Boosting Nir-Driven Photocatalytic Activity of BiOBr:Yb3+/Er3+/Ho3+ Nanosheets by Enhanced Green Up-conversion Emissions Via Energy Transfer from Er3+ to Ho3+ Ions. ACS Sustainable Chemistry & Engineering, 7, 18185-18196. [Google Scholar] [CrossRef
[36] Fang, H., Pan, Y., Yin, M. and Pan, C. (2020) Enhanced Photocatalytic Activity and Mechanism of Ti3C2-OH/Bi2WO6:Yb3+, Tm3+ Towards Degradation of Rhb under Visible and near Infrared Light Irradiation. Materials Research Bulletin, 121, 110618. [Google Scholar] [CrossRef
[37] Huang, H., Liang, X., Wang, Z., Wang, P., Zheng, Z., Liu, Y., Zhang, X., Qin, X., Dai, Y. and Huang, B. (2019) Bi20TiO32 Nanoparticles Doped with Yb3+ and Er3+ as UV, Visible, and Near-Infrared Responsive Photocatalysts. ACS Applied Nano Materials, 2, 5381-5388. [Google Scholar] [CrossRef
[38] Zhang, D., Liang, S., Yao, S., Li, H., Liu, J., Geng, Y. and Pu, X. (2020) Highly Efficient Visible/NIR Photocatalytic Activity and Mechanism of Yb3+/Er3+ Co-Doped Bi4O5I2 up-Conversion Photocatalyst. Separation and Purification Technology, 248, 117040. [Google Scholar] [CrossRef