高熵合金的3D打印国内外研究发展
Research Development on Three D Printing Technology of High Entropy Alloys
DOI: 10.12677/MET.2021.103041, PDF,   
作者: 谭旺有, 陈刚辉, 张可可:中车广东轨道交通车辆有限公司,广东 江门;向鹏宇:西南交通大学,材料科学与工程学院,四川 成都
关键词: 3D打印增材制造高熵合金选择性激光熔融技术3D Printing Additive Manufacturing High Entropy Alloy SL
摘要: 3D打印技术即增材制造技术,作为工业4.0时代最具发展前景的制造技术之一,是一种基于离散堆积成形思想的新型成形技术。目前,可用于直接制造金属功能零件的快速成型方法主要有电子束熔融(EBM)技术、电子束焊接(EBW)技术、选择性激光熔融(SLM)技术、数字光处理(DLP)技术、激光净型制造(LENS)技术和熔滴打印技术。高熵合金是近年来提出的一种全新的合金体系,与传统合金的一种或两种主元相比,高熵合金拥有四种或四种以上的主元,且每种主元含量都在5%~35% (原子含量)。高熵合金具有不同于传统合金的四大效应:高熵效应、扩散迟缓效应、晶格畸变效应以及“鸡尾酒”效应。这些效应赋予了高熵合金高强度、高硬度、耐磨耐蚀、高温抗软化及抗氧化等优异性能,使其被公认为21世纪最具发展潜力的材料之一。目前对多主元合金的加工工艺多以传统的真空电弧熔炼技术为主,但是该制备技术存在成形形状简单、成形尺寸有限、容易发生成分偏析、缩孔缺陷等不足,从而限制了其在多主元合金复杂成形构件的制备方面的应用。因此,尝试采用增材制造技术制备性能优异的多主元合金具有较大的科研意义。
Abstract: As one of the most promising manufacturing technologies in industry 4.0 era, 3D printing tech-nology is a new forming technology based on the idea of discrete stacking forming. At present, the main rapid prototyping methods for directly manufacturing metal functional parts are electron beam melting (EBM), electron beam welding (EBW), selective laser melting (SLM), digital light processing (DLP), laser net manufacturing (lens) and droplet printing. High entropy alloy is a new alloy system proposed in recent years. Compared with one or two principal components of tradi-tional alloy, high entropy alloy has four or more principal components, and the content of each principal component is 5%~35% (atomic content). High entropy alloys have four effects different from traditional alloys: high entropy effect, diffusion retardation effect, lattice distortion effect and cocktail effect. These effects endow high entropy alloy with excellent properties, such as high strength, high hardness, wear and corrosion resistance, high temperature softening resistance and oxidation resistance, which makes it recognized as one of the most potential materials in the 21st century. At present, the traditional vacuum arc melting technology is the main processing technology of multi principal component alloy. However, the disadvantages of this technology, such as simple forming shape, limited forming size, prone to component segregation and shrinkage defects, limit its application in the preparation of complex forming components of multi principal component alloy. Therefore, it is of great scientific significance to try to use additive manufacturing technology to prepare multi-component alloys with excellent properties.
文章引用:谭旺有, 向鹏宇, 陈刚辉, 张可可. 高熵合金的3D打印国内外研究发展[J]. 机械工程与技术, 2021, 10(3): 364-376. https://doi.org/10.12677/MET.2021.103041

参考文献

[1] 黎志勇, 杨斌, 王鹏程, 李俏, 莫玉梅. 金属3D打印技术研究现状及其趋势[J]. 新技术新工艺, 2017(4): 25-28.
[2] 马旻昱, 连勇, 张津. 增材制造技术制备高熵合金的研究现状及展望[J]. 材料导报, 2020, 34(17): 17082-17088.
[3] Ye, Y.,Wang, Q., Lu, J., et al. (2016) High-Entropy Alloy: Challenges and Prospects. Materials Today, 19, 349-362. [Google Scholar] [CrossRef
[4] Yeh, J.-W., Chen, S.-K., Lin, S.-J., et al. (2004) Nanostructured High-Entropy Alloys with Multiple Principal Elements: Novel Alloy Design Concepts and Outcomes. Advanced Engineering Materials, 6, 299-303. [Google Scholar] [CrossRef
[5] Ren, M., Li, B. and Fu, H. (2013) Formation Condition of Solid Solution Type High-Entropy Alloy. Transactions of Nonferrous Metals Society of China, 23, 991-995. [Google Scholar] [CrossRef
[6] Zhang, Y. and Zhou, Y.J. (2007) Solid Solution Formation Criteria for High Entropy Alloys. Materials Science Forum, 561-565, 1337-1339. [Google Scholar] [CrossRef
[7] Lei, Z., Liu, X., Wu, Y., et al. (2018) En-hanced Strength and Ductility in a High-Entropy Alloy via Ordered Oxygen Complexes. Nature, 563, 546-550. [Google Scholar] [CrossRef] [PubMed]
[8] 姜华, 汤海波, 方艳丽, 王华明. 激光熔化沉积DZ408镍基高温合金微细柱晶显微组织及性能[J]. 中国激光, 2012, 39(2): 78-84.
