聚偏氟乙烯膜制备与改性研究进展
Research Progress in Preparation and Modification of Polyvinylidene Fluoride Membrane
DOI: 10.12677/MS.2020.1012117, PDF,  被引量    科研立项经费支持
作者: 彭湘梅*, 黄 强#:深圳职业技术学院建筑与环境工程学院,广东 深圳
关键词: 聚偏氟乙烯(PVDF)PVDF膜的制备PVDF膜的改性Polyvinylidene Fluoride (PVDF) Preparation of PVDF Membrane Modification of PVDF Membrane
摘要: 聚偏氟乙烯(PVDF)膜具有出色的稳定性、可塑性、耐磨性等特点,被广泛应用于饮用水与废水处理领域中。但PVDF膜还存在抗污能力不足和渗透性较差等问题,限制了其在水处理领域中更进一步的发展。因此提高膜抗污染能力以及提高膜通量已然成为制备和改性PVDF膜的研究重点。本文对PVDF膜制备方法和改性技术进行了梳理,首先概述了PVDF材料及PVDF膜制备方法,并着重介绍了非溶剂诱导相转化法和热诱导相转化法;然后总结了近年来PVDF膜改性的研究进展;最后对PVDF膜制备及改性研究的发展前景进行了展望。针对PVDF膜通量低、易污染等问题,提供了一些科学可行的解决方法。
Abstract: Polyvinylidene fluoride (PVDF) membranes are widely used in the fields of drinking water and sewage treatment because of their excellent stability, plasticity and wear resistance. However, PVDF membranes also have problems such as easy contamination and low flux, which limits their further development in the field of water treatment. Therefore, improving membrane anti-pollution ability and increasing membrane flux have become the research focus of preparation and modification of PVDF membrane. In this paper, the preparation methods of PVDF membranes and modification techniques are sorted out. Firstly, the PVDF materials and PVDF film preparation methods are summarized, and the non-solvent induced phase inversion method and the thermally induced phase inversion method are emphasized. Then, this paper summarizes the research progress of PVDF membrane modification in recent years; finally, the development prospects of PVDF membrane preparation and modification research are prospected. In view of the low flux and easy pollution of PVDF membrane, some scientific and feasible solutions are provided.
文章引用:彭湘梅, 黄强. 聚偏氟乙烯膜制备与改性研究进展[J]. 材料科学, 2020, 10(12): 973-979. https://doi.org/10.12677/MS.2020.1012117

参考文献

[1] 赵维春, 徐晓波. 无机膜分离技术在水处理中的应用研究[J]. 中国给水排水, 2015, 31(10): 38-40.
[2] Ying, Y., Yang, Y. and Ying, W. (2016) Two-Dimensional Materials for Novel Liquid Separation Membranes. Nanotechnology, 27, Article ID: 332001. [Google Scholar] [CrossRef] [PubMed]
[3] Usmani, M.A., Khan, I. and Bhat, A. (2017) Current Trend in the Application of Nanoparticles for Waste Water Treatment and Purification: A Review. Current Organic Synthesis, 14, 206-226. [Google Scholar] [CrossRef
[4] Werber, J.R., Osuji, C.O. and Elimelech, M. (2016) Materials for Next-Generation Desalination and Water Purification Membranes. Nature Reviews Materials, 1, Article No. 16018. [Google Scholar] [CrossRef
[5] Liu, F., Hashim, N.A. and Liu, Y. (2011) Progress in the Production and Modification of PVDF Membranes. Journal of Membrane Science, 375, 1-27. [Google Scholar] [CrossRef
[6] Kang, G.D. and Cao, Y.M. (2014) Application and Modifica-tion of Poly(vinylidene fluoride) (PVDF) Membranes: A Review. Journal of Membrane Science, 463, 145-165. [Google Scholar] [CrossRef
[7] Ji, J., Liu, F. and Hashim, N.A. (2015) Poly(vinylidene fluoride) (PVDF) Membranes for Fluid Separation. Reactive & Functional Polymers, 86, 134-153. [Google Scholar] [CrossRef
[8] 虞骥. 聚偏氟乙烯膜的改性及生化应用研究[D]: [硕士学位论文]. 杭州: 浙江大学, 2003.
[9] Shirkova, V.V. and Tretyakova, S.P. (1997) Physical and Chemical Basis for the Manufacturing of Fluoropolymer Track Membranes. Radiation Measurements, 28, 791-798. [Google Scholar] [CrossRef
[10] Mulder, M. (1996) Basic Principles of Membrane Tech-nology. Springer, Berlin. [Google Scholar] [CrossRef
[11] Hashim, N.A., Liu, F. and Li, K. (2009) A Simplified Method for Preparation of Hydrophilic PVDF Membranes from an Amphiphilic Graft Copolymer. Journal of Membrane Science, 345, 134-141. [Google Scholar] [CrossRef
[12] 黄志浩. PVDF膜功能性改性研究[D]: [硕士学位论文]. 上海: 华东理工大学, 2020.
