LSCO/NBT/LSCO异质结铁电储能性能
Ferroelectric Energy Storage Properties of LSCO/NBT/LSCO Heterostructure
摘要: 采用磁控溅射法和脉冲激光沉积法,以钛酸锶(001)SrTiO3(STO)单晶基片为衬底,制备了La0.5Sr0.5CoO3/ Na0.5Bi0.5TiO3/La0.5Sr0.5CoO3(LSCO/NBT/LSCO)铁电电介质电容器,X射线衍射证实了[001]NBT// [001]LSCO//[001]STO外延关系。外延NBT薄膜电容器的有效储能密度Wrec随外加电场的增加呈线性增大规律,在1250 kV/cm时,Wrec达到了25.7 J/cm3,转化效率η为64.7%。此外,在室温到120℃的温度范围内,Wrecη都具有较好的热稳定性。大的Wrec和热稳定性归因于外延NBT薄膜中较少的缺陷和晶界。
Abstract: La0.5Sr0.5CoO3/ Na0.5Bi0.5TiO3/La0.5Sr0.5CoO3(LSCO/NBT/LSCO) ferroelectric capacitors were fabricated on strontium titanate (001)SrTiO3(STO) single crystal substrates by magnetron sputtering and pulsed laser deposition. The epitaxial relationship of [001]NBT//[001]LSCO/[001] STO was confirmed by X-ray diffraction. The effective energy storage density wrec of epitaxial NBT film capacitor increases linearly with the increase of applied electric field. At 1250 kV/cm, wrec reaches 25.7 J/cm3, and the conversion efficiency is high η 64.7%. In addition, in the temperature range from room temperature to 120˚C, Wrec and η all have good thermal stability. The larger Wrec and thermal stability are attributed to fewer defects and grain boundaries in the epitaxial NBT films.
文章引用:李紫硕, 翟亚欣, 范佳荫, 王晓丹, 丁逸, 贾明浩, 董磊, 宋建民. LSCO/NBT/LSCO异质结铁电储能性能[J]. 纳米技术, 2021, 11(3): 54-58. https://doi.org/10.12677/NAT.2021.113007

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