[9] 颜永年, 张人佶. 21世纪的重要先进制造技术——快速原型技术[C]//中国机床工具工业协会. 第七届中国国际机床展览会(CIMT 2001)论文集. 北京: 中国机床工具工业协会, 2001: 5.
[10] 曾亮华, 刘继常. 金属3D打印技术的发展分析[J]. 机械工程师, 2016(3): 42-44.
[11] Lewandowski, J.J. and Seifi, M. (2016) Metal Additive Manufacturing: A Review of Mechanical Properties. Annual Review of Materials Research, 46, 151-186. [Google Scholar] [CrossRef
[12] Gu, D.D., Meiners, W., Wissenbach, K. and Poprawe, R. (2012) Laser Additive Manufacturing of Metallic Components: Materials, Processes and Mechanisms. International Materials Reviews, 57, 133-164. [Google Scholar] [CrossRef
[13] Frazier, W.E. (2014) Metal Additive Manufacturing: A Review. Journal of Materials Engineering and Performance, 23, 1917-1928. [Google Scholar] [CrossRef
[14] 吕昭平, 雷智锋, 黄海龙, 刘少飞, 张凡, 段大波, 曹培培, 吴渊, 刘雄军, 王辉. 高熵合金的变形行为及强韧化[J]. 金属学报, 2018, 54(11): 1553-1566.
[15] Zhang, Y., Zuo, T.T., Tang, Z., Gao, M.C., Dahmen, K.A., Liaw, P.K. and Lu, Z.P. (2014) Microstructures and Properties of High-Entropy Alloys. Progress in Materials Science, 61, 1-93. [Google Scholar] [CrossRef
[16] Yang, T., Zhao, Y.L., Tong, Y., Jiao, Z.B., Wei, J., Cai, J.X., Han, X.D., Chen, D., Hu, A., Kai, J.J., Lu, K., Liu, Y. and Liu, C.T. (2018) Multicomponent Intermetallic Nanoparticles and Superb Mechanical Behaviors of Complex Alloys. Science, 362, 933-937. [Google Scholar] [CrossRef] [PubMed]
[17] Miracle, D.B. and Senkov, O.N. (2017) A Critical Review of High Entropy Alloys and Related Concepts. Acta Materialia, 122, 448-511. [Google Scholar] [CrossRef
[18] 高惠临. 管线钢屈强比分析与评述[J]. 焊管, 2010, 33(6): 10-14.
[19] Wen, Y., Zhang, B., Narayan, R.L., Wang, P., Song, X., Zhao, H., Ramamurty, U. and Qu, X. (2021) Laser Powder Bed Fusion of Compositionally Graded CoCrMo-Inconel 718. Additive Manufacturing, 40, 101926. [Google Scholar] [CrossRef
[20] Cantor, B., Chang, I.T.H., Knight, P. and Vincent, A.J.B. (2004) Microstructural Development in Equiatomic Multicomponent Alloys. Materials Science & Engineering A, 375-377, 213-218. [Google Scholar] [CrossRef
[21] 王晓鹏, 孔凡涛. 高熵合金及其他高熵材料研究新进展[J]. 航空材料学报, 2019, 39(6): 1-19.
[22] 邱增城. 激光增材制造CrMnFeCoNi高熵合金组织与力学性能研究[D]: [硕士学位论文]. 上海: 上海交通大学, 2018.
[23] 刘广. 激光3D打印制备模具材料CrMoTi中熵合金[D]: [硕士学位论文]. 哈尔滨: 哈尔滨工业大学, 2020.
[24] 王福超. 激光选区熔化CoCrFeNiMn高熵合金成形工艺优化及性能表征[D]: [硕士学位论文]. 武汉: 华中科技大学, 2019.
[25] 张咪娜. 增材制造CoCrMoNbTi与AlCoCuFeNi高熵合金及其组织性能研究[D]: [博士学位论文]. 北京: 北京科技大学, 2019.
[26] 刘启明. AlCoCrFeNiCu_x系高熵合金激光增材制造组织与性能研究[D]: [硕士学位论文]. 大连: 大连理工大学, 2019.
[27] 石杰. 3D打印高熵合金–铁基非晶合金复合材料[D]: [硕士学位论文]. 武汉: 华中科技大学, 2019.
[28] 徐震霖, 何宜柱, 毛铱, 王林, 王良龙. 3D打印CoCrFeMnNi高熵合金的组织及耐蚀性研究[C]//中国体视学学会. 第十六届中国体视学与图像分析学术会议论文集——交叉、融合、创新. 北京: 中国体视学学会, 2019: 3.
[29] 刘广, 周溯源, 杨海威, 陈鹏, 欧阳潇, 严明. 3D打印CoCrFeMnNi高熵合金的微观组织、室温及低温力学性能[J]. 材料导报, 2020, 34(11): 11076-11080.
[30] 周鑫. 激光选区熔化微尺度熔池特性与凝固微观组织[D]: [博士学位论文]. 北京: 清华大学, 2016.