铁氰化镍正极材料在天然海水中的储钠研究
The Sodium Ion Storage Process of Nickel Ferricyanide Cathode in the Natural Seawater
DOI: 10.12677/AEPE.2021.94021, PDF,    科研立项经费支持
作者: 范旭良*, 王泳茵, 冯珊珊:岭南师范学院化学化工学院,广东 湛江
关键词: 水系钠离子电池电解液海水铁氰化镍Aqueous Sodium Ion Battery Electrolyte Seawater Nickel Ferricyanide
摘要: 水系钠离子电池因为拥有安全性高、环境友好且造价成本低等特点受到广泛关注,被认为是一类极具发展潜力的新型储能体系。鉴于此,本研究使用简单的液相共沉淀法制备典型的普鲁士蓝类似物–铁氰化镍作为储钠活性材料,系统研究铁氰化镍在天然海水和0.5 mol/L氯化钠溶液中的电化学性能,阐明廉价天然海水作为水系钠离子电池电解液的可能性,进一步降低水系钠离子电池的成本,提高其应用价值。
Abstract: Owing to the high safety, environmentally friendly and low cost, aqueous sodium ion battery has been regarded as a promising energy storage system. Therefore, this study used a simple liquid phase co-precipitation method to prepare the typical Prussian blue analogue-nickel ferricyanide. And the electrochemical properties of derived nickel ferricyanide were measured in the electro-lytes of 0.5 mol/L NaCl and natural seawater. These results reveal the possibility of natural sea-water as the electrolyte of aqueous sodium ion battery. The application of natural seawater elec-trolyte would reduce the cost of aqueous sodium ion battery and increase its application value.
文章引用:范旭良, 王泳茵, 冯珊珊. 铁氰化镍正极材料在天然海水中的储钠研究[J]. 电力与能源进展, 2021, 9(4): 191-197. https://doi.org/10.12677/AEPE.2021.94021

参考文献

[1] 马慧, 张桓荣, 薛面起. 水系钠离子电池的研究进展及实用化挑战[J]. 化学学报, 2021, 79(4): 388-405.
[2] Nakamoto, K., Sakamoto, R., Sawada, Y., Ito, M. and Okada, S. (2019) Over 2 V Aqueous Sodium-Ion Battery with Prussian Blue-Type Electrodes. Small Methods, 3, Article ID: 1800220.
[3] 杨汉西, 钱江锋. 水溶液钠离子电池及其关键材料的研究进展[J]. 无机材料学报, 2013, 28(11): 1165-1171.
[4] Liu, Z., Huang, Y. and Huang, Y. (2020) Voltage Issue of Aqueous Rechargeable Metal-ion Batteries. Chemical Society Reviews, 49, 180-232.
[5] 田佳伟. 基于普鲁士蓝类似物衍生的结构调控复合材料制备及钠离子电池负极性能研究[D]: [博士学位论文]. 杭州: 浙江大学, 2019.
[6] Zhang, L.D., Huang, T. and Yu, A.S. (2015) Carbon-Coated Na3V2(PO4)3 Nanocomposite as a Novel High Rate Cathode Material for Aqueous Sodium Ion Batteries. Journal of Alloys and Compounds, 464, 522-527.
[7] Hwang, S.M., Park, J.S., Kim, Y., Go, W., Han, J., Kim, Y. and Kim, Y. (2019) Re-chargeable Seawater Batteries—From Concept to Applications. Advanced Materials, 31, Article ID: 1804936.
[8] Buser, H.J., Schwarzenbach, D., Petter, W. and Ludi, A. (1977) The Crystal Structure of Prussian Blue: Fe4[Fe(CN)6]3•xH2O. Inorganic Chemistry, 16, 2704.
[9] Zhou, Q., Wei, T., Liu, Z., Zhang, L., Yuan, B. and Fan, Z. (2019) Nickel Hexacyanoferrate on Graphene Sheets for High-Performance Asymmetric Supercapacitors in Neutral Aqueous Electrolyte. Electrochimica Acta, 303, 40-48.
[10] Shen, L.X., Jiang, Y., Liu, Y.F., Ma, J.L., Sun, T.R. and Zhu, N. (2020) High-Stability Monoclinic Nickel Hexacyanoferrate Cathode Materials for Ultrafast Aqueous Sodium Ion Battery. Chemical Engineering Journal, 388, Article ID: 124228.
[11] Fan, X., Luo, J., Shao, C., Zhou, X. and Niu, Z. (2015) Electrochemical Performance of Microdisc-Shaped Carbon-Coated Lithium Iron Phosphate with Preferentially Exposed (010) Planes in Lithium Sulfate Aqueous Solution. Electrochimica Acta, 158, 342-347.
[12] Wessells, C.D., Peddada, S.V., Huggins, R.A. and Cui, Y. (2011) Nickel Hexacyanoferrate Nanoparticle Electrodes for Aqueous Sodium and Potassium Ion Batteries. Nano Letter, 11, 5421-5425.