高熵合金化研究现状
Research Status of High Entropy Alloying
DOI: 10.12677/MEng.2021.81002, PDF,  被引量    国家自然科学基金支持
作者: 杨颜如, 张祎梣, 李嘉雯, 朱和国, 张继峰:南京理工大学,江苏 南京
关键词: 高熵合金微观组织力学性能摩擦磨损High-Entropy Alloys Micro-Structure Mechanical Properties Frictional Wear
摘要: 高熵合金具有比传统合金更为优异的机械、物理、化学性能,有极为广泛的应用前景。高熵合金的结构和性能是目前材料科学领域研究的一大热点。本文综述了Al、Ti、B、V、Si、C六种合金元素对高熵合金物相结构、组织形貌、性能的影响。指出了高熵合金目前研究中存在的不足,并提出了对策。
Abstract: High-entropy alloys have more excellent mechanical, physical and chemical properties than traditional alloys and have a wide range of applications. The structure and properties of high-entropy alloys are a hot topic in the field of material science. The effects of Al, Ti, B, V, Si and C on phase structure, micro-structure morphology and properties of high entropy alloys were reviewed. At last, the deficiencies existing in the current research of high entropy alloys were summarized and the countermeasures are put forward.
文章引用:杨颜如, 张祎梣, 李嘉雯, 朱和国, 张继峰. 高熵合金化研究现状[J]. 冶金工程, 2021, 8(1): 9-18. https://doi.org/10.12677/MEng.2021.81002

参考文献

[1] Yeh, J.W. (2013) Alloy Design Strategies and Future Trends in High-Entropy Alloys. JOM, 65, 1759-1771. [Google Scholar] [CrossRef
[2] Li, Z.M., Pradeep, K.G., Deng, Y., Raabe, D. and Tasan, C.C. (2016) Metastable High Entropy Dual-Phase Alloys Overcome the Strength-Ductility Trade-Off. Nature, 534, 227-230. [Google Scholar] [CrossRef] [PubMed]
[3] Sing, H.P., Smirnov, A.V. and Johnson, D.D. (2015) Atomic Short-Range Order and Incipient Long-Range Order in High-Entropy Alloys. Physical Review B, 91, Article ID: 224204. [Google Scholar] [CrossRef
[4] Gludovatz, B., Hohenwarter, A., Catoor, D., Chang, E.H., George, E.P. and Ritchie, R.O. (2014) A Fracture-Resistant High-Entropy Alloy for Cryogenic Applications. Science, 345, 1153-1158. [Google Scholar] [CrossRef] [PubMed]
[5] 刘亮. 合金元素对高熵合金组织与性能的影响[D]: [博士学位论文]. 长春: 吉林大学, 2012.
[6] Murty, B.S., Yeh, J.W. and Ranganathan, S. (2014) High Entropy Alloys. Butterworth-Heinemann, Oxford, 119-131. [Google Scholar] [CrossRef
[7] Zhang, Y., Lu, Z.P., Ma, S.G., Liaw, P.K., Tang, Z. and Cheng, Y.Q. (2014) Guidelines in Predicting Phase Formation of High-Entropy Alloys. MRS Communications, 4, 57-62. [Google Scholar] [CrossRef
[8] 范文进, 郑琼林, 杨中平, 林飞, 宋文胜, Do Viet, D. 基于对称多边形平滑磁链轨迹的直接转矩控制算法[J]. 电机与控制学报, 2016, 20(7): 32-39.
http://dx.chinadoi.cn/10.15938/j.emc.2016.07.005
[9] 陈萍, 唐任远, 韩雪岩. 抑制永磁体局部温升最高点的不性能分析[J]. 电机与控制学报, 2015, 19(12): 53-59.
[10] 范啟超. AlFeCrNiCoCu系高熵合金及其复合材料组织及性能研究[D]: [硕士学位论文]. 哈尔滨: 哈尔滨工业大学, 2011: 6.
[11] 林丽蓉. 高熔化温度五元高熵合金组织及性能研究[D]: [硕士学位论文]. 哈尔滨: 哈尔滨工业大学, 2007: 7.
