多孔GaN/MoO3异质结窄带响应紫外光电探测器
Narrow-Band UV Photodetector Based on Porous GaN/MoO3 Heterojunction
DOI: 10.12677/MS.2021.116091, PDF,    科研立项经费支持
作者: 郭越, 宋伟东*:五邑大学应用物理与材料学院,广东 江门
关键词: 紫外光电探测器多孔GaN异质结窄带响应UV Photodetector Porous GaN Heterojunction Narrow-Band Response
摘要: 紫外光电探测器在空间天文望远镜、军事导弹预警、非视距保密光通信、野外火灾遥感和生化检测等方面具有非常广泛的应用前景。本文介绍了一种基于GaN纳米孔阵列/MoO3异质结紫外光电探测器。通过简单的光电化学刻蚀方法,将平面u-GaN刻蚀成均匀的纳米孔,以减少表面缺陷,增强光吸收。在多孔GaN材料上沉积MoO3薄膜,制成多孔GaN/MoO3异质结。实验结果表明,该紫外光探测器在−3 V偏压下的光开/关比超过103;与纯多孔GaN器件相比,异质结器件的响应度和外量子效率均提高了两个数量级。此外,该异质结器件具有窄带响应,半峰宽度仅10 nm。这种具有高开关比、高量子效率和窄带响应特性的光电探测器有望实现在荧光检测、成像和紫外光通信方面的应用。
Abstract: UV photodetectors have very broad application prospects in space astronomy, military missile early warning, non-line-of-sight confidential optical communication, remote sensing and biochemical detection etc. In this paper, a porous GaN/MoO3 heterojunction UV photodetector is introduced. By a simple photoelectrochemical etching method, planar u-GaN was etched into uniform nanopores to reduce surface defects and enhance light absorption. The porous GaN/MoO3 heterojunction was then constructed by depositing a thin MoO3 film. Results show that the UV photodetector has a high light-to-dark of more than 103 at −3 V bias; while the responsivity and external quantum efficiency of the heterojunction device are improved by two orders of magnitude compared to the pure porous GaN device. In addition, the heterojunction device exhibits a narrow-band response with a FWHM of only 10 nm. This porous GaN/MoO3 photodetector featuring high on/off ratio, high quantum efficiency and narrow-band response characteristics may find applications in fluorescence detection, imaging and ultraviolet optical communication.
文章引用:郭越, 宋伟东. 多孔GaN/MoO3异质结窄带响应紫外光电探测器[J]. 材料科学, 2021, 11(6): 795-799. https://doi.org/10.12677/MS.2021.116091

参考文献

[1] Abe, T., Suzuki, Y., Nakagawa, A., Chiba, T., Nakagawa, M., Kashiwaba, Y., Niikura, I., Kashiwaba, Y. and Osada, H. (2019) Application of a ZnO UV Sensor for a Scintillation-Type Radiation Detector. Journal of Materials Science: Materials in Electronics, 30, 16873-16877. [Google Scholar] [CrossRef
[2] Wang, S., Zhang, D. and Ju, Z. (2020) School of Science. Application of Gallium Oxide-Based UV Detector in Complex Topography and Geological Exploration. Arabian Journal of Geosciences, 13. [Google Scholar] [CrossRef
[3] Yang, H. (2020) An Introduction to Ultraviolet Detectors Based on III Group-Nitride Semiconductor. Journal of Physics: Conference Series, 1676, 012072. [Google Scholar] [CrossRef
[4] Zou, Y., Zhang, Y., Hu, Y. and Gu, H. (2018) Ultraviolet Detectors Based on Wide Bandgap Semiconductor Nanowire: A Review. Sensors, 18. [Google Scholar] [CrossRef] [PubMed]
[5] Dong, A. and Wang, H. (2019) Lateral Photovoltaic Effect and Photo-Induced Resistance Effect in Nanoscale Metal-Semiconductor Systems. Annalen der Physik, 531, 1800440. [Google Scholar] [CrossRef
[6] Hu, X., Li, X., Li, G., Ji, T., Ai, F., Wu, J., Ha, E. and Hu, J.Q. (2021) Recent Progress of Methods to Enhance Photovoltaic Effect for Self-Powered Heterojunction Photodetectors and Their Applications in Inorganic Low-Dimensional Structures. Advanced Functional Materials, 31, 2011284. [Google Scholar] [CrossRef
[7] Goswami, L., Aggarwal, N., Vashishtha, P., Jain, S.K., Nirantar, S., Ahmed, J., Khan, M.A.M., Pandey, R. and Gupta, G. (2021) Lateral Photovoltaic Effect and Photo-Induced Resistance Effect in Nanoscale Metal-Semiconductor Systems. Scientific Reports, 11, 10859.
