析氢电催化剂的研究进展
Research Progress of Electrocatalyst for Hydrogen Evolution Reaction
DOI: 10.12677/NAT.2021.113019, PDF,  被引量    国家自然科学基金支持
作者: 程 煜, 徐新楠, 张莉芳, 刘 杰, 钱 涛：南通大学化学化工学院，江苏 南通；周 希：南通大学化学化工学院，江苏 南通；江苏省生物质能源与材料重点实验室，江苏 南京
关键词: 电催化；析氢反应；催化剂；氢能源；过渡金属； Electrocatalysis； Hydrogen Evolution Reaction； Catalyst； Hydrogen Energy； Transition Metal
摘要: 随着社会生活和科技的发展，人类赖以生存的化石燃料被过渡消耗，由此引发的能源危机及环境污染迫在眉睫，全球能源供应与相关的环境问题成为科学技术人员面临的最大挑战之一。针对以上问题，以太阳能、风能、生物质能、海洋能、地热能和核聚变能等为主的绿色能源备受关注。氢能由于具有高效、清洁、储量丰富、燃烧热值高(142 MJ/kg)，连续性好等优势被认为是一种替代化石能源极具潜力的次世代燃料。利用电解水制氢是生产氢能的高效途径，但电解水制氢的顺利进行需要高效电催化剂的辅助。传统的贵金属电催化剂尽管具有高的催化活性，但由于其储量匮乏、成本高昂、长时间稳定性差等缺点，严重制约了其规模化应用。因此，急需开发高效、廉价、稳定且可宏量化制备的电催化剂，以实现“氢经济”蓝图。本文综述了近几年电催化产氢(Hydrogen Evolution Reaction, HER)领域的研究进展。
Abstract: With the development of social life, science and technology, the fossil fuels on which humans depend for survival are being consumed excessively. The resulting energy crisis and environmental pollution are imminent. The global energy supply and related environmental issues have become one of the biggest challenges faced by scientific and technical personnel. In response to the above problems, green energy, mainly solar energy, wind energy, biomass energy, ocean energy, geothermal energy and nuclear fusion energy, has attracted much attention. Because of its high efficiency, cleanliness, abundant reserves, high combustion calorific value (142 MJ/kg), and good continuity, hydrogen energy is considered to be a next-generation fuel with great potential to replace fossil energy. Using water splitting to produce hydrogen is an efficient way, but the smooth progress of water splitting to produce hydrogen requires the assistance of highly efficient electrocatalysts. Despite its high activity, traditional precious metal electrocatalysts have severely restricted their large-scale applications due to their lack of reserves, high cost, and poor long-term stability. Therefore, there is an urgent need to develop electrocatalysts that are efficient, cheap, stable, and can be prepared in a macroscopic manner to achieve the “hydrogen economy” blueprint. This article reviews the research progress in the field of Hydrogen Evolution Reaction (HER) in recent years.
文章引用：程煜, 徐新楠, 张莉芳, 刘杰, 周希, 钱涛. 析氢电催化剂的研究进展[J]. 纳米技术, 2021, 11(3): 155-165. https://doi.org/10.12677/NAT.2021.113019

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