[12] Shunt, T., Changl, Y. and Shium, H. (2012) Microstructures and Mechanical Properties of Multi-Principal Component CoCrFeNiTix Alloys. Materials Sci-ence & Engineering: A, 556, 170-174. [Google Scholar] [CrossRef
[13] Praveen, S., Murty, B.S. and Kottadar, S.R. (2012) Alloying Behavior in Multi-Component AlCoCrCuFe and NiCoCrCuFe High-Entropy Alloys. Materials Science and Engineering: A, 534, 83-89. [Google Scholar] [CrossRef
[14] Hsu, C.Y., Juan, C.C., Wang, W.R., Sheu, T.-S., Yeh, J.-W. and Chen, S.-K. (2011) On the Superior Hot Hardness and Softening Resistance of AlCoCrxFeMo0.5Ni High-Entropy Al-loys. Materials Science and Engineering: A, 528, 3581-3588. [Google Scholar] [CrossRef
[15] Lin, C.M. and Tsai, H.L. (2011) Evolution of Microstructure, Hardness, and Corrosion Properties of High-Entropy Al0.5CoCrFeNi alloy. Intermetallics, 19, 288-294. [Google Scholar] [CrossRef
[16] Qiu, X.W., Zhang, Y.P., He, L. and Liu, C.-G. (2013) Micro-structure and Corrosion Resistance of AlCrFeCuCo High-Entropy Alloy. Journal of Alloys and Compounds, 549, 195-199. [Google Scholar] [CrossRef
[17] Senkov, O.N., Wilks, G.B., Miracle, D.B., Chuang, C.P. and Liaw, P.K. (2010) Refractory High-Entropy Alloys. Intermetallics, 18, 1758-1765. [Google Scholar] [CrossRef
[18] Huang, Y.S., Che, N.L., Lui, H.W., Cai, M.-H. and Yeh, J.-W. (2007) Microstructure, Hardness, Resistivity and Thermal Stability of Sputtered Oxide Films of AlCoCrCu0.5NiFe High-Entropy Alloy. Materials Science and Engineering: A, 457, 77-83. [Google Scholar] [CrossRef
[19] 曲明洋, 李廷取, 颜丙辉, 索忠源. AlxCoFeNiMo高熵合金的结构演变及力学性能[J]. 试验研究, 2020, 69(1): 11-15.
[20] 张正, 于忠卡, 程皓, 李维火. Al含量对Al,FeCoNiCu高熵合金结构和纳米压痕蠕变行为的影响[J]. 金属热处理, 2019, 48(12): 62-65.
http://dx.chinadoi.cn/10.14158/j.cnki.1001-3814.2019.12.015
[21] 郭富强. AlxCrCuNiTi高熵合金的微观组织与硬度[J]. 特色铸造及有色合金, 2019, 39(12), 1277-1281.
http://dx.chinadoi.cn/10.15980/j.tzzz.2019.12.001
[22] 侯丽丽, 要玉宏, 梁霄羽, 陈建, 刘江南. AlxFeCo-NiB0.1高熵合金的微观组织和力学性能[J]. 稀有金属材料与工程, 2019, 48(1): 113-115.
[23] 徐义库, 刘建儒, 宋绪丁, 陈永楠, 黄兆皓, 郝建民, 等. CoCrFeNiTiAlx高熵合金的组织演变及其力学性能研究[J]. 热加工工艺. 2018, 24(47): 21-30.
http://dx.chinadoi.cn/10.14158/j.cnki.1001-3814.2018.24.005
[24] Juan, C.C., Hsu, C.Y., Tsai, C.-W., Wang, W.-R., Sheu, T.-S., Yeh, J.W., et al. (2013) On Microstructure and Mechanical Performance of Al-CoCrFeMo0.5Nix High-Entropy Alloys. Intermetallics, 32, 401-407. [Google Scholar] [CrossRef
[25] Hsu, C.Y., Juan, C.C., Chen, S.-T., Sheu, T.-S., Yeh, J.W. and Chen, S.-K. (2013) Phase Diagrams of High-Entropy Alloy System Al-Co-Cr-Fe-Mo-Ni. JOM, 65, 1829-1839. [Google Scholar] [CrossRef
[26] Tsai, M.H., Yuan, H., Cheng, G.M., Xu, W.Z., Tsai, K.-Y., Yeh, J.W., et al. (2013) Morphology, Structure and CoMposition of Precipitates in Al0.3CoCrCu0.5FeNi High-Entropy Alloy. Intermetallics, 32, 329-336. [Google Scholar] [CrossRef
[27] 董鑫涛, 刘贵仲, 班煜峰, 喻学谦, 郭景杰. Ti元素对Al1.2FeCrCoNiTix高熵合金微观组织及硬度的影响[J]. 热加工工艺, 2018, 47(4): 75-79.