[13] Wienk, I.M., Boom, R.M., Beerlage, M.A.M., et al. (1996) Recent Advances in the Formation of Phase Inversion Membranes Made from Amorphous or Semi-Crystalline Polymers. Journal of Membrane Science, 113, 361-371. [Google Scholar] [CrossRef
[14] Munari, S., Bottino, A. and Capannelli, G. (1983) Casting and Performance of Polyvinylidene Fluoride Based Membranes. Journal of Membrane Science, 16, 181-193. [Google Scholar] [CrossRef
[15] Xing, Q., Dong, X. and Li, R. (2013) Morphology and Per-formance of PLLA Based Porous Membranes by Phase Separation Control. Polymer, 54, 30011. [Google Scholar] [CrossRef
[16] Tang, Y.L., Sun, J., Li, S.F., Ran, Z.L. and Xiang, Y.X. (2019) Effect of Ethanol in the Coagulation Bath on the Structure and Performance of PVDF-g-PEGMA/PVDF Membrane. Journal of Applied Polymer Science, 136, Article No. 47380. [Google Scholar] [CrossRef
[17] 裴志强, 张玉亮, 陈卫文. 凝固浴体系对PVDF超滤膜性能与结构的影响[J]. 水处理技术, 2014, 40(4): 27-30.
[18] 汪帅, 李方, 李勇. 采用聚合左旋多巴涂覆及MPEG-NH_2接枝对PVDF膜亲水改性的研究[J]. 膜科学与技术, 2015, 35(1): 42-48.
[19] 周军, 刘云, 张宏忠. 聚偏氟乙烯膜的Fenton氧化改性研究[J]. 化工新型材料, 2008, 36(2): 30-32.
[20] 胡峰, 陈锋涛, 俞三传. PVDF膜表面两性离子化改性及其性能[J]. 浙江理工大学学报, 2018, 43(6): 774-780.
[21] Rahimpour, A., Madaeni, S.S., Zereshki, S., et al. (2009) Preparation and Characterization of Modified Nano-Porous PVDF Membrane with High Antifouling Property Using UV Photo-Grafting. Applied Surface Science, 255, 7455-7461. [Google Scholar] [CrossRef
[22] 罗子安, 魏俊富, 赵孔银. 辐照接枝改性对PVDF中空纤维膜性能的影响[J]. 天津工业大学学报, 2012, 31(3): 6-10.
[23] Yan, L., Hong, S. and Li, M.L. (2009) Application of the Al2O3-PVDF Nanocomposite Tubular Ultrafiltration (UF) Membrane for Oily Wastewater Treatment and Its Anti-fouling Research. Separation & Purification Technology, 66, 347-352. [Google Scholar] [CrossRef
[24] 张宏忠, 张钰, 王明花. 二氧化钛光催化膜分离耦合技术在水处理中的应用[J]. 无机盐工业, 2017, 49(7): 50-54.
[25] 朱志超, 朱小燕, 雷新荣. 硅烷偶联剂改性高岭土对PVDF膜性能的影响研究[J]. 膜科学与技术, 2015, 35(6): 9-15.
[26] 杨虎, 许振良, 周立志. 聚偏氟乙烯膜表面丙烯酸接枝改性研究[J]. 膜科学与技术, 2006, 26(4): 24-26.
[27] 张娇, 邱广明, 杨春霞. 聚偏氟乙烯共混膜的制备和性能研究[J]. 内蒙古石油化工, 2011, 37(8): 346-350.
[28] Chen, Y., Chen, H. and Feng, M. (2016) Amphiphilic Gradient Copolymers: Synthesis, Self-Assembly, and Applications. European Polymer Journal, 85, 489-498. [Google Scholar] [CrossRef
[29] Zhao, Y.H., Qian, Y.L. and Zhu, B.K. (2008) Modification of Porous Poly(vinylidene fluoride) Membrane Using Amphiphilic Polymers with Different Structures in Phase Inversion Process. Journal of Membrane Science, 310, 567-576. [Google Scholar] [CrossRef
[30] Kise, H., Ogata, H. and Nakata, M. (1989) Chemical Dehydro-fluorination and Electrical Conductivity of Poly(vinylidene fluoride) Films. Macromolecular Materials & Engineering, 168, 205-216. [Google Scholar] [CrossRef
[31] Chong, M.N., Jin, B., Chow, C.W.K., et al. (2010) Recent Developments in Photocatalytic Water Treatment Technology: A Review. Water Research, 44, 2997-3027. [Google Scholar] [CrossRef] [PubMed]
[32] Loddo, V., Augugliaro, V. and Palmisano, L. (2010) Photo-catalytic Membrane Reactors: Case Studies and Perspectives. Asia-Pacific Journal of Chemical Engineering, 4, 380-384. [Google Scholar] [CrossRef
[33] Malato, S., Cáceres, J., Fernández-Alba, A.R., et al. (2003) Photocatalytic Treatment of Diuron by Solar Photocatalysis: Evaluation of Main Intermediates and Toxicity. Environmental Science & Technology, 37, 2516-2524. [Google Scholar] [CrossRef] [PubMed]
[34] Lee, K.M., Lai, C.W., Ngai, K.S., et al. (2015) Recent Developments of Zinc Oxide Based Photocatalyst in Water Treatment Technology: A Review. Water Research, 88, 428-448. [Google Scholar] [CrossRef] [PubMed]