[8] Zhang, Y. and Song, W. (2021) High Performance Self-Powered CuZnS/GaN UV Photodetectors with Ultrahigh on/off Ratio (3 × 108). Journal of Materials Chemistry C, 9, 4799-4807. [Google Scholar] [CrossRef
[9] Kangawa, Y., Kusaba, A., Kempisty, P., Shiraishi, K., Nitta, S. and Amano, H. (2021) Fabrication of GaN Nano- Towers Based Self-Powered UV Photodetector. Crystal Growth & Design, 21, 1878-1890. [Google Scholar] [CrossRef
[10] Upadhyaya, K., Ayachit, N. and Shivaprasad, S.M. (2020) Com-parison of Optoelectronic Properties of Epitaxial and Non-Epitaxial GaN Nanostructures. Journal of Materials Science: Materials in Electronics, 31, 13756-13764. [Google Scholar] [CrossRef
[11] Wang, W., Yang, W., Wang, H., Zhu, Y., Yang, M., Gao, J. and Li, G. (2016) A Comparative Study on the Properties of c-Plane and a-Plane GaN Epitaxial Films Grown on Sapphire Substrates by Pulsed Laser Deposition. Vacuum, 128, 158-165. [Google Scholar] [CrossRef
[12] Gao, Q., Liu, R., Xiao, H., Cao, D., Liu, J. and Ma, J. (2016) Anodic Etching of GaN Based Film with a Strong Phase- Separated InGaN/GaN Layer: Mechanism and Properties. Applied Surface Science, 387, 406-411. [Google Scholar] [CrossRef
[13] Pandey, A., Yadav, B.S., Rao, D.V.S., Kaur, D. and Kapoor, A.K. (2016) Dislocation Density Investigation on MOCVD-Grown GaN Epitaxial Layers Using Wet and Dry Defect Selective Etching. Applied Physics A, 122. [Google Scholar] [CrossRef
[14] Wen, L., Wang, L., Chai, R., Li, W. and Yang, S. (2021) Wet Etching of Semi-Polar (11-22) GaN on m-Sapphire by Different Methods. Journal of Crystal Growth, 570, 126200. [Google Scholar] [CrossRef
[15] Calahorra, Y., Spiridon, B., Wineman, A., Busolo, T., Griffin, P., Szewczyk, P.K., Zhu, T., Jing, Q., Oliver, R. and Kar-Narayan, S. (2020) Enhanced Piezoelectricity and Electromechanical Efficiency in Semiconducting GaN Due to Nanoscale Porosity. Applied Materials Today, 21, 100858. [Google Scholar] [CrossRef
[16] Li, J., Xi, X., Li, X., Lin, S., Ma, Z., Xiu, H. and Zhao, L. (2020) Ultra-High and Fast Ultraviolet Response Photodetectors Based on Lateral Porous GaN/Ag Nanowires Composite Nanostructure. Advanced Optical Materials, 8, 1902162. [Google Scholar] [CrossRef
[17] Monaico, E., Tiginyanu, I. and Ursaki, V. (2020) Porous Semi-conductor Compounds. Semiconductor Science and Technology, 35, 103001. [Google Scholar] [CrossRef
[18] Fuentes-Hernandez, C., Chou, W.F., Khan, T.M., Diniz, L., Lukens, J., Larrain, F.A., Rodriguez-Toro, V.A. and Kippelen, B. (2020) Large-Area Low-Noise Flexible Organic Photodiodes for Detecting Faint Visible Light. Science, 370, 698-701. [Google Scholar] [CrossRef] [PubMed]
[19] Qiu, M., Sun, P., Liu, Y., Huang, Q., Zhao, C., Li, Z. and Mai, W. (2018) Visualized UV Photodetectors Based on Prussian Blue/TiO2 for Smart Irradiation Monitoring Application. Advanced Materials Technologies, 3, 1700288. [Google Scholar] [CrossRef
[20] Zheng, Y., Li, Y., Tang, X., Wang, W. and Li, G. (2020) A Self-Powered High-Performance UV Photodetector Based on Core-Shell GaN/MoO3–x Nanorod Array Heterojunction. Advanced Optical Materials, 8, 2000197.