http://dx.chinadoi.cn/10.14158/j.cnki.1001-3814.2018.04.018
[28] 马明星, 王志新, 周家臣, 梁存, 朱达川, 张德良. Ti掺杂对CoCrCuFeMn高熵合金组织结构和耐磨性的影响[J].机械工程学报, 2020, 56(10): 110-116.
http://dx.chinadoi.cn/10.3901/JME.2020.10.110
[29] 黄蕾, 王雪洁, 王长征, 杨院生. Ti对AlCoCrFeNiTix高熵合金微观组织和摩擦性能的影响[J]. 特种铸造及有色合金, 2020, 40(5): 562-566.
http://dx.chinadoi.cn/10.15980/j.tzzz.2020.05.023
[30] 张太超, 李俊魁, 徐向俊, 韩柯, 彭竹琴. V、Ti、Si、Zr对CoCrFeMnNi高熵合金组织与性能的影响[J]. 金属热处理, 2018, 43(6): 28-33.
http://dx.chinadoi.cn/10.13251/j.issn.0254-6051.2018.06.007
[31] Zhu, J.M., Zhang, H.F., Fu, H.M., Wang, A.M., Li, H. and Hu, Z.Q. (2010) Microstructures and Compressive Properties of Multicomponent AlCoCrCuFeNiMox Alloys. Journal of Alloys and Compounds, 497, 52-56. [Google Scholar] [CrossRef
[32] Yu, Y., Shi, P.Y., Feng, K., Liu, J.J., Cheng, J., Qiao, Z.H., Yang, J., Li, J.S. and Liu, W.M. (2020) Effects of Ti and Cu on the Microstructure Evolution of AlCoCrFeNi High-Entropy Alloy during Heat Treatment. Acta Metallurgica Sinica (English Letters), 33, 1077-1090. [Google Scholar] [CrossRef
[33] 姜越, 程思梦, 祖红梅. Ti元素对CrTeCoNiTix高熵合金组织及性能的影响[J]. 哈尔滨理工大学学报, 2018, 23(3): 149-152.
http://dx.chinadoi.cn/10.15938/j.jhust.2018.03.026
[34] 叶海梅, 杨文超, 庞兴志, 杨剑冰, 湛永钟. Ti元素对CoCuFeNiVTix高熵合金耐磨性能的影响[J]. 广西大学学报(自然科学版), 2017, 42(3): 1187-1191.
http://dx.chinadoi.cn/10.13624/j.cnki.issn.1001-7445.2017.1187
[35] 崔忠坼, 覃耀春. 金属学与热处理[M]. 北京: 机械工业出版社, 2010: 161-175.
[36] 李涵, 马玲玲, 位超群, 孙琳, 张维平. 钛合金表面激光熔覆AlBxCoCrNiTi高熵合金涂层的组织与性能[J]. 表面技术, 2017, 46(6): 226-231.
http://dx.chinadoi.cn/10.16490/j.cnki.issn.1001-3660.2017.06.036
[37] Wang, F., Inoue, A., Kong, F.L., Zhao, C.C., Zhang, J.Y., Zhu, S.L., Botta, W.J., Kiminami, C.S., Ivanov, Yu. P. and Greer, A.L. (2020) Formation, Thermal Stability and Mechanical Properties of High-Entropy (Fe0.25Co0.25Ni0.25Cr0.125Mo0.0625 Nb0.0625)(100-x)Bx (x=7-14)Amorphous Alloys. Journal of Alloys and Compounds, 825, Article ID: 153858. [Google Scholar] [CrossRef
[38] Cahn, J.W. (1962) The Impurity-Drag Effect in Grain Bound-ary Motion. Acta Metallurgica, 10, 789-798. [Google Scholar] [CrossRef
[39] 要玉宏, 梁霄羽, 金耀华, 王正品, 南條弘. 硼对AlMo0.5NbTa0.5TiZr难熔高熵合金组织和高温氧化性能的影响[J]. 表面技术, 2020, 49(2): 235-242+287.
http://dx.chinadoi.cn/10.16490/j.cnki.issn.1001-3660.2020.02.029
[40] 刘晓涛, 雷文斌, 马立娟, 刘金玲. 刘静. 崔建忠. B对Al0.5CoCrCuFeNi高熵合金组织、相组成及耐磨性能的影响[J]. 稀有金属材料与工程, 2016, 45(9): 2201-2207
[41] 张立君, 史秀梅, 马兰, 王若兰. 激光熔覆FeCrNiCoMnBx熵合金涂层的组织结构与性能研究[J]. 世界有色金属, 2020(10): 249-250
[42] 钱天宝, 崔红保, 郭雪峰. Mo和V对FeCoNiCrAl0.3高熵合金组织的影响[J]. 热加工工艺, 2017, 46(8): 54-60.
http://dx.chinadoi.cn/10.14158/j.cnki.1001-3814.2017.08.014
[43] 刘慧琳, 张琰斌, 吴钇冲, 周涛. Nb-V-Ti含量对FeCoNiCrMn系高熵合金析出规律热力学模拟[J]. 广州化工, 2020, 48(20): 10-12+22.
[44] 李安敏, 徐飞, 郭宝航, 等. AlNiFeCuCoCrVx高熵合金的显微组织与力学性能[J]. 机械工程材料, 2019, 43(4): 48-52.
http://dx.chinadoi.cn/10.11973/jxgccl201904011
[45] 谢红波, 刘贵仲, 郭景杰. Mn、V、Mo、Ti、Zr元素对AlFeCrCoCu-X高熵合金组织与高温氧化性能的影响[J].中国有色金属学报, 2015, 25(1): 103-110.
[46] 刘亮, 齐锦刚, 王冰. 赵作福, 商剑, 张越. CoCrFeNiVx高熵合金的组织与力学性能[J]. 特种铸造机有色合金, 2015, 35(11): 1130-1133.
http://dx.chinadoi.cn/10.15980/j.tzzz.2015.11.003
[47] 薛彦均, 尉文超, 王毛球, 时捷. Si对FeMoCrVTiSix高熵合金组织和力学性能的影响[J]. 特种铸造及有色合金, 2020, 40(1): 112-116.
http://dx.chinadoi.cn/10.15980/j.tzzz.2020.01.027
[48] 吴炳乾, 饶湖常, 张冲, 戴品强. Si含量对FeCoCr0.5NiBSix高熵合金涂层组织结构和耐磨性的影响[J]. 表面技术, 2015, 44(12): 85-91.
http://dx.chinadoi.cn/10.16490/j.cnki.issn.1001-3660.2015.12.014
[49] 白莉, 王宇哲, 吕煜坤, 颜屹, 付梅文. 碳对无Co高熵合金Fe40Mn30Ni10Cr10Al10组织以及力学性能的影响[J].材料导报, 2020, 34(17): 17072-17076.
http://dx.chinadoi.cn/10.11896/cldb.20050196
[50] 黄英杰. 原位生成C和TiC对AlFeCoNiCxTiy耐磨性的影响[D]: [硕士学位论文]. 西安: 西安工业大学, 2019
[51] 邵华, 上官晓峰, 王晓博, 吕煜坤, 陈建. AlFeCoNiCx高熵合金微观组织及性能[J]. 西安工业大学学报, 2017, 37(4): 309-314.
http://dx.chinadoi.cn/10.16185/j.jxatu.edu.cn.2017.04.008
[52] 饶湖常, 戴品强, 陈鼎宁, 王乾廷. 碳含量对FeCoCrNiMnCx高熵合金显微组织与性能的影响[J]. 机械工程材料, 2016, 40(8): 76-80.
http://dx.chinadoi.cn/10.11973/jxgccl201608018
[53] 李田野. Mo和C对CoCrFeMnNi系高熵合金组织及性能的影响[D]: [硕士学位论文]. 西安: 西安工业大学, 2019.
[54] 夏凡, 程虎, 唐前辉, 金源, 钱超群. FeCoCrNiMnCx高熵合金的组织和力学性能[J]. 热加工工艺, 2018, 47(8): 44-48.
http://dx.chinadoi.cn/10.14158/j.cnki.1001-3814.2018.08.011